1.西安交通大学能源与动力工程学院,陕西 西安 710049
2.西安交通大学化学学院,陕西 西安 710049
周辛梓(1996—),男,博士研究生,xinzizhou@stu.xjtu.edu.cn
孟现阳(1978—),男,博士,教授,xymeng@mail.xjtu.edu.cn
收稿:2026-02-12,
修回:2026-07-08,
录用:2026-07-09,
移动端阅览
周辛梓, 谢锦涛, 季桓旭, 等. 仲氢和标准氢的黏度与导热系数的研究综述[J/OL]. 化工学报, 2026.
ZHOU Xinzi, XIE Jintao, JI Huanxu, et al. A survey of viscosity and thermal conductivity of parahydrogen and normal hydrogen[J/OL]. CIESC Journal, 2026.
周辛梓, 谢锦涛, 季桓旭, 等. 仲氢和标准氢的黏度与导热系数的研究综述[J/OL]. 化工学报, 2026. DOI: 10.11949/0438-1157.20260215.
ZHOU Xinzi, XIE Jintao, JI Huanxu, et al. A survey of viscosity and thermal conductivity of parahydrogen and normal hydrogen[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260215.
氢的热物理性质研究是其生产、储存和应用的基础。本研究调研了自1900年至今的仲氢和标准氢的黏度和导热系数研究,梳理了测量技术、实验数据现状及模型开发进展。结果表明,当前氢迁移性质研究存在早期实验技术不成熟、完整实验信息缺乏和测量不确定度被低估等问题。低温区不同研究结果差异显著。仲氢与标准氢的实际差别在某些温区难以与实验测量误差有效区分。受限于实验研究现状,现有模型预测性能在低温区普遍降低。尽管近年来已有新的实验及模型研究报道,但低温热氢物性的探索仍显不足。本研究工作剖析了目前氢黏度与导热系数研究中的关键问题,为未来实验测量及模型开发提供参考。
The thermophysical properties of hydrogen have an impact on its production
storage
and utilization. A literature survey from 1900 has been conducted on the viscosity and thermal conductivity of hydrogen
encompassing the primary measurement method
experimental research status and model development progress. The results show several challenges in current research
including immature early experimental techniques
incomplete experimental information
and an underestimation of measurement uncertainties. The results of different studies in low-temperature regions vary significantly. The actual differences between parahydrogen and normal hydrogen are difficult to distinguish from measurement errors within specific temperature ranges. Constrained by the state of experimental research
the predictive performance of existing models generally decreases in low-temperature regions. Although novel experimental and modelling studies have been reported recently
research on the thermophysical properties of hydrogen at low temperatures remains inadequate. The present work analyzes the key issues in current research on hydrogen viscosity and thermal conductivity
providing a reference for future experimental measurements and model development.
Li F Y , Ma W , Zhang X . Database of thermophysical properties of H 2 /CO 2 /CO/CH 4 /H 2 O mixtures [J ] . International Journal of Hydrogen Energy , 2023 , 48 ( 44 ): 16923 - 16935 .
Haynes W M , Diller D E , Roder H M . Transport properties of fluids of cryogenic interest [J ] . Cryogenics , 1987 , 27 ( 7 ): 348 - 360 .
da Silva Falcão B , Jeong K , Al Ghafri S , et al . Ortho-to para-hydrogen catalytic conversion kinetics [J ] . International Journal of Hydrogen Energy , 2024 , 62 : 345 - 351 .
Leachman J W , Jacobsen R T , Penoncello S G , et al . Fundamental equations of state for parahydrogen, normal hydrogen, and orthohydrogen [J ] . Journal of Physical and Chemical Reference Data , 2009 , 38 ( 3 ): 721 - 748 .
Leachman J W , Jacobsen R T , Penoncello S G , et al . Current status of transport properties of hydrogen [J ] . International Journal of Thermophysics , 2007 , 28 ( 3 ): 773 - 795 .
Welber B , Quimby S L . Measurement of the product of viscosity and density of liquid helium with a torsional crystal [J ] . Physical Review , 1957 , 107 ( 3 ): 645 .
Diller D E . Measurements of the viscosity of parahydrogen [J ] . The Journal of Chemical Physics , 1965 , 42 ( 6 ): 2089 - 2100 .
Konareva V G , Rudenko N S . Measurement of the viscosity of hydrogen isotopes along a liquid-vapor equilibrium curve [J ] . Zhurnal Fizicheskoi Khimii , 1967 , 41 ( 9 ): 2387 - 2388 .
