特高矿化度采出液曝氧诱导盐—颗粒复合沉积及堵塞风险

齐红媛; 卫肖喧; 艾国生; 吴俊霖; 韩国强; 张波; 张新庆; 王玉龙

doi:10.11949/0438-1157.20261001

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特高矿化度采出液曝氧诱导盐—颗粒复合沉积及堵塞风险

能源和环境工程 | 更新时间：2026-08-26

- 特高矿化度采出液曝氧诱导盐—颗粒复合沉积及堵塞风险
- Oxygen exposure of ultra-high salinity produced fluid induces salt-particle composite deposition and plugging risk
- 化工学报 2026年
- 作者机构：
  
  1.西安石油大学石油工程学院，陕西西安 710065
  2.西安石油大学陕西省油气田特种增产技术重点实验室，陕西西安 710065
  3.油气储运安全与节能陕西省高校工程研究中心，陕西西安 710065
  4.中国石油塔里木油田分公司，新疆库尔勒 841000
  5.中国石油天然气集团有限公司超深层复杂油气藏勘探开发技术研发中心，新疆库尔勒 841000
- 作者简介：
  
  齐红媛（1986-），女，博士，副教授，362882601@qq.com
- 基金信息：
  
  陕西省教育厅重点科学研究计划项目(25JR139)
- DOI：10.11949/0438-1157.20261001
  中图分类号： TE866
- 收稿：2026-07-26，
  
  修回：2026-08-25，
  
  录用：2026-08-26，
- 稿件说明：
移动端阅览
齐红媛, 卫肖喧, 艾国生, 等. 特高矿化度采出液曝氧诱导盐—颗粒复合沉积及堵塞风险[J/OL]. 化工学报, 2026.

QI Hongyuan, WEI Xiaoxuan, AI Guosheng, et al. Oxygen exposure of ultra-high salinity produced fluid induces salt-particle composite deposition and plugging risk[J/OL]. CIESC Journal, 2026.
齐红媛, 卫肖喧, 艾国生, 等. 特高矿化度采出液曝氧诱导盐—颗粒复合沉积及堵塞风险[J/OL]. 化工学报, 2026. DOI： 10.11949/0438-1157.20261001.

QI Hongyuan, WEI Xiaoxuan, AI Guosheng, et al. Oxygen exposure of ultra-high salinity produced fluid induces salt-particle composite deposition and plugging risk[J/OL]. CIESC Journal, 2026. DOI： 10.11949/0438-1157.20261001.

摘要

针对塔里木油田某区块特高矿化度采出液在集输过程中易发

生管壁沉积并诱发堵塞风险的问题，开展原水水质分析、静态曝氧实验、动态曝氧沉积实验和沉积物物相与微观结构表征，研究曝氧条件下采出液盐 - 颗粒复合沉积行为及潜在堵塞风险。结果表明：该采出液矿化度为 295491.39 mg/L，Na⁺和 Cl⁻为主导离子，Ca

⁺浓度较高，表观 Zeta 电位接近零值，颗粒体系稳定性较弱。静态曝氧过程中，HCO

⁻由 160.18 mg/L 降至 21.85 mg/L，pH 由 5.78 升至 6.10，悬固含量由 160.20 mg/L 增至 316.67 mg/L，说明曝氧可促进碳酸盐平衡迁移、难溶盐沉淀生成及颗粒复合团聚。动态沉积实验表明，不同管材表面沉积强度差异明显，144 h 时钢骨架管沉积量最高，为 7855.78 g·m⁻

，柔性复合管最低，为 2879.63 g·m⁻

。综合表征结果表明，沉积物中存在NaCl相关晶相信号、硅质颗粒及其他颗粒性固相，并具有明显的多组分复合累积和内部非均质结构特征。综合认为，敞口空气暴露引起的水化学变化、颗粒失稳、盐分富集、难溶盐固相形成及管壁捕获共同影响盐 - 颗粒复合沉积过程，该过程可导致沉积物在管壁持续累积，并进一步增加现场管道堵塞的潜在风险。研究结果可为特高矿化度采出液集输系统的管材优选、控氧、控颗粒和防堵治理提供依据。

