中国矿业大学化工学院,江苏 徐州 221116
董彬(1984—),男,博士,副教授,cumtdong@cumt.edu.cn
周长春(1972—),男,博士,教授,cczhoucumt@126.com
收稿:2026-03-23,
修回:2026-05-21,
录用:2026-05-22,
移动端阅览
董彬, 车心怡, 周长春. 水凝胶基锂吸附材料研究进展[J/OL]. 化工学报, 2026.
DONG Bin, CHE Xinyi, ZHOU Changchun. Recent Progress on Hydrogel-Based Lithium Adsorbents[J/OL]. CIESC Journal, 2026.
董彬, 车心怡, 周长春. 水凝胶基锂吸附材料研究进展[J/OL]. 化工学报, 2026. DOI: 10.11949/0438-1157.20260352.
DONG Bin, CHE Xinyi, ZHOU Changchun. Recent Progress on Hydrogel-Based Lithium Adsorbents[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260352.
锂资源需求持续增长,吸附法因绿色高效,被认为是从盐湖卤水、海水等液态锂资源中提锂的具有潜力的技术之一。水凝胶基吸附材料凭借三维多孔网络、可功能化设计、机械性能优异,成为新一代锂吸附材料的重要方向。目前,已发展出冠醚/氟功能化水凝胶、锂离子筛复合水凝胶、锂铝层状双金属氢氧化物复合水凝胶、金属有机框架复合水凝胶及MXene复合水凝胶等材料体系,在吸附容量、锂离子选择性和循环稳定性方面表现突出。但该领域仍面临多离子竞争吸附、水凝胶结构稳定性不足及功能基团耐久性有限等挑战。未来研究需聚焦多机制协同提锂、材料结构与性能的精准调控及规模化制备技术,以推动水凝胶基吸附材料实现绿色高效的工业化提锂。
The demand for lithium resources continues to grow
and adsorption is considered one of the promising technologies for lithium extraction from liquid lithium resources (e.g.
salt lake brines and seawater) owing to its green and efficient characteristics. Hydrogel-based adsorbents have emerged as a significant direction for next-generation lithium adsorbents
characterized by their three-dimensional porous networks
facile functionalization design
and good mechanical properties. Currently
some systems have been developed
including crown ether/fluorine-functionalized hydrogels
lithium-ion sieve composite hydrogels
lithium-aluminum layered double hydroxide composite hydrogels
metal organic framework composite hydrogels
and MXene composite hydrogels. These materials exhibit outstanding performance in terms of adsorption capacity
lithium-ion selectivity
and cyclic stability. However
the field still faces multiple challenges
such as competitive adsorption from coexisting ions
insufficient structural stability of the hydrogels
and limited durability of functional groups. Future research should focus on synergistic multi-mechanism effects for lithium extraction
precise structure-property regulation
and scalable preparation technologies
in order to promote the green and efficient industrial application of hydrogel-based adsorbents for lithium extraction.
盛涛 , 王武名 , 代定 , 等 . 刚果(金)马诺诺含锂尾矿特征及锂资源回收评价 [J ] . 中国矿业 , 2025 , 34 ( 10 ): 226 - 233 .
Sheng T , Wang W M , Dai D , et al . Characteristics of lithium tailings and evaluation of lithium resource recovery in Manono, DRC [J ] . China Mining Magazine , 2025 , 34 ( 10 ): 226 - 233 .
Li Z H , Wang C Y , Chen J . Supply and demand of lithium in China based on dynamic material flow analysis [J ] . Renewable and Sustainable Energy Reviews , 2024 , 203 : 114786 .
郭宇 , 于刚强 , 陈标华 . 废锂离子电池的冶金回收工艺研究进展 [J ] . 北京工业大学学报 , 2024 , 50 ( 2 ): 230 - 245 .
Guo Y , Yu G Q , Chen B H . Research progress on metallurgical recovery process of waste lithium batteries [J ] . Journal of Beijing University of Technology , 2024 , 50 ( 2 ): 230 - 245 .
Attia P M , Moch E , Herring P K . Challenges and opportunities for high-quality battery production at scale [J ] . Nature Communications , 2025 , 16 : 611 .
张照志 , 潘昭帅 , 车东 . 基于中国锂矿床及资源特征的2024—2035年锂供需形势分析 [J ] . 中国矿业 , 2024 , 33 ( 6 ): 26 - 44 .
