环氧氯丙烷与离子液体的交联过程研究

涂卓恒; 史名珍; 张效敏; 吴有庭; 胡兴邦

doi:10.11949/0438-1157.20200804

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环氧氯丙烷与离子液体的交联过程研究

南京大学化工学院院庆专栏 | 更新时间：2026-07-24

- 环氧氯丙烷与离子液体的交联过程研究
- Research on crosslinking of epichlorohydrin and ionic liquids
- 化工学报 2020年71卷第11期页码：4971-4980
- 作者机构：
  
  南京大学化学化工学院，江苏南京 210023
- 作者简介：
  
  涂卓恒(1994—)，男，博士研究生，zhuohengtu@foxmail.com
  吴有庭(1968—)，男，博士，教授，ytwu@nju.edu.cn
- 基金信息：
  
  国家自然科学基金项目(21376115;21576129);江苏省自然科学基金项目(BK20190310)
- DOI：10.11949/0438-1157.20200804
  中图分类号： TQ 028.8
- 收稿：2020-06-22，
  
  修回：2020-09-15，
  
  网络首发：2020-11-03，
  
  纸质出版：2020-11-05
- 稿件说明：
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涂卓恒, 史名珍, 张效敏, 吴有庭, 胡兴邦. 环氧氯丙烷与离子液体的交联过程研究[J]. 化工学报, 2020, 71(11): 4971-4980

TU Zhuoheng, SHI Mingzhen, ZHANG Xiaomin, WU Youting, HU Xingbang. Research on crosslinking of epichlorohydrin and ionic liquids[J]. CIESC Journal, 2020, 71(11): 4971-4980
涂卓恒, 史名珍, 张效敏, 吴有庭, 胡兴邦. 环氧氯丙烷与离子液体的交联过程研究[J]. 化工学报, 2020, 71(11): 4971-4980 DOI： 10.11949/0438-1157.20200804.

TU Zhuoheng, SHI Mingzhen, ZHANG Xiaomin, WU Youting, HU Xingbang. Research on crosslinking of epichlorohydrin and ionic liquids[J]. CIESC Journal, 2020, 71(11): 4971-4980 DOI： 10.11949/0438-1157.20200804.

摘要

鉴于目前离子液体交联反应所用交联剂存在的高成本、难制备的问题，提出以廉价易得的环氧氯丙烷交联二胺质子型离子液体制备离子液体凝胶的设想。基于此，通过监测反应体系动力学信息证明了反应的可能性，同时研究了与酸中和顺序、反应温度、交联比例对环氧基团和氯基团转化率的影响。探究了环氧氯丙烷-二胺交联体系的凝胶转变性能以及可能的反应机理。并且初步测试了交联产物的CO

分离性能。

Abstract

Ionic liquid supported liquid membranes have shown high CO

selective separation performance

but their low pressure resistance greatly limits their industrial applications. From the viewpoint of high cost and complex synthesis of crosslinkers used for crosslinking ILs

preparing IL-based gels by crosslinking diamino protic ionic liquids (PILs) with epichlorohydrin (ECH) was proposed in this work. The feasibility of this conception was confirmed

via

monitoring dynamical information of reaction system. The effects of protonation

reac

tion temperature and ECH-to-PIL molar ratio on the conversion of epoxy and chloride groups were systematically investigated. The gel transition property of these crosslinked PILs and the possible crosslinking mechanism were studied. Moreover

permeation performance in crosslinked ILs was preliminarily tested.

关键词

Keywords

references

Chestnut D H . Ten years of experience with accidental dural puncture and post-dural puncture headache in a tertiary obstetric anaesthesia department [J ] . Yearbook of Anesthesiology and Pain Management , 2009 , 2009 : 252 - 253 .

Ramdin M , de Loos T W , Vlugt T J H . State-of-the-art of CO 2 capture with ionic liquids [J ] . Industrial & Engineering Chemistry Research , 2012 , 51 ( 24 ): 8149 - 8177 .

Liu A H , Ma R , Song C , et al . Equimolar CO 2 capture by N-substituted amino acid salts and subsequent conversion [J ] . Angewandte Chemie International Edition , 2012 , 51 ( 45 ): 11306 - 11310 .

Rochelle G T . Amine scrubbing for CO 2 capture [J ] . Science , 2009 , 325 ( 5948 ): 1652 - 1654 .

Bernardo P , Drioli E , Golemme G . Membrane gas separation: a review/state of the art [J ] . Industrial & Engineering Chemistry Research , 2009 , 48 ( 10 ): 4638 - 4663 .