Kestin J , Wakeham W A . Transport Properties of Fluids: Thermal Conductivity, Viscosity and Diffusion Coefficient: thermal conductivity, viscosity & diffusion coefficient [M ] . New York : Hemisphere Publishing Corporation , 1988 .
Wakeham W A , Richardson S M . The torsional quartz-crystal viscometer [J ] . International Journal of Thermophysics , 2021 , 42 ( 8 ): 120 .
Wakeham W A , Nagashima A , Sengers J V . Measurement of the Transport Properties of Fluids [M ] . Oxford : Blackwell Scientific Publications , 1991 .
Poiseuille J L M . Recherches Expérimentales Sur Le Mouvement des Liquides Dans Les Tubes de Très-Petits Diamètres [M ] . Paris : Imprimerie Royale de France , 1844 : 1041 - 1048 .
Berg R F . Simple flow meter and viscometer of high accuracy for gases [J ] . Metrologia , 2005 , 42 ( 1 ): 11 - 23 .
Johns H E . The viscosity of liquid hydrogen [J ] . Canadian Journal of Research , 1939 , 17 a( 12 ): 221 - 226 .
Rudenko N S , Konareva V G . Viscosity of liquid hydrogen and deuterium [J ] . Zhurnal Fizicheskoi Khimii , 1963 , 37 ( 12 ): 1493 - 1496 .
Owuna F J , Chapoy A , Ahmadi P , et al . Viscosity of hydrogen and methane blends: experimental and modelling investigations [J ] . International Journal of Thermophysics , 2024 , 45 ( 8 ): 119 .
Kuss E . High pressure research Ⅱ: The viscosity of compressed gases [J ] . Zeitschrift für Angewandte Physik , 1952 , 4 ( 6 ): 203 - 207 .
Michels A , Schipper A C J , Rintoul W H . The viscosity of hydrogen and deuterium at pressures up to 2000 atmospheres [J ] . Physica , 1953 , 19 ( 1/2/3/4/5/6/7/8/9/10/11/12 ): 1011 - 1028 .
Golubev I F , Shepeleva R I . Viscosity of hydrogen at low temperatures and high pressures [J ] . Gazovaya Promyshlennost , 1966 , 11 ( 4 ): 54 - 58 .
Chuang S Y , Chappelear P S , Kobayashi R . Viscosity of methane, hydrogen, and four mixtures of methane and hydrogen from-100. degree. C to 0. degree. C at high pressures [J ] . Journal of Chemical & Engineering Data , 1976 , 21 ( 4 ): 403 - 411 .
Yusibani E , Nagahama Y , Kohno M , et al . A capillary tube viscometer designed for measurements of hydrogen gas viscosity at high pressure and high temperature [J ] . International Journal of Thermophysics , 2011 , 32 ( 6 ): 1111 - 1124 .
Nabizadeh H , Mayinger F . Viscosity of binary mixtures of hydrogen and natural gas (hythane) in the gaseous phase [J ] . High Temperatures-High Pressures , 1999 , 31 ( 6 ): 601 - 612 .
Breitenbach P . Ueber die innere Reibung der Gase und deren Aenderung mit der Temperatur [J ] . Annalen der Physik , 1901 , 310 ( 5 ): 166 - 169 .
Markowski H . Die innere Reibung von Sauerstoff, Wasserstoff, chemischem und atmosphärischem Stickstoff und ihre Äenderung mit der Temperatur [J ] . Annalen der Physik , 1904 , 319 ( 9 ): 742 - 755 .
Schmitt K . Über die innere Reibung einiger Gase und Gasgemische bei verschiedenen Temperaturen [J ] . Annalen der Physik , 1909 , 335 ( 12 ): 393 - 410 .
Dorsman C , Kamerlingh Onnes H , Weber S . Investigation on the viscosity of gases at low temperatures. I. Hydrogen [J ] . Koninklijke Nederlandse Akademie van Wetenschappen Proceedings Series B Physical Sciences , 1913 , 15 : 1386 - 1396 .
Vogel H . Über die Viskosität einiger Gase und ihre Temperaturabhängigkeit bei tiefen Temperaturen [J ] . Annalen der Physik , 1914 , 348 ( 8 ): 1235 - 1272 .
Nicaise C , Verschaffelt J E . The viscosity of liquefied gases. IX. Preliminary determination of the viscosity of liquid hydrogen [J ] . Koninklijke Nederlandse Akademie van Wetenschappen Proceedings Series B Physical Sciences , 1917 , 19 : 1084 - 1088 .