Zhang Z Z , Pan Z S , Che D . Analysis of lithium supply and demand situation based on lithium deposits and resources characteristics from 2024 to 2035, China [J ] . China Mining Magazine , 2024 , 33 ( 6 ): 26 - 44 .
文佳豪 , 代鸿章 , 陈翠华 , 等 . 中国锂资源供需现状与资源保障程度研究 [J ] . 地质通报 , 2025 , 44( 2 ~ 3 ): 245 - 258 .
Wen J H , Dai H Z , Chen C H , et al . The supply and demand status and resource guarantee degree of lithium in China [J ] . Geological Bulletin of China , 2025 , 44( 2 ~ 3 ): 245 - 258 .
Wang X L , Ding T , Zheng M P , et al . Lithium extraction from oil and gas produced water: resource characteristics, technological challenges and future perspectives [J ] . Water Research , 2026 , 294 : 125546 .
Darling S B . The brine of the times [J ] . Science , 2024 , 385 ( 6716 ): 1421 - 1422 .
黄豪擎 , 郭游 , 路生全 , 等 . 卤水型锂矿开发利用前景: 理论、技术与可持续发展路径 [J ] . 世界有色金属 , 2025 ( 18 ): 225 - 228 .
Huang H Q , Guo Y , Lu S Q , et al . Prospects for the development and utilization of brine-type lithium deposits: theories, technologies, and sustainable development pathways [J ] . World Nonferrous Metals , 2025 ( 18 ): 225 - 228 .
齐涛 , 苏慧 , 周彬彬 , 等 . 盐湖卤水提锂技术进展 [J ] . 有色金属(冶炼部分) , 2026 ( 4 ): 724 - 742 .
Qi T , Su H , Zhou B B , et al . Progress in lithium extraction technologies from salt lake brines [J ] . Nonferrous Metals (Extractive Metallurgy) , 2026 ( 4 ): 724 - 742 .
代玉 , 杨凯华 , 伍淑敏 , 等 . 吸附法盐湖提锂的研究进展与挑战 [J ] . 稀有金属与硬质合金 , 2025 , 53 ( 6 ): 29 - 40 .
Dai Y , Yang K H , Wu S M , et al . Research progress and challenges of lithium extraction from salt lake by adsorption method [J ] . Rare Metals and Cemented Carbides , 2025 , 53 ( 6 ): 29 - 40 .
李露 , 马来波 , 王亮 , 等 . 锂资源回收技术研究进展 [J ] . 盐科学与化工 , 2025 , 54 ( 11 ): 17 - 20 .
Li L , Ma L B , Wang L , et al . Research progress of lithium resource recycling technology [J ] . Journal of Salt and Chemical Industry , 2025 , 54 ( 11 ): 17 - 20 .
Shi C L , Jing Y , Jia Y Z . Solvent extraction of lithium ions by tri-n-butyl phosphate using a room temperature ionic liquid [J ] . Journal of Molecular Liquids , 2016 , 215 : 640 - 646 .
Hu H Q , Guo X S , Yang L M , et al . Adsorption materials toward highly-efficient lithium extraction from non-conventional lithium sources [J ] . Advanced Materials , 2025 , 37 ( 38 ): 2506055 .
Limjuco L A , Nisola G M , Lawagon C P , et al . H 2 TiO 3 composite adsorbent foam for efficient and continuous recovery of Li + from liquid resources [J ] . Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2016 , 504 : 267 - 279 .
Li J , Luo Q L , Dong M Z , et al . Synthesis of granulated Li/Al-LDHs adsorbent and application for recovery of Li from synthetic and real salt lake brines [J ] . Hydrometallurgy , 2022 , 209 : 105828 .
Oral I , Abetz V . A highly selective polymer material using benzo-9-crown-3 for the extraction of lithium in presence of other interfering alkali metal ions [J ] . Macromolecular Rapid Communications , 2021 , 42 ( 9 ): 2000746 .
Yang L M , Tu Y Y , Li H Y , et al . Fluorine-rich supramolecular nano-container crosslinked hydrogel for lithium extraction with super-high capacity and extreme selectivity [J ] . Angewandte Chemie International Edition , 2023 , 62 ( 38 ): e202308702 .
Hou J , Zhang H C , Thornton A W , et al . Lithium extraction by emerging metal–organic framework-based membranes [J ] . Advanced Functional Materials , 2021 , 31 ( 46 ): 2105991 .
