北京交通大学碳中和与环境学院,智能交通绿色低碳技术教育部工程研究中心,北京 100044
2.北京交通大学碳中和与环境学院,碳评估重点实验室国家铁路局铁路行业科技创新基地,北京 100044
3.新疆干旱区环境污染与生态修复重点实验室,中国科学院新疆生态与地理研究所,新疆 乌鲁木齐 830063
刘福星(2002—),男,硕士研究生,24126632@bjtu.edu.cn
李俊杰(1989—),男,博士,副教授,jjli1@bjtu.edu.cn
收稿:2026-04-10,
修回:2026-05-18,
录用:2026-05-19,
移动端阅览
刘福星, 李俊杰, 陈雨佳, 等. 中国合成氨行业碳-能-水足迹研究[J/OL]. 化工学报, 2026.
LIU Fuxing, LI Junjie, CHEN Yujia, et al. Research on carbon-energy-water footprints of China’s ammonia synthesis industry[J/OL]. CIESC Journal, 2026.
刘福星, 李俊杰, 陈雨佳, 等. 中国合成氨行业碳-能-水足迹研究[J/OL]. 化工学报, 2026. DOI: 10.11949/0438-1157.20260494.
LIU Fuxing, LI Junjie, CHEN Yujia, et al. Research on carbon-energy-water footprints of China’s ammonia synthesis industry[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260494.
合成氨是粮食安全基石,我国煤制合成氨占比超75%,其高碳排放、高能耗、高水耗引发广泛关注。现有研究多聚焦于不同原料路线制合成氨的碳足迹(CF)对比,但对碳-能-水足迹的综合分析不足,且未系统揭示技术升级与规模扩张对煤制合成氨碳-能-水足迹的影响机制。本研究构建了合成氨生产的碳-能-水足迹分析框架,基于181家企业运行数据系统评估13种原料(煤、焦炉气、天然气)-技术(气流床、流化床、固定床)-规模(大、中、小)组合的碳-能-水足迹差异。结果表明,焦炉气-中型组合环境表现最优,其CF(0.92 t CO
2
-eq/t)和水足迹(WF)(4.39 m
3
/t)仅为煤-固定床-小型组合的10.4%和12.4%,但能源足迹(EF)(21.86 GJ/t)介于天然气-中型和天然气-大型之间。研究结果为煤制合成氨行业推进固定床向气流床升级、装置规模化、分区精准管控及低碳原料路线(焦炉气、天然气)推广提供量化依据,支撑碳-能-水协同减排。
Ammonia serves as the cornerstone of food security. In China
coal-based ammonia synthesis accounts for over 75% of the total production
and its high carbon emissions
high energy consumption
and high water consumption have attracted widespread attention. Existing research has mostly focused on comparing the carbon footprints (CF) of ammonia synthesis via different feedstock routes
but there is a lack of comprehensive analysis on the carbon-energy-water footprint. Moreover
the impact mechanisms of technological upgrading and scale expansion on the carbon-energy-water footprint of coal-based ammonia synthesis have not been systematically revealed. This study constructs a carbon-energy-water footprint analysis framework for ammonia production
and systematically evaluates the differences in carbon-energy-water footprints among 13 feedstock-technology-scale combinations (including coal
coke oven gas
natural gas; entrained-flow bed
fluidized bed
fixed bed; large
medium
and small scales) based on the operational data of 181 enterprises. The results show that the medium-scale coke oven gas combination exhibits the optimal environmental performance. Its carbon footprint (CF
0.92 t CO₂-eq/t) and water footprint (WF
4.39 m³/t) are only 10.4% and 12.4% of those of the small-scale coal-fixed bed combination
respectively
while the energy footprint (EF
21.86 GJ/t) is between that of the medium-scale and large-scale natural gas combinations. The research findings provide a quantitative basis for the coal-to-ammonia industry to promote the upgrading from fixed-bed to entrained-bed technologies
large-scale installation development
zoned precise regulation
and the popularization of low-carbon raw material routes (coke oven gas
natural gas)
and support the coordinated reduction of carbon
energy and water footprints.
谢克昌 . 新型能源体系发展背景下煤炭清洁高效转化的挑战及途径 [J ] . 煤炭学报 , 2024 , 49 ( 01 ): 47 - 56 .
Xie K C . Develop new energy system and promote clean and efficient conversion of coal [J ] . Journal of China Coal Society , 2024 , 49 ( 1 ): 47 - 56 .
张晓龙 . “双碳”目标下火电厂降耗增效技术体系构建与实践 [J ] . 清洗世界 , 2026 , 42 ( 4 ): 7 - 9 .
Zhang X L . Construction and practice of energy saving and efficiency improvement technology eystem for thermal power plants under the dual carbon target [J ] . Cleaning World , 2026 , 42 ( 4 ): 7 - 9 .