Yen K L . LVIII. An absolute determination of the coefficients of viscosity of hydrogen, nitrogen, and oxygen [J ] . The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science , 1919 , 38 ( 227 ): 582 - 596 .
Ishida Y . Determination of viscosities and of the Stokes-Millikan law constant by the oil-drop method [J ] . Physical Review , 1923 , 21 ( 5 ): 550 - 563 .
Klemenc A , Remi W . Experimentelle Untersuchung über die Koeffizienten der inneren Reibung von Stickoxyd und Propan und deren Mischungen mit Wasserstoff [J ] . Monatshefte für Chemie und Verwandte Teile Anderer Wissenschaften , 1923 , 44 ( 7 ): 307 - 316 .
Trautz M , Baumann P B . Die reibung, Wärmeleitung und diffusion in gasmischungen. II. die reibung von H 2 N 2 -und H 2 CO-gemischen [J ] . Annalen der Physik , 1929 , 394 ( 6 ): 733 - 736 .
Trautz M , Ludewigs W . Die reibung, Wärmeleitung und diffusion in gasmischungen VI. reibungsbestimmung an reinen gasen durch direkte messung und durch solche an ihren gemischen [J ] . Annalen der Physik , 1929 , 395 ( 3 ): 409 - 428 .
Trautz M , Stauf F W . Dié Reibung, Wärmeleitung und diffusion in gasmischungen. III.die reibung von H 2 -C 2 H 4 ‐ge mischen [J ] . Annalen der Physik , 1929 , 394 ( 6 ): 737 - 742 .
Trautz M , Binkele H E . Die Reibung, Wärmeleitung und diffusion in gasmischungen. VIII. die reibung des H 2 , He, Ne, Ar und ihrer binären gemische [J ] . Annalen der Physik , 1930 , 397 ( 5 ): 561 - 580 .
Trautz M , Melster A . Die reibung, Wärmeleitung und diffusion in gasmischungen Ⅺ. die reibung von H 2 , N 2 , CO, C 2 H 4 , O 2 und ihren binären gemischen [J ] . Annalen der Physik , 1930 , 399 ( 4 ): 409 - 426 .
Trautz M , Zink R . Die reibung, Wärmeleitung und diffusion in gasmischungen Ⅻ. gasreibung Bei höheren temperaturen [J ] . Annalen der Physik , 1930 , 399 ( 4 ): 427 - 452 .
Boyd J H . The viscosity of compressed gases [J ] . Physical Review , 1930 , 35 ( 10 ): 1284 - 1297 .
Trautz M , Kurz F . Die reibung, Wärmeleitung und diffusion in gasmischungen XV. die reibung von H 2 , N 2 O, CO 2 und C 3 H 8 und ihren binären gemischen [J ] . Annalen der Physik , 1931 , 401 ( 8 ): 981 - 1003 .
Trautz M , Heberling R . Die reibung, Wärmeleitung und diffusion in gasmischungen XVII. die reibung von NH 3 und seinen gemischen mit H 2 , N 2 , O 2 , C 2 H 4 [J ] . Annalen der Physik , 1931 , 402 ( 2 ): 155 - 177 .
Trautz M , Sorg K G . Die reibung, Wärmeleitung und diffusion in gasmischungen XVI. die reibung von H 2 , CH 4 , C 2 H 6 , C 3 H 8 und ihren binären gemischen [J ] . Annalen der Physik , 1931 , 402 ( 1 ): 81 - 96 .
Sutherland B P , Maass O . Measurement of the viscosity of gases over a large temperature range [J ] . Canadian Journal of Research , 1932 , 6 ( 4 ): 428 - 443 .
Trautz M , Husseini I . Die reibung, Wärmeleitung und diffusion in gasmischungen. XXVI. die innere reibung von propylen und β-butylen und von ihren mischungen mit He oder H 2 [J ] . Annalen der Physik , 1934 , 412 ( 2 ): 121 - 126 .
Trautz M , Zimmermann H . Die reibung, Wärmeleitung und diffusion von gasmischungen XXX. die innere reibung bei tiefen temperaturen von wasserstoff, helium und neon und binären gemischen davon bis 90, 0° abs. herab [J ] . Annalen der Physik , 1935 , 414 ( 2 ): 189 - 194 .
Van Cleave A B , Maass O . The molecular diameter of deuterium as determined by viscosity measurements [J ] . Canadian Journal of Research , 1935 , 12 ( 1 ): 57 - 62 .
