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二维纳米片增强间位芳纶纳米纤维及其阻燃性能
材料化学工程与纳米技术 | 更新时间：2026-08-13
|
二维纳米片增强间位芳纶纳米纤维及其阻燃性能
Two-dimensional nanosheet reinforced
meta -aramid nanofibers and their flame retardancy- 化工学报 2026年77卷第6期 页码：3652-3662
- 作者机构：
河北工业大学化工学院，天津 300130
- 作者简介：
韩珂（2001—），男，硕士研究生，13106537691@163.com
杨韵颖（2006—），女，本科生，m18649014136@163.com
吴兴江（1992—），男，博士，教授，wuxingjiang@hebut.edu.cn
李浩（1986—），男，博士，教授，ctstlihao@hebut.edu.cn
- 基金信息：国家自然科学基金项目(22025801;22478094;22208190);河北省燕赵黄金台聚才计划骨干人才项目（教育平台类）(HJYB202507);河北省科技研发平台专项项目(25361502D)
DOI：10.11949/0438-1157.20251409
中图分类号： TQ 342.7收稿：2025-12-15，
修回：2026-02-03，
网络首发：2026-07-29，
纸质出版：2026-06-25
- 稿件说明：
移动端阅览
韩珂, 杨韵颖, 赵纯, 方静, 吴兴江, 李浩. 二维纳米片增强间位芳纶纳米纤维及其阻燃性能[J]. 化工学报, 2026, 77(6): 3652-3662
HAN Ke, YANG Yunying, ZHAO Chun, FANG Jing, WU Xingjiang, LI Hao. Two-dimensional nanosheet reinforced meta-aramid nanofibers and their flame retardancy[J]. CIESC Journal, 2026, 77(6): 3652-3662
韩珂, 杨韵颖, 赵纯, 方静, 吴兴江, 李浩. 二维纳米片增强间位芳纶纳米纤维及其阻燃性能[J]. 化工学报, 2026, 77(6): 3652-3662 DOI： 10.11949/0438-1157.20251409.
HAN Ke, YANG Yunying, ZHAO Chun, FANG Jing, WU Xingjiang, LI Hao. Two-dimensional nanosheet reinforced meta-aramid nanofibers and their flame retardancy[J]. CIESC Journal, 2026, 77(6): 3652-3662 DOI： 10.11949/0438-1157.20251409.
二维纳米片增强间位芳纶纳米纤维及其阻燃性能
摘要
间位芳纶（聚间苯二甲酰间苯二胺，PMIA）纳米纤维具有耐高温、耐化学腐蚀等优势，被广泛应用于特种防护等领域，但其实际应用仍受限于较差的力学性能。基于此，采用静电纺丝策略制备二维纳米片原位增强的PMIA纳米纤维，如MXene、氧化石墨烯（GO）、二硫
化钼（MoS
2
）、六方氮化硼（h-BN）。其中，MXene和GO具有丰富的含氧官能团，能够与PMIA分子链形成丰富的氢键网络，进而增强PMIA纳米纤维的界面相互作用，减少局部应力集中。因此，MXene/PMIA（抗拉强度59 MPa）和GO/PMIA（抗拉强度56 MPa）纳米纤维具有优异的力学性能，远高于PMIA纳米纤维（抗拉强度16 MPa）。值得注意的是，MoS
2
和h-BN含氧官能团匮乏，与PMIA分子链主要通过范德华力作用。因此，MoS
2
/PMIA（抗拉强度44 MPa）和h-BN/PMIA（抗拉强度43 MPa）纳米纤维的力学性能低于MXene/PMIA和GO/PMIA，但仍远高于PMIA纳米纤维。基于凝聚相阻燃机理，二维纳米片的加入协同强化了PMIA纳米纤维的阻燃性，在高性能特种防护服领域具有广阔的应用前景。
Abstract
Meta
-aramid (polyisophthaloyl metaphenylene diamine
PMIA) nanofibers exhibit excellent properties such as high temperature resistance and chemical corrosion resistance
thus being widely used in the field of special protection. However
their practical applications are still limited by poor mechanical properties. Based on this
two-dimensional nanosheet-reinforced PMIA nanofibers
such as MXene
graphene oxide (GO)
molybdenum disulfide (MoS
2
)
and hexagonal boron nitride (h-BN)
were prepared using an electrospinning strategy. Among these nanofillers
MXene and GO possess abundant oxygen-containing functional groups
which can form extensive hydrogen-bonding networks with PMIA molecular chains. This not only enhances the interfacial interactions of PMIA nanofibers but also reduces local stress concentration. Consequently
MXene/PMIA (tensile strength 59 MPa) and GO/PMIA (tensile strength 56 MPa) nanofibers achieve superior mechanical properties
which are much higher than those of pure PMIA nanofibers (tensile strength 16 MPa). It is worth noting that MoS₂ and h-BN lack oxygen-containing functional groups
and their interaction with PMIA molecular chains is dominated by van der Waals forces. As a result
the mechanical properties of MoS
2
/PMIA (tensile strength 44 MPa) and h-BN/PMIA (tensile strength 43 MPa) nanofibers are lower than those of MXene/PMIA and GO/PMIA nanofibers
but still far exceed those of pure PMIA nanofibers. Based on the condensed-phase flame-retardant mechanism
the incorporation of 2D nan
osheets synergistically enhances the flame retardancy of PMIA nanofibers
endowing them with broad application prospects in the field of high-performance special protective clothing.
关键词
Keywords
references
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