王智 . 基于绿色化学理念的合成氨与尿素工艺优化研究 [J ] . 现代盐化工 , 2025 , 52 ( 3 ): 41 - 43 .
Wang Z . Study on process optimization of synthetic ammonia and urea based on green chemistry concept [J ] . Modern Salt and Chemical Industry , 2025 , 52 ( 3 ): 41 - 43 .
曲志鹏 , 池若夕 . 化工合成氨工艺增效及节能减排脱硝技术优化 [J ] . 山西化工 , 2025 , 45 ( 10 ): 210 - 212 .
Qu Z P , Chi R X . Optimization of efficiency enhancement, energy conservation, emission reduction, and disposal technology for chemical synthetic ammonia process [J ] . Shanxi Chemical Industry , 2025 , 45 ( 10 ): 210 - 212 .
韦佳宁 . 合成氨工业节能减排技术探析 [J ] . 中国设备工程 , 2024 ( 14 ): 227 - 229 .
Wei J N . Discussion on energy saving and emission reduction technology of synthetic ammonia industry [J ] . China Plant Engineering , 2024 ( 14 ): 227 - 229 .
刘迪 , 汤玮健 , 韩伟 , 等 . 绿氢时代的船用燃料: 绿色甲醇和绿氨 [J ] . 化工进展 , 2025 , 44 ( 12 ): 6747 - 6754 .
Liu D , Tang W J , Han W , et al . Marine fuels in the era of green hydrogen: green methanol and green ammonia [J ] . Chemical Industry and Engineering Progress , 2025 , 44 ( 12 ): 6747 - 6754 .
梁嘉麟 , 宋健伟 . 可持续合成氨技术研究进展: 传统工艺优化与绿氨产业化对比 [J ] . 化工设计通讯 , 2026 , 52 ( 2 ): 1 - 4 .
Liang J L , Song J W . Research progress on sustainable ammonia synthesis technology: optimization of traditional processes and challenges in green ammonia industrialization [J ] . Chemical Engineering Design Communications , 2026 , 52 ( 2 ): 1 - 4 .
贾蓉蓉 , 任腊春 , 王井 , 等 . 绿电制氢规模优化分析 [J ] . 当代化工 , 2026 , 55 ( 1 ): 188 - 192 .
Jia R R , Ren L C , Wang J , et al . Analysis of green hydrogen scale optimization [J ] . Contemporary Chemical Industry , 2026 , 55 ( 1 ): 188 - 192 .
杨洋 , 初祺涵 , 黄海博 , 等 . 轨道交通列车碳排放核算与低碳减排技术综述 [J ] . 铁道运输与经济 , 2026 , 48 ( 3 ): 1 - 17 .
Yang Y , Chu Q H , Huang H B , et al . Review of carbon emission accounting and low-carbon emission reduction technologies for rail transit trains [J ] . Railway Transport and Economy , 2026 , 48 ( 3 ): 1 - 17 .
Chen X J , Lei T Y , Zhao W C , et al . China’s petrochemical plants’ CO 2 emissions and high-impact contributors for carbon-neutrality production [J ] . Science Advances , 2026 , 12 ( 12 ): eadx7784 .
佘青汀 , 高翔 . 基于专利视角的生物质化工耦合绿氢技术发展态势分析 [J ] . 中国科技产业 , 2026 ( 3 ): 62 - 66 .
She Q T , Gao X . Development trend analysis of biomass chemical coupling green hydrogen technology based on patent perspective [J ] . Science & Technology Industry of China , 2026 ( 3 ): 62 - 66 .
李娟 . 光伏制绿氢绿氨发展和展望 [J ] . 价值工程 , 2026 , 45 ( 4 ): 81 - 84 .
Li J . Development and prospect of photovoltaic green hydrogen and green ammonia production [J ] . Value Engineering , 2026 , 45 ( 4 ): 81 - 84 .
Zhang Y L , Liu H , Li J J , et al . Life cycle assessment of ammonia synthesis in China [J ] . The International Journal of Life Cycle Assessment , 2022 , 27 ( 1 ): 50 - 61 .
汪家铭 . 安徽晋煤中能化工新60万吨/年合成氨智能升级技术改造项目开工 [J ] . 四川化工 , 2017 , 20 ( 4 ): 57 .
Wang J M . Anhui Jinmei Zhongneng Chemical Industry started the new 600, 000-ton/year intelligent upgrading technical transformation project of synthetic ammonia [J ] . Sichuan Chemical Industry , 2017 , 20 ( 4 ): 57 .
朱桂芳 . 煤基氨联产天然气技改项目的技术经济可行性分析 [J ] . 煤化工 , 2015 , 43 ( 5 ): 51 - 53, 66 .