Wu Y N , Jia M M , Li S M , et al . Positively charged Ti 3 C 2 T x membrane for enhanced Li + /Mg 2+ sieving [J ] . Journal of Membrane Science , 2025 , 717 : 123604 .
Xu X , Chen Y M , Wan P Y , et al . Extraction of lithium with functionalized lithium ion-sieves [J ] . Progress in Materials Science , 2016 , 84 : 276 - 313 .
Orooji Y , Nezafat Z , Nasrollahzadeh M , et al . Recent advances in nanomaterial development for lithium ion-sieving technologies [J ] . Desalination , 2022 , 529 : 115624 .
Zhang G T , Hai C X , Zhou Y , et al . Synthesis and performance estimation of a granulated PVC/PAN-lithium ion-sieve for Li + recovery from brine [J ] . Separation and Purification Technology , 2023 , 305 : 122431 .
Sun D S , Meng M J , Yin Y J , et al . Highly selective, regen erated ion-sieve microfiltration porous membrane for targeted separation of Li + [J ] . Journal of Porous Materials , 2016 , 23 ( 6 ): 1411 - 1419 .
段皓月 . MnO 2 ·0.5H 2 O型锂离子筛的制备和成型 [D ] . 上海 : 上海师范大学 , 2020 .
Duan H Y . Preparation and forming of MnO 2 ·0.5H 2 O lithium ion-sieve [D ] . Shanghai : Shanghai Normal University , 2020 .
Gao J M , Du Z Y , Zhao Q , et al . Enhanced Li + adsorption by magnetically recyclable iron-doped lithium manganese oxide ion-sieve: Synthesis, characterization, adsorption kinetics and isotherm [J ] . Journal of Materials Research and Technology , 2021 , 13 : 228 - 240 .
Liu J J , Qu S X , Suo Z G , et al . Functional hydrogel coatings [J ] . National Science Review , 2021 , 8 ( 2 ): nwaa254 .
刘旭 , 李杨可欣 , 杜黎 , 等 . 水凝胶的制备及仿生设计在能源领域应用的研究进展 [J ] . 应用化学 , 2022 , 39 ( 1 ): 35 - 54 .
Liu X , Li Y K X , Du L , et al . Bio-inspired hydrogels: synthesis, bionic design and applications in the field of energy storage and conversion [J ] . Chinese Journal of Applied Chemistry , 2022 , 39 ( 1 ): 35 - 54 .
Xu X W , Jerca V V , Hoogenboom R . Bioinspired double network hydrogels: from covalent double network hydrogels via hybrid double network hydrogels to physical double network hydrogels [J ] . Materials Horizons , 2021 , 8 ( 4 ): 1173 - 1188 .
Szarpak A , Auzély-Velty R . Hyaluronic acid single-network hydrogel with high stretchable and elastic properties [J ] . Carbohydrate Polymers , 2023 , 320 : 121212 .
陈庆龙 . 抗干抗冻高应变水凝胶的制备与应变传感性能研究 [D ] . 长春 : 长春工业大学 , 2024 .
Chen Q L . Preparation and strain sensing performance study of anti-drying, anti-freezing, high-strain hydrogels [D ] . Changchun : Changchun University of Technology , 2024 .
秦绪平 . 微凝胶复合高强度水凝胶的制备及性能研究 [D ] . 济南 : 山东大学 , 2011 .
Qin X P . Preparation and properties of microgel composite hydrogels with high mechanical strength [D ] . Jinan : Shandong University , 2011 .
梅晶 , 刘改华 , 张堃 , 等 . 互穿网络结构PMMA共混体系研究进展 [J ] . 包装工程 , 2020 , 41 ( 19 ): 99 - 107 .
Mei J , Liu G H , Zhang K , et al . Research progress of interpenetrating network structure of PMMA blending system [J ] . Packaging Engineering , 2020 , 41 ( 19 ): 99 - 107 .
Bongiovanni Abel S , Busatto C A , Karp F , et al . Weaving the next generation of (bio)materials: Semi-interpenetrated and interpenetrated polymeric networks for biomedical applications [J ] . Advances in Colloid and Interface Science , 2023 , 321 : 103026 .
张博 , 张振 , 江东 . 单宁酸改性互穿网络水凝胶促进断裂跟腱术后的组织重塑 [J ] . 中国组织工程研究 , 2025 , 29 ( 4 ): 721 - 729 .