D&#x 1001 b3;Alessandro D M, Smit B, Long J R. Carbon dioxide capture: prospects for new materials [J ] . Angewandte Chemie International Edition, 2010 , 49 ( 35 ): 6058 - 6082 .

Blanchard L A , Hancu D , Beckman E J , et al . Green processing using ionic liquids and CO 2 [J ] . Nature , 1999 , 399 ( 6731 ): 28 - 29 .

Aki S N V K , Mellein B R , Saurer E M , et al . High-pressure phase behavior of carbon dioxide with imidazolium-based ionic liquids [J ] . Journal of Physical Chemistry B , 2004 , 108 ( 52 ): 20355 - 20365 .

Bates E D , Mayton R D , Ntai I , et al . CO 2 capture by a task-specific ionic liquid [J ] . Journal of the American Chemical Society , 2002 , 124 ( 6 ): 926 - 927 .

Xue Z , Zhang Z , Han J , et al . Carbon dioxide capture by a dual amino ionic liquid with amino-functionalized imidazolium cation and taurine anion [J ] . International Journal of Greenhouse Gas Control , 2011 , 5 ( 4 ): 628 - 633 .

Luo X Y , Fan X , Shi G L , et al . Decreasing the viscosity in CO 2 capture by amino-functionalized ionic liquids through the formation of intramolecular hydrogen bond [J ] . Journal of Physical Chemistry B , 2016 , 120 ( 10 ): 2807 - 2813 .

Hu X B , Li Y X , Huang K , et al . Impact of α-d-glucose pentaacetate on the selective separation of CO 2 and SO 2 in supported ionic liquid membranes [J ] . Green Chemistry , 2012 , 14 ( 5 ): 1440 - 1446 .

Huang K , Lu J F , Wu Y T , et al . Absorption of SO 2 in aqueous solutions of mixed hydroxylammonium dicarboxylate ionic liquids [J ] . Chemical Engineering Journal , 2013 , 215/216 : 36 - 44 .

Huang K , Chen Y L , Zhang X M , et al . Experimental study and thermodynamical modelling of the solubilities of SO 2 , H 2 S and CO 2 in N- dodecylimidazole and 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl) ] bis(imidazole): an evaluation of their potential application in the separation of acidic gases [J ] . Fluid Phase Equilibria , 2014 , 378 : 21 - 33 .

Huang K , Xia S , Zhang X M , et al . Comparative study of the solubilities of SO 2 in five low volatile organic solvents (sulfolane, ethylene glycol, propylene carbonate, N -methylimidazole, and N -methylpyrrolidone) [J ] . Journal of Chemical & Engineering Data , 2014 , 59 ( 4 ): 1202 - 1212 .

Zhao T X , Liang J , Zhang Y Y , et al . Unexpectedly efficient SO 2 capture and conversion to sulfur in novel imidazole-based deep eut ectic solvents [J ] . Chemical Communication , 2018 , 54 ( 65 ): 8964 - 8967 .

Huang K , Cai D N , Chen Y L , et al . Thermodynamic validation of 1-alkyl-3-methylimidazolium carboxylates as task-specific ionic liquids for H 2 S absorption [J ] . AIChE Journal , 2013 , 59 ( 6 ): 2227 - 2235 .

Zhang X M , Tu Z H , Li H , et al . Selective separation of H 2 S and CO 2 from CH 4 by supported ionic liquid membranes [J ] . Journal of Membrane Science , 2017 , 543 : 282 - 287 .

Zheng W T , Wu D S , Feng X , et al . Low viscous protic ionic liquids functionalized with multiple Lewis base for highly efficient capture of H 2 S [J ] . Journal of Molecular Liquids , 2018 , 263 : 209 - 217 .

Tao D J , Chen F F , Tian Z Q , et al . Highly efficient carbon monoxide capture by carbanion-functionalized ionic liquids through C-site interactions [J ] . Angewandte Chemie International Edition , 2017 , 56 ( 24 ): 6843 - 6847 .

Liu Y M , Tian Z , Qu F , et al . Tuning ion-pair interaction in cuprous-based protic ionic liquids for significantly improved CO capture [J ] . ACS Sustainable Chemistry & Engineering , 2019 , 7 ( 13 ): 11894 - 11900 .

Tu Z H , Zhang Y Y , Wu Y T , et al . Self-enhancement of CO reversible absorption accompanied by phase transition in protic chlorocuprate ionic liquids for effective CO separation from N 2 [J ] . Chemical Communication , 2019 , 55 ( 23 ): 3390 - 3393 .