Adzumi H . Studies on the flow of gaseous mixtures through capillaries. Ⅰ the viscosity of binary gaseous mixtures [J ] . Bulletin of the Chemical Society of Japan , 1937 , 12 ( 5 ): 199 - 226 .
Adzumi H . Studies on the flow of gaseous mixtures through capillaries. III. the flow of gaseous mixtu res at medium pressures [J ] . Bulletin of the Chemical Society of Japan , 1937 , 12 ( 6 ): 292 - 303 .
van Itterbeek A , Claes A . Viscosity of light hydrogen gas and deuterium between 293° K. and 14° K [J ] . Nature , 1938 , 142 ( 3600 ): 793 - 794 .
van Itterbeek A , Claes A . Measurements on the viscosity of hydrogen-and deuterium gas between 293° k and 14° k [J ] . Physica , 1938 , 5 ( 10 ): 938 - 944 .
Keesom W H , Macwood G E . The viscosity of hydrogen vapour [J ] . Physica , 1938 , 5 ( 8 ): 749 - 752 .
van Itterbeek A , van Paemel O . Measurements on the viscosity of neon, hydrogen, deuterium and helium as a function of the temperature, between room temperature and liquid hydrogen temperatures [J ] . Physica , 1940 , 7 ( 3 ): 265 - 272 .
van Itterbeek A , van Paemel O . Measurements on the viscosity of gases for low pressures at room temperature and at low temperatures [J ] . Physica , 1940 , 7 ( 3 ): 273 - 283 .
Keesom W H , Keesom P H . The viscosity of hydrogen vapour [J ] . Physica , 1940 , 7 ( 1 ): 29 - 32 .
Johnston H L , McCloskey K E . Viscosities of several common gases between 90°K. and room temperature [J ] . The Journal of Physical Chemistry , 1940 , 44 ( 9 ): 1038 - 1058 .
van Itterbeek A , van Paemel O . Bestimmung der inneren reibung vom flüssigen wasserstoff und deuterium [J ] . Physica , 1941 , 8 ( 1 ): 133 - 143 .
Wobser R , Müller F . Die innere reibung von gasen und dämpfen und ihre messung im Höppler-viskosimeter [J ] . Kolloid-Beihefte , 1941 , 52 ( 6 ): 165 .
Buddenberg J W , Wilke C R . Viscosities of some mixed gases [J ] . The Journal of Physical Chemistry , 1951 , 55 ( 9 ): 1491 - 1498 .
Kompaneets V Y . Experimental investigation of the viscosity of gases and gaseous mixtures at high temperatures [G ] // Collection of Scientific Works . Leningrad: Leningrad Institute of Agricultural Mechanization, 1953 , 9 : 113 .
Kestin J , Pilarczyk K . Measurement of the viscosity of five gases at elevated pressures by the oscillating-disk method [J ] . Journal of Fluids Engineering , 1954 , 76 ( 6 ): 987 - 997 .
Rietveld A O , van Itterbeek A . Viscosity of mixtures of H 2 and HD between 300 and 14 °K [J ] . Physica , 1957 , 23 ( 6/7/8/9/10 ): 838 - 842 .
Kestin J , Wang H E . The viscosity of five gases: a re-evaluation [J ] . Journal of Fluids Engineering , 1958 , 80 ( 1 ): 11 - 17 .
Coremans J M J , van Itterbeek A , Beenakker J J M , et al . The viscosity of gaseous He, Ne, H 2 and D 2 below 80°K [J ] . Physica , 1958 , 24 ( 6/7/8/9/10 ): 557 - 576 .
Rietveld A O , van Itterbeek A , Velds C A . Viscosity of binary mixtures of hydrogen isotopes and mixtures of He and Ne [J ] . Physica , 1959 , 25 ( 1/2/3/4/5/6 ): 205 - 216 .
Kestin J , Leidenfrost W . An absolute determination of the viscosity of eleven gases over a range of pressures [J ] . Physica , 1959 , 25 ( 7/8/9/10/11/12 ): 1033 - 1062 .
Barua A K , Afzal M , Flynn G P , et al . Viscosity of hydrogen, deuterium, methane, and carbon monoxide from: 50°to 150°C below 200 atmospheres [J ] . The Journal of Chemical Physics , 1964 , 41 ( 2 ): 374 - 378 .