Zhu G F . Techno-economic analysis of the upgrading project for coal-based ammonia plants to co-generate SNG [J ] . Coal Chemical Industry , 2015 , 43 ( 5 ): 51 - 53, 66 .
张洪航 , 梁传彬 , 张文歆 , 等 . 水-能-碳视角下的中国主粮作物热量生产力评估 [J ] . 水资源与水工程学报 , 2025 , 36 ( 5 ): 195 - 204 .
Zhang H H , Liang C B , Zhang W X , et al . Caloric productivity assessment of major grain crops in China from water-energy-carbon perspective [J ] . Journal of Water Resources and Water Engineering , 2025 , 36 ( 5 ): 195 - 204 .
王红瑞 , 李晓军 , 张力 , 等 . 水-能源-碳排放复杂关系研究进展及展望 [J ] . 南水北调与水利科技(中英文) , 2023 , 21 ( 1 ): 13 - 21 .
Wang H R , Li X J , Zhang L , et al . Research progress and the prospect of a complex relationship between water-energy-carbon emission [J ] . South-to-North Water Transfers and Water Science & Technology , 2023 , 21 ( 1 ): 13 - 21 .
杨屹 , 张园园 . 呼包鄂榆资源型城市群“水-能-碳”耦合变化及影响因素 [J ] . 中国环境科学 , 2023 , 43 ( 11 ): 6212 - 6224 .
Yang Y , Zhang Y Y . Analysis of the coupling process and the influencing factors of the “water-energy-carbon” relationship in the Hohhot-Baotou-Ordos-Yulin resource-based urban agglomeration [J ] . China Environmental Science , 2023 , 43 ( 11 ): 6212 - 6224 .
陈小时 . 双碳目标下新疆油田甲烷与VOCs协同减排路径与安全管控研究 [J ] . 化工安全与环境 , 2026 , 39 ( 3 ): 79 - 84, 88 .
Chen X S . Research on synergistic emission reduction path and safety management and control of methane and VOCs in Xinjiang Oilfield under the double carbon target [J ] . Chemical Safety & Environment , 2026 , 39 ( 3 ): 79 - 84, 88 .
贺帅 . 四川省农业水—能—碳系统影响因素及耦合关系研究 [D ] . 雅安 : 四川农业大学 , 2025 .
He S . Research on the influencing factors and coupling relationships of agricultural water-energy-carbon nexus in Sichuan Province [D ] . Yaan : Sichuan Agricultural University , 2025 .
刘梦华 , 黄逍 , 李爽 , 等 . 基于全生命周期评价的中国制氨路线碳排放、能源效率研究及展望 [J ] . 中国科学(技术科学) , 2024 , 54 ( 7 ): 1329 - 1346 .
Liu M H , Huang X , Li S , et al . Carbon emission and energy efficiency analysis of ammonia production routes in China from life-cycle perspective and prospects [J ] . Scientia Sinica (Technologica) , 2024 , 54 ( 7 ): 1329 - 1346 .
Li G X , Chen R Y , Wen Z X , et al . Global coal-rock gas resource potential and distribution [J ] . Petroleum Exploration and Development , 2026 , 53 ( 1 ): 16 - 30 .
郭丽 , 王亚楠 , 许文 , 等 . 我国天然气制合成氨行业发展现状及建议 [J ] . 化学工业 , 2025 , 43 ( 2 ): 33 - 36, 40 .
Guo L , Wang Y N , Xu W , et al . The development situation and suggestions of natural gas synthetic ammonia production in China [J ] . Chemical Industry , 2025 , 43 ( 2 ): 33 - 36, 40 .
Zhao Y X , Zhao Y J , Huang Y , et al . Pinch analysis for heat integration of pulverized coke chemical looping gasification coupled with coke-oven gas to methanol and ammonia [J ] . Processes , 2022 , 10 ( 9 ): 1879 .
窦睿然 , 殷景雨 , 李敏 . 水煤浆气化技术研究进展与展望 [J ] . 氮肥技术 , 2025 , 46 ( 6 ): 4 - 7, 15 .
Dou R R , Yin J Y , Li M . Research progress and prospects of water-coal slurry gasification technology [J ] . Danfei Jishu , 2025 , 46 ( 6 ): 4 - 7, 15 .
张志东 , 周建欣 , 孙洋洋 , 等 . E-Gas水煤浆气化与常规水煤浆气化技术对比分析 [J ] . 中氮肥 , 2025 ( 5 ): 15 - 18 .
Zhang Z D , Zhou J X , Sun Y Y , et al . Comparative analysis of E-Gas coal water slurry gasification and conventional coal water slurry gasification technology [J ] . M-Sized Nitrogenous Fertilizer Progress , 2025 ( 5 ): 15 - 18 .
王强民 . 生态脆弱富煤区矿井水水文地球化学成因及资源化利用 [J ] . 工业水处理 , 2026 , 46 ( 4 ): 81 - 88 .