Jiang Y Y , Zhou Z , Jiao Z , et al . SO 2 gas separation using supported ionic liquid membranes [J ] . Journal of Physical Chemistry B , 2007 , 111 ( 19 ): 5058 - 5061 .

Bara J E , Gabriel C J , Carlisle T K , et al . Gas separations in fluoroalkyl-functionalized room-temperature ionic liquids using supported liquid membranes [J ] . Chemical Engineering Journal , 2009 , 147 ( 1 ): 43 - 50 .

Scovazzo P . Determination of the upper limits, benchmarks, and critical properties for gas separations using stabilized room temperature ionic liquid membranes (SILMs) for the purpose of guiding future research [J ] . Journal of Membrane Science , 2009 , 343 ( 1/2 ): 199 - 211 .

Hanioka S , Maruyama T , Sotani T , et al . CO 2 separation facilitated by task-specific ionic liquids using a supported liquid membrane [J ] . Journal of Membrane Science , 2008 , 314 ( 1/2 ): 1 - 4 .

Zhang X M , Tu Z H , Li H , et al . Supported protic-ionic-liquid membranes with facilitated transport mechanism for the selective separation of CO 2 [J ] . Journal of Membrane Science , 2017 , 527 : 60 - 67 .

Kasahara S , Kamio E , Ishigami T , et al . Amino acid ionic liquid-based facilitated transport membranes for CO 2 separation [J ] . Chemical Communication , 2012 , 48 ( 55 ): 6903 - 6905 .

Zhang X M , Xiong W J , Tu Z H , et al . Supported ionic liquid membranes with dual-site interaction mechanism for efficient separation of CO 2 [J ] . ACS Sustainable Chemistry & Engineering , 2019 , 7 ( 12 ): 10792 - 10799 .

Huang K , Zhang X M , Li Y X , et al . Facilitated separation of CO 2 and SO 2 through supported liquid membranes using carboxylate-based ionic liquids [J ] . Journal of Membrane Science , 2014 , 471 : 227 - 236 .

Zeng S J , Zhang X P , Bai L , et al . Ionic-liquid-based CO 2 capture systems: structure, interaction and process [J ] . Chemical Reviews , 2017 , 117 ( 14 ): 9625 - 9673 .

Bara J E , Lessmann S , Gabriel C J , et al . Synthesis and performance of polymerizable room-temperature ionic liquids as gas separation membranes [J ] . Industrial & Engineering Chemistry Research , 2007 , 46 ( 16 ): 5397 - 5404 .

Carlisle T K , Wiesenauer E F , Nicodemus G D , et al . Ideal CO 2 /light gas separation performance of poly(vinylimidazolium) membranes and poly(vinylimidazolium)-ionic liquid composite films [J ] . Industrial & Engineering Chemistry Research , 2012 , 52 ( 3 ): 1023 - 1032 .

Li P , Coleman M R . Synthesis of room temperature ionic liquids based random copolyimides for gas separation applications [J ] . European Polymer Journal , 2013 , 49 ( 2 ): 482 - 491 .

Chen H Z , Li P , Chung T-S . PVDF/ionic liquid polymer blends with superior separation performance for removing CO 2 from hydrogen and flue gas [J ] . International Journal of Hydrogen Energy , 2012 , 37 ( 16 ): 11796 - 11804 .

Voss B A , Bara J E , Gin D L , et al . Physically gelled ionic liquids: solid membrane materials with liquidlike CO 2 gas transport [J ] . Chemistry of Materials , 2009 , 21 ( 14 ): 3027 - 3029 .

Nguyen P T , Voss B A , Wiesenauer E F , et al . Physically gelled room-temperature ionic liquid-based composite membranes for CO 2 /N 2 separation: effect of composition and thickness on membrane properties and performance [J ] . Industrial & Engineering Chemistry Research , 2012 , 52 ( 26 ): 8812 - 8821 .

Zhang X M , Kar M , Mendes T C , et al . Supported ionic liquid gel membrane electrolytes for flexible supercapacitors [J ] . Advanced Energy Materials , 2018 , 8 ( 15 ): 1702702 .

McDanel W M , Cowan M G , Chisholm N O , et al . Fixed-site-carrier facilitated transport of carbon dioxide through ionic-liquid-based epoxy-amine ion gel membranes [J ] . Journal of Membrane Science , 2015 , 492 : 303 - 311 .

Dai Z , Ansaloni L , Gin D L , et al . Facile fabrication of CO 2 separation membranes by cross-linking of poly(ethylene glycol) diglycidyl ether with a diamine and a polyamine-based ionic liquid [J ] . Journal of Membrane Science , 2017 , 523 : 551 - 560 .

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