Kestin J , Nagashima A . Viscosity of the isotopes of hydrogen and their intermolecular force potentials [J ] . The Physics of Fluids , 1964 , 7 ( 5 ): 730 - 734 .
Menabde N E . Viscosity coefficient of hydrogen (H 2 , D 2 ), neon (Ne 20 , Ne 22 ) and helium (He 3 ) isotopes in the temperature range −195 to +25°C [J ] . Atomic Energy , 1965 , 19 ( 5 ): 1421 - 1422 .
Tsederberg N V , Popov V N , Andreev I Ⅰ . Experimental investigation of the viscosity of hydrogen [J ] . Teploenergetika , 1965 , 12 ( 4 ): 84 - 85 .
Kestin J , Yata J . Viscosity and diffusion coefficient of six binary mixtures [J ] . The Journal of Chemical Physics , 1968 , 49 ( 11 ): 4780 - 4791 .
Rudenko N S , Sliusar V P . Viscosity of hydrogen at constant density in the temperature range from 16.6 to 300 K [J ] . Ukrainian Journal of Physics , 1968 , 13 ( 6 ): 917 - 922 .
Gracki J A , Flynn G P , Ross J . Viscosity of nitrogen, helium, hydrogen, and argon from– 100 to 25℃ up to 150–250 atm [J ] . The Journal of Chemical Physics , 1969 , 51 ( 9 ): 3856 - 3863 .
Guevara F A , McInteer B B , Wageman W E . High-temperature viscosity ratios for hydrogen, helium, argon, and nitrogen [J ] . The Physics of Fluids , 1969 , 12 ( 12 ): 2493 - 2505 .
Kestin J , Ro S T , Wakeham W A . Reference values of the viscosity of twelve gases at 25℃ [J ] . Transactions of the Faraday Society , 1971 , 67 : 2308 - 2313 .
Carey C , Bradshaw J , Lin E , et al . Experimental determination of gas properties at high temperatures and/or pressure: AD77977 [R ] . Waltham, USA : Panametrics Inc. , 1974 .
Clifford A A , Kestin J , Wakeham W A . The viscosity of mixtures of hydrogen with three noble gases [J ] . Berichte der Bunsengesellschaft für Physikalische Chemie , 1981 , 85 ( 5 ): 385 - 388 .
Lukin V I , Ivakin B A , Suetin P . E. Temperature dependence of the viscosity coefficients of some gases [J ] . Soviet physics - Technical physics , 1983 , 28 ( 5 ): 597 .
Mal’tsev V A , Nerushev O A , Novopashin S A , et al . Viscosity of H 2 –CO 2 mixtures at (500, 800, and 1100) K [J ] . Journal of Chemical & Engineering Data , 2004 , 49 ( 3 ): 684 - 687 .
May E F , Berg R F , Moldover M R . Reference viscosities of H 2 , CH 4 , Ar, and Xe at low densities [J ] . International Journal of Thermophysics , 2007 , 28 ( 4 ): 1085 - 1110 .
Mehl J B , Huber M L , Harvey A H . Ab initio transport coefficients of gaseous hydrogen [J ] . International Journal of Thermophysics , 2010 , 31 ( 4/5 ): 740 - 755 .
Sakoda N , Hisatsugu T , Furusato K , et al . Viscosity measurements of hydrogen at high temperatures up to 573K by a curved vibrating wire method [J ] . The Journal of Chemical Thermodynamics , 2015 , 89 : 22 - 26 .
Cheng S Y , Shang F , Ma W G , et al . Viscosity Measurements of the H 2 –CO 2 , H 2 –CO 2 –CH 4 , and H 2 –H 2 O mixtures and the H 2 –CO 2 –CH 4 –CO–H 2 O system at 280–924 K and 0.7–33.1 MPa with a capillary apparatus with a capillary apparatus [J ] . Journal of Chemical & Engineering Data , 2020 , 65 ( 8 ): 3834 - 3847 .
Betken B , Austegard A , Finotti F , et al . Measurements of the viscosity of hydrogen and a (hydrogen+ methane) mixture with a two-capillary viscometer [J ] . International Journal of Thermophysics , 2024 , 45 ( 4 ): 60 .
Muzny C D , Huber M L , Kazakov A F . Correlation for the viscosity of normal hydrogen obtained from symbolic regression [J ] . Journal of Chemical & Engineering Data , 2013 , 58 ( 4 ): 969 - 979 .
McCarty R D , Weber L A . Thermophysical Properties of Parahydrogen from the Freezing Liquid Line to 5000 R for Pressures to 10,000 Psia [M ] . Washington, DC : US Government Printing Office , 1972 .