Wang Q M . Hydrogeochemical causes and resource utilization of mine water in ecologically fragile coal-rich areas [J ] . Industrial Water Treatment , 2026 , 46 ( 4 ): 81 - 88 .
Shu C , Xiang N , Li S N , et al . Temporal-sectoral assessment and driving factors exploration of air pollution and carbon reduction synergy during the transformation process in a petroleum resource-based city [J ] . Journal of Cleaner Production , 2025 , 537 : 147194 .
Yang J D , Guan Y F , Wang R , et al . The impact of resource endowment and digital transformation on the efficiency of energy transition [J ] . Energy Science & Engineering , 2026 , 14 ( 4 ): 2182 - 2205 .
Wang Z , Zhang Y H , Wang J , et al . Carbon footprint calculation for power transmission and distribution equipment: a comprehensive review of methodologies, standards, and applications [J ] . Resources , Conservation & Recycling Advances, 2025 , 28 : 200295 .
李俊杰 . 基于GIS-LCA的中国现代煤化工行业环境足迹研究 [D ] . 北京 : 中国矿业大学(北京) , 2022 .
Li J J . GIS-LCA based assessment of the environmental footprint of the advanced coal chemical industry in China [D ] . Beijing : China University of Mining & Technology, Beijing , 2022 .
Wang K , Wang X P , Feng X , et al . Improved gray water footprint calculation and assessment method for polyester fabric production [J ] . AATCC Journal of Research , 2022 , 9 ( 2 ): 74 - 80 .
Zhang J , Li J J , Wang Y R , et al . Unveiling the heterogeneity of environmental impacts of China’s coal washing plants by a configuration-specific life cycle assessment [J ] . Environmental Impact Assessment Review , 2025 , 110 : 107725 .
Liu Y R , Lv D , Wang W , et al . Insight into magnetic characteristics and magnetization plateaus of the metal-coordinated polymer [Dy 2 Cu 2 ] n [J ] . Applied Physics A , 2026 , 132 ( 5 ): 386 .
Li J Y , Ma X X , Liu H , et al . Life cycle assessment and economic analysis of methanol production from coke oven gas compared with coal and natural gas routes [J ] . Journal of Cleaner Production , 2018 , 185 : 299 - 308 .
Wen Z G , Meng F X , Di J H , et al . Technological approaches and policy analysis of integrated water pollution prevention and control for the coal-to-methanol industry based on Best Available Technology [J ] . Journal of Cleaner Production , 2016 , 113 : 231 - 240 .
Wang S , Yu S J , Feng T X , et al . Life cycle environmental impacts based on detailed stages and synergistic environmental benefits of coke production in China [J ] . Journal of Environmental Chemical Engineering , 2025 , 13 ( 5 ): 117527 .
Wu R N , Wang R N , Nian Z W , et al . Spatio-temporal variation and decoupling effects of energy carbon footprint based on nighttime light data: Evidence from counties in Northeast China [J ] . Atmospheric Pollution Research , 2025 , 16 ( 2 ): 102366 .
Chen J J , Yang S Y , Qian Y . A novel path for carbon-rich resource utilization with lower emission and higher efficiency: an integrated process of coal gasification and coking to methanol production [J ] . Energy , 2019 , 177 : 304 - 318 .
Cui P Z , Yao D , Ma Z Y , et al . Life cycle water footprint comparison of biomass-to-hydrogen and coal-to-hydrogen processes [J ] . Science of the Total Environment , 2021 , 773 : 145056 .
Liu J , Yu M , Ren Y Q , et al . LCA-based environment and economic assessment of UCG coupled with CCS for methanol production [J ] . Energy , 2025 , 336 : 138573 .
Zeng T , Chen Y Q , Wang L H , et al . Carbon emission calculation during the production and construction phases of overhead transmission lines [J ] . Energies , 2026 , 19 ( 4 ): 873 .
Yang J , Zhang P D . Assessment methods of carbon dioxide emitted from bioenergy utilization [J ] . Renewable and Sustainable Energy Reviews , 2011 , 15 ( 6 ): 2684 - 2689 .
Ma R , Duan W T , Zhang Q . Integrated liquid hydrogen production technology with cascade separation and waste heat&cooling energy utilization [J ] . Energy , 2025 , 335 : 138224 .
Liu Z Y , Yu Q B , Xie H Q , et al . Process design and kinetic-based simulation of a coupled biomass gasification and chemical looping ammonia generation system [J ] . Processes , 2026 , 14 ( 4 ): 588 .
Soni K , Lanjekar P R , Panwar N L . Biomass-based green ammonia: Pathways, technologies, and sustainability for a carbon-neutral future [J ] . Unconventional Resources , 2025 , 8 : 100241 .
0
浏览量
6
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010102001995号