Abstract

Aiming at the problem that the ultra-high salinity produced liquid in a block of Tarim Oilfield is prone to wall deposition and blockage risk during the gathering and transportation process

the raw water quality analysis

static oxygen exposure experiment

dynamic oxygen exposure deposition experiment and sediment phase and microstructure characterization were carried out to study the salt-particle composite deposition behavior and potential blockage mechanism of produced liquid under oxygen exposure conditions. The results show that the salinity of the produced liquid is 295491.39 mg / L

Na⁺ and Cl⁻ are the dominant ions

the concentration of Ca

⁺

is high

the apparent Zeta potential is close to zero

and the stability of the particle system is weak. In the process of static oxygen exposure

HCO

⁻ ~ -decreased from 160.18 mg / L to 21.85 mg / L

pH increased from 5.78 to 6.10

and suspended solid content increased from 160.20 mg / L to 316.67 mg / L

indicating that oxygen exposure could promote the equilibrium migration of carbonate

the formation of insoluble salt precipitation and the composite agglomeration of particles. The dynamic deposition experiment showed that the deposition strength of different pipe surfaces was significantly different. The deposition amount of steel skeleton pipe was the highest at 144

which was 7855.78 g·m

-2

and that of flexible composite pipe was the lowest

which was 2879.63 g·m

-2

. The comprehensive characterization results show that there are NaCl-related crystal phase signals

siliceous particles and other granular solids in the sediments

and there are obvious multi-component composite accumulation and internal heterogeneous structural characteristics. It is concluded that the chemical changes of water

particle instability

salt enrichment

solid phase formation of insoluble salt and pipe wall capture caused by open air exposure jointly affect the salt-particle composite deposition process

which can lead to the continuous accumulation of sediments on the pipe wall and further increase the potential risk of on-site pipeline blockage. The research results can provide a basis for pipe optimization

oxygen control

particle control and anti-blocking treatment of ultra-high salinity produced liquid gathering and transportation system.

关键词

Keywords

references

Amakiri K T , Canon A R , Molinari M , et al . Review of oilfield produced water treatment technologies [J ] . Chemosphere , 2022 , 298 : 134064 .

Cooper C M , McCall J , Stokes S C , et al . Oil and gas produced water reuse: opportunities, treatment needs, and challenges [J ] . ACS ES&T Engineering , 2022 , 2 ( 3 ): 347 - 366 .

李清方 , 刘中良 , 庞会中 , 等 . 基于机械蒸汽压缩蒸发的油田污水脱盐系统及分析 [J ] . 化工学报 , 2011 , 62 ( 7 ): 1963 - 1969 .

Li Q F , Liu Z L , Pang H Z , et al . Process simulation and analysis of mechanical vapor compression based oilfield waste water desalination systems [J ] . Ciesc Journa , 2011 , 62 ( 7 ): 1963 - 1969 .

曹立虎 , 江同文 , 潘昭才 , 等 . 塔里木盆地库车山前超深气井砂垢堵塞成因及靶向解除技术 [J ] . 天然气工业 , 2024 , 44 ( 8 ): 85 - 94 .

Cao L H , Jiang T W , Pan Z C , et al . Formation mechanism and targeted descaling technology of sand-scale composites in ultra-deep gas wells in the Kuqa piedmont of the Tarim Basin [J ] . Natural Gas Industry , 2024 , 44 ( 8 ): 85 - 94 .

江同文 , 孟祥娟 , 黄锟 , 等 . 克深2气田井筒堵塞机理及解堵工艺 [J ] . 石油钻采工艺 , 2020 , 42 ( 5 ): 657 - 661 .