Hanley H J M , McCarty R D , Cohen E G D . Analysis of the transport coefficients for simple dense fluid: Application of the modified Enskog theory [J ] . Physica , 1972 , 60 ( 2 ): 322 - 356 .
Vargaftik N B , Vinogradov Y K , Yargin V S . Handbook of Physical Properties of Liquids and Gases [M ] . New York : Begall house, inc. , 1996 .
Lemmon E W , Bell I H , Huber M L , et al . NIST Standard Reference Database 23: Reference Fluid Thermodynamic and Transport Properties-REFPROP, Version 10.0 [DS/OL ] . Gaithersburg: National Institute of Standards and Technology , 2018 .
Yusibani E , Woodfield P L , Shinzato K , et al . Prediction of hydrogen gas viscosity at high pressure and high temperature [J ] . Netsu Bussei , 2010 , 24 ( 1 ): 21 - 27 .
Vogel E , Küchenmeister C , Bich E , et al . Reference correlation of the viscosity of propane [J ] . Journal of Physical and Chemical Reference Data , 1998 , 27 ( 5 ): 947 - 970 .
Wei C , Jafari Raad S M , Leonenko Y , et al . Correlations for prediction of hydrogen gas viscosity and density for production, transportation, storage, and utilization applications [J ] . International Journal of Hydrogen Energy , 2023 , 48 ( 89 ): 34930 - 34944 .
Zéberg-Mikkelsen C K , Quiñones-Cisneros S E , Stenby E H . Viscosity prediction of hydrogen+ natural gas mixtures (hythane) [J ] . Industrial & Engineering Chemistry Research , 2001 , 40 ( 13 ): 2966 - 2970 .
Yang X X , Xiao X , Thol M , et al . Linking viscosity to equations of state using residual entropy scaling theory [J ] . International Journal of Thermophysics , 2022 , 43 ( 12 ): 183 .
Heidaryan E , Aryana S A . Empirical correlations for density, viscosity, and thermal conductivity of pure gaseous hydrogen [J ] . Advances in Geo-Energy Research , 2024 , 11 ( 1 ): 54 - 73 .
Assael M J , Wakeham W A . Thermal conductivity of four polyatomic gases [J ] . Journal of the Chemical Society , Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1981 , 77 ( 3 ): 697 - 707 .
Mustafa M , Ross M , Trengove R D , et al . Absolute measurement of the thermal conductivity of helium and hydrogen [J ] . Physica A: Statistical Mechanics and its Applications , 1987 , 141 ( 1 ): 233 - 248 .
Powers R W , Mattox R W , Johnston H L . Thermal conductivity of condensed gases. II. the thermal conductivities of liquid normal and of liquid parahydrogen from 15 to 27°K [J ] . Journal of the American Chemical Society , 1954 , 76 ( 23 ): 5972 - 5973 .
Dwyer R F , Cook G A , Berwaldt O E . The thermal conductivity of solid and liquid parahydrogen [J ] . Journal of Chemical & Engineering Data , 1966 , 11 ( 3 ): 351 - 353 .
Roder H M , Diller D E . Thermal conductivity of gaseous and liquid hydrogen [J ] . The Journal of Chemical Physics , 1970 , 52 ( 11 ): 5928 - 5949 .
Roder H M . Experimental thermal conductivity values for hydrogen, methane, ethane and propane: NBSIR 84-3006 [R ] . Gaithersburg : National Institute of Standards and Technology , 1984 .
Eucken A . On the temperature dependence of the thermal conductivity of several gases [J ] . Physikalische Zeitschrift , 1911 , 12 : 1101 - 1107 .
Eucken A . On the thermal conductivity, specific heat, and viscosity of gases [J ] . Physikalische Zeitschrift , 1913 , 14 : 324 - 332 .
Weber S . Untersuchungen über die Wärmeleitfähigkeit der gase. II [J ] . Annalen der Physik , 1917 , 359 ( 22 ): 437 - 462 .
Gregory H , Archer C T . Experimental determination of the thermal conductivities of gases [J ] . Proceedings of the Royal Society of London Series A, Containing Papers of a Mathematical and Physical Character , 1926 , 110 ( 753 ): 91 - 122 .
Schuster F . Studien zur zustandstheorie der materie. VII. Das Siedevolumen [J ] . Zeitschrift für Elektrochemie und Angewandte Physikalische Chemie , 1926 , 32 ( 11 ): 550 - 552 .