Zhang B , Zhang Z , Jiang D . Tannic acid modified interpenetrating network hydrogel promotes tissue remodeling of ruptured Achilles tendon after surgery [J ] . Chinese Journal of Tissue Engineering Research , 2025 , 29 ( 4 ): 721 - 729 .
王晓飞 . 基于动态可逆共价键与非共价键结合的自修复IPN水凝胶的制备与性能研究 [D ] . 青岛 : 青岛科技大学 , 2018 .
Wang X F . Research on synthesis and properties of self-healing interpenetrating network hydrogels based on reversible covalent bonds and reversible non-covalent bonds [D ] . Qingdao : Qingdao University of Science & Technology , 2018 .
Gong J P , Katsuyama Y , Kurokawa T , et al . Double-network hydrogels with extremely high mechanical strength [J ] . Advanced Materials , 2003 , 15 ( 14 ): 1155 - 1158 .
黎贵凤 , 梁家玲 , 郭世锐 , 等 . 双网络水凝胶的构筑及其在生物医药领域的应用 [J ] . 工程塑料应用 , 2024 , 52 ( 12 ): 165 - 170 .
Li G F , Liang J L , Guo S R , et al . Construction of double network hydrogels and their application in biomedicine field [J ] . Engineering Plastics Application , 2024 , 52 ( 12 ): 165 - 170 .
Wang Z J , Jiang J L , Mu Q F , et al . Azo-crosslinked double-network hydrogels enabling highly efficient mechanoradical generation [J ] . Journal of the American Chemical Society , 2022 , 144 ( 7 ): 3154 - 3161 .
Hua Y J , Xia H T , Jia L T , et al . Ultrafast, tough, and adhesive hydrogel based on hybrid photocrosslinking for articular cartilage repair in water-filled arthroscopy [J ] . Science Advances , 2021 , 7 ( 35 ): eabg0628 .
Jiang F , Chi Z , Ding Y Y , et al . Wound dressing hydrogel of Enteromorpha prolifera polysaccharide–polyacrylamide composite: a facile transformation of marine blooming into biomedical material [J ] . ACS Applied Materials & Interfaces , 2021 , 13 ( 12 ): 14530 - 14542 .
Lei H , Zhao J , Ma X X , et al . Antibacterial dual network hydrogels for sensing and human health monitoring [J ] . Advanced Healthcare Materials , 2021 , 10 ( 21 ): 2101089 .
Zhang J , Chen L D , Chen L Q , et al . Highly antifouling, biocompatible and tough double network hydrogel based on carboxybetaine-type zwitterionic polymer and alginate [J ] . Carbohydrate Polymers , 2021 , 257 : 117627 .
Tang L , Zhang D , Gong L , et al . Double-network physical cross-linking strategy to promote bulk mechanical and surface adhesive properties of hydrogels [J ] . Macromolecules , 2019 , 52 ( 24 ): 9512 - 9525 .
He P , Guo R S , Hu K , et al . Tough and super-stretchable conductive double network hydrogels with multiple sensations and moisture-electric generation [J ] . Chemical Engineering Journal , 2021 , 414 : 128726 .
Ghosh T , Das A K . Dynamic boronate esters cross-linked guanosine hydrogels: a promising biomaterial for emergent applications [J ] . Coordination Chemistry Reviews , 2023 , 488 : 215170 .
Cui C , Shao C Y , Meng L , et al . High-strength, self-adhesive, and strain-sensitive chitosan/poly(acrylic acid) double-network nanocomposite hydrogels fabricated by salt-soaking strategy for flexible sensors [J ] . ACS Applied Materials & Interfaces , 2019 , 11 ( 42 ): 39228 - 39237 .
Zhu H J , Zheng J , Oh X Y , et al . Nanoarchitecture-integrated hydrogel systems toward therapeutic applications [J ] . ACS Nano , 2023 , 17 ( 9 ): 7953 - 7978 .
Zhang Z Y , Hu Y , Ma H L , et al . MXene/gelatin/polyacrylamide nanocomposite double network hydrogel with improved mechanical and photothermal properties [J ] . Polymers , 2022 , 14 ( 23 ): 5247 .
Liu J , Jiang L , He S R , et al . Recent progress in PNIPAM-based multi-responsive actuators: a mini-review [J ] . Chemical Engineering Journal , 2022 , 433 : 133496 .
程倩 . 冠醚改性壳聚糖复合材料的制备及其选择性吸附锂离子的研究 [D ] . 常州 : 常州大学 , 2021 .