Jiang T W , Meng X J , Huang K , et al . Well blockage mechanism and blockage removal technology in Keshen 2 Gas Field [J ] . Oil Drilling & Production Technology , 2020 , 42 ( 5 ): 657 - 661 .

韩巧云 , 杨晓杰 , 邹声华 . 深井降温系统管道结垢微观机理 [J ] . 化工学报 , 2016 , 67 ( 9 ): 3936 - 3945 .

Han Q Y , Yang X J , Zou S H . Micro-mechanism of scaling in a cooling system under deep mine [J ] . CIESC Journal , 2016 , 67 ( 9 ): 3936 - 3945 .

刘钲凯 , 邱正松 , 李佳 , 等 . 陵水25-1深水气田结垢预测与防治研究 [J ] . 钻井液与完井液 , 2022 , 39 ( 1 ): 126 - 132 .

Liu Z K , Qiu Z S , Li J , et al . Experimental research on prediction and prevention of scaling in Lingshui 25-1 gas reservoir [J ] . Drilling Fluid & Completion Fluid , 2022 , 39 ( 1 ): 126 - 132 .

邓志诚 , 许世峰 , 王淇冬 , 等 . 浸没燃烧处理高盐高化学需氧量废水过程与能耗分析 [J ] . 化工学报 , 2024 , 75 ( 3 ): 1000 - 1008 .

Deng Z C , Xu S F , Wang Q D , et al . Process and energy consumption analysis of high salt and high COD wastewater treatment by submerged combustion [J ] . CIESC Journal , 2024 , 75 ( 3 ): 1000 - 1008 .

吴文明 , 侯吉瑞 . 新疆某油田油井堵塞物成分及成因分析 [J ] . 油田化学 , 2022 , 39 ( 2 ): 349 - 354 .

Wu W M , Hou J R . Analysis on components and origin of the well blockage in one Xinjiang Oilfield [J ] . Oilfield Chemistry , 2022 , 39 ( 2 ): 349 - 354 .

Kamal M S , Hussein I , Mahmoud M , et al . Oilfield scale formation and chemical removal: a review [J ] . Journal of Petroleum Science and Engineering , 2018 , 171 : 127 - 139 .

Kumar S , Naiya T K , Kumar T . Developments in oilfield scale handling towards green technology-a review [J ] . Journal of Petroleum Science and Engineering , 2018 , 169 : 428 - 444 .

Yan Y , Tao Y , Huan Z , et al . Co-Deposition Mechanisms of Calcium Sulfate and Calcium Carbonate Scale in Produced Water [J ] . Crystals . 2021 , Vol.11(No. 12 ): 1494.

Valadbeygian V , Hajipour M , Behnood M . Static and dynamic evaluation of formation damage due to barium sulfate scale during water injection in carbonate reservoirs [J ] . Journal of Petroleum Exploration and Production Technology , 2023 , 13 ( 8 ): 1819 - 1831 .

Rafiee H , Sorbie K S , MacKay E J . The deposition kinetics of barium sulphate scale: model development [J ] . Frontiers in Materials , 2023 , 10 : 1198176 .

Pochapski D J , Carvalho Dos Santos C , Leite G W , et al . Zeta potential and colloidal stability predictions for inorganic nanoparticle dispersions: effects of experimental conditions and electrokinetic models on the interpretation of results [J ] . Langmuir , 2021 , 37 ( 45 ): 13379 - 13389 .

Daneshfar R , Soltani Soulgani B , Ashoori S . Identifying the mechanisms behind the stability of silica nano- and micro-particles: Effects of particle size, electrolyte concentration and type of ionic species [J ] . Journal of Molecular Liquids , 2024 , 397 : 124059 .

Awan F U R , Arif M , Iglauer S , et al . Coal fines migration: a holistic review of influencing factors [J ] . Advances in Colloid and Interface Science , 2022 , 301 : 102595 .

