MOF衍生碳基催化剂的甲烷干重整性能研究

陈子朝; 何方书; 杨扬; 陈汉平; 杨海平

doi:10.11949/0438-1157.20260034

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MOF衍生碳基催化剂的甲烷干重整性能研究

催化、动力学与反应器 | 更新时间：2026-06-03

- MOF衍生碳基催化剂的甲烷干重整性能研究
- Study on MOF-derived carbon-based catalysts for dry reforming of methane
- 化工学报 2026年
- 作者机构：
  
  华中科技大学煤燃烧与低碳利用全国重点实验室，湖北武汉 430074
- 作者简介：
  
  陈子朝（1997—），男，博士研究生，903307351@qq.com
  杨海平（1977—），女，博士，教授，yhping2002@163.com
- 基金信息：
  
  国家杰出青年科学基金(52125601);华中科技大学交叉研究支持计划(2023JCYJ004)
- DOI：10.11949/0438-1157.20260034
  中图分类号： TQ426;O643
- 收稿：2026-01-08，
  
  修回：2026-06-02，
  
  录用：2026-06-03，
- 稿件说明：
移动端阅览
陈子朝, 何方书, 杨扬, 等. MOF衍生碳基催化剂的甲烷干重整性能研究[J/OL]. 化工学报, 2026.

CHEN Zizhao, HE Fangshu, YANG Yang, et al. Study on MOF-derived carbon-based catalysts for dry reforming of methane[J/OL]. CIESC Journal, 2026.
陈子朝, 何方书, 杨扬, 等. MOF衍生碳基催化剂的甲烷干重整性能研究[J/OL]. 化工学报, 2026. DOI： 10.11949/0438-1157.20260034.

CHEN Zizhao, HE Fangshu, YANG Yang, et al. Study on MOF-derived carbon-based catalysts for dry reforming of methane[J/OL]. CIESC Journal, 2026. DOI： 10.11949/0438-1157.20260034.

摘要

甲烷干重整（DRM）是将甲烷和二氧化碳两种温室气体转化为合成气的重要途径。以金属有机骨架（MOF）为前驱体合成了典型的NiXMg

@C（X = Co

Cu）催化剂，并评估了其DRM催化反应性能。结果表明，Co的掺杂可以显著提升NiMg@C催化剂的活性，其CH

和CO

转化率分别提高了7.16%和3.77%，但长期稳定性欠佳。Mn和Fe的掺入可以显著提高催化剂稳定性，可主要归因于催化剂抗积碳能力的增强。Cu的催化活性较弱，其掺杂使得CH

和CO

转化率均有所下降。该研究为DRM催化剂的开发提供了一种新的思路。

Abstract

Dry reforming of methane (DRM) is an important pathway for converting two greenhouse gases

methane and carbon dioxide

into syngas. Typical NiXMg

@C (X = Co

Cu) catalysts were synthesized using metal-organic frameworks (MOFs) as precursors

and their catalytic performance in DRM was evaluated. Results revealed that Co doping significantly enhanced the activity of the NiMg@C catalyst

increasing CH

and CO

conversions by 7.16% and 3.77%

respectively; however

its long-term stability was unsatisfactory. Conversely

the incorporation of Mn and Fe significantly improved catalyst stability

which was primarily attributed to enhanced coking resistance. The introduction of Cu resulted in lower catalytic activity

leading to

a decrease in both CH

and CO

conversions. This study provides a new strategy for the development of efficient DRM catalysts.

关键词

Keywords

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