Cheng Q . Study on the preparation of crown ether modified chitosan composites and the selective separation of lithium ion [D ] . Changzhou : Changzhou University , 2021 .
Izatt R M . Charles J. Pedersen’s legacy to chemistry [J ] . Chemical Society Reviews , 2017 , 46 ( 9 ): 2380 - 2384 .
Ali M , Ahmed I , Ramirez P , et al . Lithium ion recognition with nanofluidic diodes through host–guest complexation in confined geometries [J ] . Analytical Chemistry , 2018 , 90 ( 11 ): 6820 - 6826 .
Ma J G , Zhang Y P , Ouyang J X , et al . A facile preparation of dicyclohexano-18-crown-6 ether impregnated titanate nanotubes for strontium removal from acidic solution [J ] . Solid State Sciences , 2019 , 90 : 49 - 55 .
Coman A G , Stavarache C , Paun A , et al . A novel profluorescent paramagnetic diaza-crown ether: synthesis, characterization and alkaline metal-ion complexation [J ] . RSC Advances , 2019 , 9 ( 11 ): 6078 - 6083 .
刘思琪 , 曹朋飞 , 彭静 , 等 . 含冠醚基团水凝胶的辐射制备及其对锂离子的响应性能 [J ] . 辐射研究与辐射工艺学报 , 2017 , 35 ( 4 ): 40 - 45 .
Liu S Q , Cao P F , Peng J , et al . Radiation synthesis of lithium-ion-response hydrogels based on crown ether [J ] . Journal of Radiation Research and Radiation Processing , 2017 , 35 ( 4 ): 40 - 45 .
Liu X W , Zhu S , Wu S R , et al . Response behavior of ion-sensitive hydrogel based on crown ether [J ] . Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2013 , 417 : 140 - 145 .
Li E Z , Yuan Y S , Li Z L , et al . Precisive lithium extraction based on synergistic effect of water-rich 3D network in hydrogel and covalent grafted crown ether [J ] . Desalination , 2026 , 617 : 119411 .
Knapik E , Rotko G , Piotrowski M , et al . Crown ether-grafted graphene oxide-based materials—synthesis, characterization and study of lithium adsorption from complex brine [J ] . Materials , 2024 , 17 ( 24 ): 6269 .
Wu Y B , Wei Y , Guo X S , et al . Ultrahigh-selective lithium adsorption from low-quality lithium sources via oxygen-enhanced fluorine-lithium affinity [J ] . Resources, Conservation and Recycling , 2026 , 227 : 108780 .
Fang Z Y , Luo F , Fu K X , et al . Significance of fluorine chain-driven active sites for enhanced selective lithium recovery [J ] . Advanced Functional Materials , 2026 , 36 ( 10 ): e18476 .
Liu G , Zhao Z W , Ghahreman A . Novel approaches for lithium extraction from salt-lake brines: a review [J ] . Hydrometallurgy , 2019 , 187 : 81 - 100 .
Li Y , Yang Z , Ma P H . Research progress on new types of H 2 TiO 3 lithium-ion sieves: a review [J ] . Metals , 2023 , 13 ( 5 ): 977 .
Weng D , Duan H Y , Hou Y C , et al . Introduction of manganese based lithium-ion sieve-a review [J ] . Progress in Natural Science: Materials International , 2020 , 30 ( 2 ): 139 - 152 .
Liu M X , Wu D , Qin D L , et al . Spray-drying assisted layer-structured H 2 TiO 3 ion sieve synthesis and lithium adsorption performance [J ] . Chinese Journal of Chemical Engineering , 2022 , 45 : 258 - 267 .
Disu B , Rafati R , Sharifi Haddad A , et al . Maximizing lithium adsorption and selectivity on manganese-based ion sieves: effects of thermal treatment, acid content, and operating conditions [J ] . Industrial & Engineering Chemistry Research , 2025 , 64 ( 24 ): 11961 - 11980 .
侯旭东 . 锂离子筛基纳米复合水凝胶界面结构调控与提锂研究 [D ] . 太原 : 太原理工大学 , 2024 .
Hou X D . Interface structure regulation of lithium ion-sieve nanocomposite hydrogel for lithium extraction [D ] . Taiyuan : Taiyuan University of Technology , 2024 .