Awan F U R , Keshavarz A , Akhondzadeh H , et al . Stable dispersion of coal fines during hydraulic fracturing flowback in coal seam gas reservoirs: an experimental study [J ] . Energy & Fuels , 2020 , 34 ( 5 ): 5566 - 5577 .

Lin R , Huang Y J , Zhao J Z , et al . Coupled CFD-DEM modeling of fine particles and fibers migration and clogging mechanisms in bridging regions [J ] . Computers and Geotechnics , 2026 , 189 : 107647 .

Moriconi L , Nascimento T , de Souza B G B , et al . Top-down model of calcium carbonate scale formation in turbulent pipe flows [J ] . Thermal Science and Engineering Progress , 2022 , 28 : 101141 .

Gong L , Wu F Y , Pan M F , et al . Exploring the mechanisms of calcium carbonate deposition on various substrates with implications for effective anti-scaling material selection [J ] . Petroleum Science , 2024 , 21 ( 4 ): 2870 - 2880 .

Vazirian M M , Charpentier T V J , de Oliveira Penna M , et al . Surface inorganic scale formation in oil and gas industry: as adhesion and deposition processes [J ] . Journal of Petroleum Science and Engineering , 2016 , 137 : 22 - 32 .

韩志敏 , 周相宇 , 张宏宇 , 等 . 不同粗糙元结构下CaCO 3 污垢局部沉积特性 [J ] . 化工学报 , 2025 , 76 ( 1 ): 151 - 160 .

Han Z M , Zhou X Y , Zhang H Y , et al . Local deposition characteristics of CaCO 3 fouling under different roughness element structures [J ] . CIESC Journal , 2025 , 76 ( 1 ): 151 - 160 .

SY/T 5523-2025 . 油田水分析方法 [S ] . 北京 : 石油工业出版社 , 2026 .

SY/T 5523-2025 . Analysis method for oil and gas field water [S ] . Beijing : Petroleum Industry Press , 2026 .

SY/T 6662.1-2022 . 石油天然气工业用非金属复合管第1部分：钢骨架增强聚乙烯复合管 [S ] . 北京 : 石油工业出版社 , 2022 .

SY/T 6662.1-2022 . Non-metallic composite pipe for petroleum and natural gas industries -Part 1: Steel skeleton reinforced polythene composite pipes [S ] . Beijing : Petroleum Industry Press , 2022 .

SY/T 6662.2-2020 . 石油天然气工业用非金属复合管第2部分：柔性复合高压输送管 [S ] . 北京 : 石油工业出版社 , 2021 .

SY/T 6662.2-2020 . Non-metallic composite pipe for petroleum and natural gas industriesPart 2: Flexible composite pipe for high pressure transmission [S ] . Beijing : Petroleum Industry Press , 2021 .

张劲军 , 黄启玉 , 严大凡 . 管输剪切模拟搅拌槽中流体平均剪切率的计算 [J ] . 石油学报 , 2003 , 24 ( 2 ): 94 - 96, 100 .

Zhang J J , Huang Q Y , Yan D F . Estimation of average shear rate in stirred vessels for pipelining shear simulation [J ] . Acta Petrolei Sinica , 2003 , 24 ( 2 ): 94 - 96, 100 .

Metzner A B , Otto R E . Agitation of non-Newtonian fluids [J ] . AIChE Journal , 1957 , 3 ( 1 ): 3 - 10 .

Wang H N , Duan X X , Feng X , et al . Effect of impeller type and scale-up on spatial distribution of shear rate in a stirred tank [J ] . Chinese Journal of Chemical Engineering , 2022 , 42 : 351 - 363 .

Parkhurst D. L. , Appelo C. A. J. . Description of Input and Examples for PHREEQC Version 3: A Computer Program for Speciation, Batch-Reaction, One-Dimensional Transport, and Inverse Geochemical Calculations .[R ] . Reston, VA : U.S. Geological Survey , 2013 .

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