Kannuluik W G , Martin L H . The thermal conductivity of some gases at 0° C [J ] . Proceedings of the Royal Society of London Series A, Containing Papers of a Mathematical and Physical Character , 1934 , 144 ( 853 ): 496 - 513 .
Dickins B G . The effect of accommodation on heat conduction through gases [J ] . Proceedings of the Royal Society of London Series A, Containing Papers of a Mathematical and Physical Character , 1934 , 143 ( 850 ): 517 - 540 .
Gregory H S . The effect of temperature on the thermal conductivity and the accommodation coefficient of hydrogen [J ] . Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences , 1935 , 149 ( 866 ): 35 - 56 .
Nothdurft W . Zur absolutmessung des Wärmeleitvermögens von gasen [J ] . Annalen der Physik , 1936 , 420 ( 2 ): 137 - 156 .
Spencer-Gregory H , Dock E H . VIII.The effect of temperature on the thermal conductivity and the accommodation coefficient of hydrogen below0°C [J ] . The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science , 1938 , 25 ( 166 ): 129 - 147 .
Archer C T . Thermal conduction in hydrogen-deuterium mixtures [J ] . Proceedings of the Royal Society of London Series A Mathematical and Physical Sciences , 1938 , 165 ( 923 ): 474 - 485 .
Ubbink J B , de Haas W J . An apparatus to measure the specific thermal conductivity of gases at low temperatures [J ] . Physica , 1943 , 10 ( 7 ): 451 - 464 .
Johnston H L , Grilly E R . The thermal conductivites of eight common gases between 80° and 380° K [J ] . The Journal of Chemical Physics , 1946 , 14 ( 4 ): 233 - 238 .
Ubbink J B . Thermal conductivity of gaseous hydrogen and of gaseous deuterium [J ] . Physica , 1948 , 14 ( 2/3 ): 165 - 174 .
Stolyarove A , Ipatjer V V , Theodorowitsch V P . Determination of thermal conductivity coefficients of compressed gases (H 2 , N 2 , Air, CH 4 and CO 2 ) [J ] . Zhurnal Fizicheskoi Khimii , 1950 , 24 : 166 - 176 .
Lenoir J M , Comings E W . Thermal conductivity of gases. Measurement at high pressure [J ] . Chemical Engineering Progress , 1951 , 47 ( 5 ): 223 .
Keyes F G . Thermal conductivity of gases [J ] . Journal of Fluids Engineering , 1954 , 76 ( 5 ): 809 - 816 .
Salceanu C. ; Bojin S. On the thermal conductivity of gases and vapors [J ] . Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences , 1956 , 243 : 237 .
Chaikin A M , Markevich A M . The determination of the thermal conductivity coefficients of gases and gaseous mixtures [J ] . Zhurnal Fizicheskoi Khimii , 1958 , 32 ( 1 ): 116 - 120 .
Srivastava B N , Srivastava R C . Thermal conductivity and eucken correction for diatomic gases and binary gas mixtures [J ] . The Journal of Chemical Physics , 1959 , 30 ( 5 ): 1200 - 1205 .
Geier H , Schafer K . Heat Conductivity of Pure Gases and Gas Mixtures at 0 and 1200 degrees C [J ] . Allgemeine Wärmetechnik , 1961 , 10 ( 4 ): 70 .
Golubev I F , Kal’sina M V . Thermal conductivity of nitrogen and hydrogen at temperatures from 20 to-195 deg. C and pressures from 1 to 500 atmospheres [J ] . Gazovaya Promyshlennaya , 1964 , 9 ( 8 ): 41 - 43 .
Sherif I I . The thermal conductivity of hydrogen between 90° and 280°K [J ] . Applied Scientific Research , Section A, 1965 , 14 ( 1 ): 353 - 360 .
Hamrin C E , Thodos G . The thermal conductivity of hydrogen for pressures up to 660 atm and temperatures between 1.6 and 74.6℃ [J ] . Physica , 1966 , 32 ( 5 ): 918 - 932 .
Mukhopadhyay P , Das Gupta A , Barua A K . Thermal conductivity of hydrogen-nitrogen and hydrogen-carbon-dioxide gas mixtures [J ] . British Journal of Applied Physics , 1967 , 18 ( 9 ): 1301 .
Van Dael W , Cauwenbergh H . Measurements of the thermal conductivity of gases: I . Experimental method. Data for pure gases [J ] . Physica , 1968 , 40 ( 2 ): 165 - 172 .