Zhang X S , Wu J X , He Y , et al . Porous polyvinyl alcohol/polyacrylamide hydrogels loaded with HTO lithium-ion sieves for highly rapid and efficient Li + extraction [J ] . Desalination , 2024 , 580 : 117587 .
Li C W , Zhan H L , Qiao Y J , et al . Constructing porous hydrophilic HMO/CTA@PDA composite hydrogel for super-high and ultrafast extraction of lithium ions [J ] . Desalination , 2025 , 593 : 118216 .
Liu S K , Cao C L , Li H L , et al . In-situ pH regulation of biomass-based hydrogel composite: a green approach to efficient lithium ion capture from salt lake brine [J ] . Chemical Engineering Journal , 2025 , 523 : 168426 .
Meng Z X , Wang M L , Cao X , et al . Highly flexible interconnected Li + ion-sieve porous hydrogels with self-regulating nanonetwork structure for marine lithiu m recovery [J ] . Chemical Engineering Journal , 2022 , 445 : 136780 .
Xiao J L , Sun S Y , Song X F , et al . Lithium ion recovery from brine using granulated polyacrylamide–MnO 2 ion-sieve [J ] . Chemical Engineering Journal , 2015 , 279 : 659 - 666 .
Zhang Y J , Wang Y , Guo L , et al . Lithium-ion-sieve hydrogel based on aluminum doping with high stretchability, strong adsorption capacity and low dissolution loss [J ] . Gels , 2024 , 10 ( 11 ): 710 .
Jiang Y M , Liu R R , Liu M J , et al . Yttrium doping Li + ion-sieve porous fluorinated hydrogel adsorbents for enhanced selective lithium recovery [J ] . Separation and Purification Technology , 2025 , 377 : 134442 .
Krishnan M R , Alsharaeh E H . Efficient lithium-ion recovery using selective organically crosslinked HTO-polyacrylamide-graphene nanocomposite hydrogels [J ] . Cell Reports Physical Science , 2025 , 6 ( 12 ): 102984 .
Ma Y , Liu Y Z , Li J Y , et al . Performance study of lithium ion sieve composite in high gravity for Li + adsorption [J ] . Chemical Engineering and Processing - Process Intensification , 2025 , 208 : 110079 .
Cui J S , Xu H X , Ding Y F , et al . Recovery of lithium using H 4 Mn 3.5 Ti 1.5 O 12 /reduced graphene oxide/polyacrylamide composite hydrogel from brine by Ads-ESIX process [J ] . Chinese Journal of Chemical Engineering , 2022 , 44 : 20 - 28 .
Liu B W , Yang Y W , Zhou M , et al . Solar-driven dual-functional adsorvaporator enabling efficient lithium concentration and freshwater generation with life cycle assessment evaluation [J ] . Small , 2025 , 21 ( 32 ): 2505347 .
Zhu Z Z , Li H Y , Wang Z Q , et al . Synergistic photothermal-adsorption of porous hydrogel system for simultaneous Li + extraction and interface evaporation [J ] . Chemical Engineering Science , 2025 , 318 : 122145 .
Zhou Z K , Wang H N , Li Q Q , et al . Solar-driven pump for simultaneous lithium capture and freshwater generation from salt-lake brine [J ] . Journal of Materials Science & Technology , 2026 , 254 : 299 - 306 .
Han Z H , Qi S M , Fu M T , et al . A scalable route to constructing hydrogel-encapsulated lithium-ion sieves-based photothermal fabric adsorbent for solar-enhanced lithium extraction from seawater [J ] . Advanced Functional Materials , 2025 , 35 ( 25 ): 2422901 .
He H B , Ma Y , Zhu Q K , et al . Solar-driven janus fabric evaporator: efficient desalination and selective lithium enrichment [J ] . Chemical Engineering Journal , 2025 , 519 : 165433 .
Yu Z , Mao Z Y , Guo S , et al . Adsorption-responsive bionic photothermal ion pump for reversible seawater lithium extraction [J ] . Nature Communications , 2025 , 16 : 8825 .
Yang G Y , Yin Z Z , Han X Y , et al . A scalable, bionic gemini-structured solar evaporator enabling ultrahigh-efficiency and selective lithium extraction [J ] . Advanced Functional Materials , 2026 , 36 ( 26 ): e27626 .
Wang X Y , Ma B , Liu L N , et al . The recent advances and modification strategies of Li/Al-LDHs toward lithium extraction [J ] . Desalination , 2026 , 618 : 119499 .
Thiel J P , Chiang C K , Poeppelmeier K R . Structure of lithium aluminum hydroxide dihydrate (LiAl 2 (OH) 7 .2H 2 O) [J ] . Chemistry of Materials , 1993 , 5 ( 3 ): 297 - 304 .
Graham T R , Hu J Z , Zhang X , et al . Unraveling gibbsite transformation pathways into LiAl-LDH in concentrated lithium hydroxide [J ] . Inorganic Chemistry , 2019 , 58 ( 18 ): 12385 - 12394 .
Stepanova L N , Belskaya O B , Vasilevich А V , et al . The study of structural, textural and basic properties of MgAl- and LiAl-LDH prepared by mechanochemical method [J ] . Catalysis Today , 2020 , 357 : 638 - 645 .
孟盖军 , 黄安 , 方明 , 等 . LiAlFe-LDH/石墨烯/海藻酸钠复合水凝胶的制备及锂吸附性能研究 [J ] . 化工新型材料 , 2022 , 50 ( 5 ): 118 - 125 .
Meng G J , Huang A , Fang M , et al . Preparation and adsorption performance of LiAlFe-LDH/graphene/sodium alginate composite hydrogel on Li + [J ] . New Chemical Materials , 2022 , 50 ( 5 ): 118 - 125 .
Zhao L Q , Zhang X J , Liu K Y , et al . Convenient synthesis of granulated Li/Al-layered double hydroxides/chitosan composite adsorbents for lithium extraction from simulated brine with a high Mg 2+ /Li + ratio [J ] . Chemical Engineering Journal , 2024 , 501 : 157780 .
Miao Q S , Jiang L R , Yang J , et al . MOF/hydrogel composite-based adsorbents for water treatment: a review [J ] . Journal of Water Process Engineering , 2022 , 50 : 103348 .
Yilmaz G , Peh S B , Zhao D , et al . Atomic- and molecular-level design of functional metal–organic frameworks (MOFs) and derivatives for energy and environmental applications [J ] . Advanced Science , 2019 , 6 ( 21 ): 1901129 .
Ma S H , Yu B , Pei X W , et al . Structural hydrogels [J ] . Polymer , 2016 , 98 : 516 - 535 .
Park S H , Kim K , Lim J H , et al . Selective lithium and magnesium adsorption by phosphonate metal-organic framework-incorporated alginate hydrogel inspired from lithium adsorption characteristics of brown algae [J ] . Separation and Purification Technology , 2019 , 212 : 611 - 618 .
Qiu Y B , Gao Y D , Liu J R , et al . In-situ construction of ZIF-embedded hydrogel electro-driven membranes for lithium selectivity [J ] . Journal of Membrane Science , 2026 , 741 : 125043 .
Solangi N H , Karri R R , Mazari S A , et al . MXene as emerging material for photocatalytic degradation of environmental pollutants [J ] . Coordination Chemistry Reviews , 2023 , 477 : 214965 .
曾广勇 , 赵思邈 , 王宏山 , 等 . 二维材料在盐湖提锂领域的研究进展 [J ] . 复合材料学报 , 2023 , 40 ( 6 ): 3125 - 3135 .
Zeng G Y , Zhao S M , Wang H S , et al . Research progress of two-dimensional materials in the field of lithium extraction from salt lake [J ] . Acta Materiae Compositae Sinica , 2023 , 40 ( 6 ): 3125 - 3135 .
Abdelrahman N S , Hong S , Choi D S , et al . Interfacial adsorption and recovery of Lithium ions using sulfonated graphene oxide and Ti 3 C 2 T x MXene nanocomposite hydrogels [J ] . Desalination , 2025 , 606 : 118766 .
Song Z C , Wang C J , Wang Q Y , et al . Construction of gradient hydrogel-based lithium ion channels enhanced by Hofmeister effects [J ] . Chemical Engineering Journal , 2025 , 521 : 166653 .
Mirmohammadi S A , Kagayama T , Gotoh T , et al . Dual-component thermoresponsive anionic-cationic hydrogel networks: molecular interactions governing lithium ion adsorption and desorption [J ] . Journal of Molecular Liquids , 2026 , 449 : 129414 .
Zhou J Y , Li X K , Xie W , et al . Realizing efficient solar evaporation and rapid lithium sorption by the halloysite nanotubes-based hydrogel [J ] . Journal of Cleaner Production , 2024 , 437 : 140523 .
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