Timrot D.L , Umanskii A S . Investigation of thermal conductivity of hydrogen and argon [J ] . Teplofizika vysokikh temperatur , 1966 , 4 ( 2 ): 289 - 292 .
Saxena S C , Saxena V K . Thermal conductivity data for hydrogen and deuterium in the range 100-1100 degrees C [J ] . Journal of Physics A: General Physics , 1970 , 3 ( 3 ): 309 - 320 .
Saxena S C , Gupta G P . Experimental data and procedures for predicting thermal conductivity of multicomponent mixtures of nonpolar gases [J ] . Journal of Chemical & Engineering Data , 1970 , 15 ( 1 ): 98 - 107 .
Saxena S C , Tondon P K . Experimental data and procedures for predicting thermal conductivity of binary mixtures of nonpolar gases [J ] . Journal of Chemical & Engineering Data , 1971 , 16 ( 2 ): 212 - 220 .
Le Neindre B . Contribution a l’etude experimentale de la conductivite thermique de quelques fluides a haute temperature et a haute pression [J ] . International Journal of Heat and Mass Transfer , 1972 , 15 ( 1 ): 1 - 24 .
Clifford A A , Colling L , Dickinson E , et al . Testing intermolecular potential functions using transport property data. Part 2: Thermal conductivities of mixtures of helium with the hydrogen isotopes [J ] . Journal of the Chemical Society , Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1975 , 71 : 1962 - 1977 .
Clifford A A , Kestin J , Wakeham W A . The Thermal conductivity of hydrogen, deuterium and their mixtures near room temperature within the pressure range 2 36 MPa [J ] . Berichte der Bunsengesellschaft für Physikalische Chemie , 1980 , 84 ( 1 ): 9 - 18 .
Clifford A A , Gray P , Johns A I , et al . Thermal conductivities of argon, nitrogen and hydrogen between 300 and 400 K and up to 25 MPa [J ] . Journal of the Chemical Society , Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1981 , 77 ( 11 ): 2679 - 2691 .
Hemminger W . The thermal conductivity of gases: Incorrect results due to desorbed air [J ] . International Journal of Thermophysics , 1987 , 8 ( 3 ): 317 - 333 .
Charignon T , Celik D , Hemmati A , et al . Thermal Conductivity of Subcooled Liquid Hydrogen [C ] //Advances in Cryogenic Engineering: Transactions of the Cryogenic Engineering Conference - CEC, Vol. 52 , Chattanooga (Tennessee). AIP , 2008 : 765 - 772 .
Moroe S , Woodfield P L , Kimura K , et al . Measurements of hydrogen thermal conductivity at high pressure and high temperature [J ] . International Journal of Thermophysics , 2011 , 32 ( 9 ): 1887 .
Liu Y H , Wang X W , Sheng B W , et al . Measurements of Hydrogen Thermal Conductivity for Pressures up to 37 MPa and Temperatures Between 69 and 150 K [J ] . Journal of Chemical & Engineering Data , 2026 , 71 ( 1 ): 63 - 71 .
Assael M J , Assael J M , Huber M L , Perkins R A , et al . Correlation of the Thermal Conductivity of Normal and Parahydrogen from the Triple Point to 1000 K and up to 100 MPa [J ] . Journal of Physical and Chemical Reference Data , 2011 , 40 ( 3 ): 033101 .
Roder H M . Thermal conductivity of hydrogen for temperatures between 78 and 310 K with pressures to 70 MPa [J ] . International Journal of Thermophysics , 1984 , 5 ( 4 ): 323 - 350 .
Hanley H J M , McCarty R D , Intemann H . The viscosity and thermal conductivity of dilute gaseous hydrogen from 15 to 5000 K [J ] . Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry , 1970 , 74A(3): 331.
Olchowy G A , Sengers J V . A simplified representation for the thermal conductivity of fluids in the critical region [J ] . International Journal of Thermophysics , 1989 , 10 ( 2 ): 417 - 426 .
Li Z , Duan Y Y , Yang X X . Linking Thermal Conductivity to Equations of State Using the Residual Entropy Scaling Theory [J ] . Industrial & Engineering Chemistry Research , 2024 , 63 ( 42 ): 18160 - 18175 .
Yang X X , Kim D , May E F , et al . Entropy scaling of thermal conductivity: application to refrigerants and their mixtures [J ] . Industrial & Engineering Chemistry Research , 2021 , 60 ( 35 ): 13052 - 13070 .
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