三维筋撑石墨烯负载氧化锰的超级电容器

李鑫健; 王保禄; 高天; 王旗; 王学斌

doi:10.11949/0438-1157.20200797

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三维筋撑石墨烯负载氧化锰的超级电容器

南京大学化工学院院庆专栏 | 更新时间：2026-07-24

- 三维筋撑石墨烯负载氧化锰的超级电容器
- Three-dimensional strutted graphene loading manganese oxide for supercapacitor
- 化工学报 2020年71卷第11期页码：5025-5034
- 作者机构：
  
  固体微结构物理国家重点实验室，人工微结构科学与技术协同创新中心，江苏省功能材料设计原理与应用技术重点实验室，南京大学现代工程与应用科学学院，江苏南京 210093
- 作者简介：
  
  李鑫健(1996—)，女，硕士研究生，2014—2018年在南京大学获学士学位，2018年至今在南京大学攻读硕士学位，lixinjian@smail.nju.edu.cn
  王学斌（1983—），男，博士，教授，2002—2009年在南京大学化学系获学士和硕士学位,2015年至今在南京大学现代工程与应用科学学院工作，wangxb@nju.edu.cn
- 基金信息：
  
  国家自然科学基金项目(51672124;51972168;21603096);江苏双创计划;青年千人计划
- DOI：10.11949/0438-1157.20200797
  中图分类号： TQ 031.2
- 收稿：2020-06-22，
  
  修回：2020-09-08，
  
  网络首发：2020-11-03，
  
  纸质出版：2020-11-05
- 稿件说明：
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李鑫健, 王保禄, 高天, 王旗, 王学斌. 三维筋撑石墨烯负载氧化锰的超级电容器[J]. 化工学报, 2020, 71(11): 5025-5034

LI Xinjian, WANG Baolu, GAO Tian, WANG Qi, WANG Xuebin. Three-dimensional strutted graphene loading manganese oxide for supercapacitor[J]. CIESC Journal, 2020, 71(11): 5025-5034
李鑫健, 王保禄, 高天, 王旗, 王学斌. 三维筋撑石墨烯负载氧化锰的超级电容器[J]. 化工学报, 2020, 71(11): 5025-5034 DOI： 10.11949/0438-1157.20200797.

LI Xinjian, WANG Baolu, GAO Tian, WANG Qi, WANG Xuebin. Three-dimensional strutted graphene loading manganese oxide for supercapacitor[J]. CIESC Journal, 2020, 71(11): 5025-5034 DOI： 10.11949/0438-1157.20200797.

摘要

石墨烯基超级电容器，其功率密度较高，但能量密度受限。开发以三维石墨烯材料为载体的复合型赝电容多孔电极，是解决方案之一。本文采用铵盐辅助化学发泡法，制备了三维筋撑石墨烯泡沫体（SG）；以SG为载体，采用水热还原法在其表面生长二氧化锰（MnO

）纳米棒阵列，从而构建了MnO

/SG自支撑多孔材料。利用MnO

/SG复合电极，组装了超级电容器，在0.5 A·g

-1

的电流密度下，比电容达343.6 F·g

-1

；经5000次循环，其容量保持率为83.8%；在500 W·kg

-1

的功率密度下，其能量密度达11.93 W·h·kg

-1

。因此，MnO

/SG复合电极是一种性能优异的赝电容材料，在电化学储能领域有良好的应用前景。

Abstract

Graphene has shown superiorit

y for advanced carbon electrodes in supercapacitors， characterized by high power density but limited energy density. Combining pseudocapacitive materials with graphene can alleviate the problem. This work synthesized the three-dimensional strutted graphene (SG)

via

the ammonium-salt-assisted sugar-blowing method

and the self-supporting MnO

/SG porous monolith was then constructed

via

growing manganese oxide (MnO

) nanorod array on the SG support in hydrothermal process. When tested in supercapacitor， the MnO

/SG hybrid electrode achieved a high specific capacitance of 343.6 F·g

-1

at a current density of 0.5 A·g

-1

， exhibiting excellent cycling stability with 83.8% capacitance retention after 5000 cycles. The symmetric supercapacitor further showed a high energy density of 11.93 W·h·kg

-1

at a power density of 500 W·kg

-1

. The impressive result indicates a promising prospect of the excellent MnO

/SG hybrid to be applied to electrochemical energy storage.

关键词

Keywords

references

Xia J , Chen F , Li J , et al . Measurement of the quantum capacitance of graphene [J ] . Nature Nanotechnology , 2009 , 4 ( 8 ): 505 - 509 .

Raccichini R , Varzi A , Passerini S , et al . The role of graphene for electrochemical energy storage [J ] . Nature Materials , 2015 , 14 : 271 - 279 .

Huang H B , Shi H D , Das P , et al . The chemistry and promising applications of graphene and porous graphene materials [J ] . Advanced Functional Materials , 2020 , doi: 10.1002/adfm.201909035 http://dx.doi.org/10.1002/adfm.201909035 .

Vivekchand S R C , Rout C S , Subrahmanyam K S , et al . Graphene-based electrochemical supercapacitors [J ] . Journal of Chemical Sciences , 2008 , 120 ( 1 ): 9 - 13 .

Stoller M D , Park S , Zhu Y W , et al . Graphene-based ultracapacitors [J ] . Nano Letters , 2008 , 8 ( 10 ): 3498 - 3502 .

高天 , 肖庆林 , 许晨阳 , 等 . 发泡法制备二维材料泡沫体的进展 [J ] . 无机材料学报 , 2020 , doi: 10.15541/jim20200096 http://dx.doi.org/10.15541/jim20200096 .

Gao T , Xiao Q L , Xu C Y , et al . Blowing route to fabricate foams of 2D materials [J ] . Journal of Inorganic Materials , 2020 , doi: 10.15541/jim20200096 http://dx.doi.org/10.15541/jim20200096 .

Xu Y , Sheng K , Li C , et al . Self-assembled graphene hydrogel via a one-step hydrothermal process [J ] . ACS Nano , 2010 , 4 ( 7 ): 4324 - 4330 .

Choi B G , Yang M H , Hong W H , et al . 3D macroporous graphene frameworks for supercapacitors with high energy and power densities [J ] . ACS Nano , 2012 , 6 ( 5 ): 4020 - 4028 .

Zhu C , Han T Y J , Duoss E B , et al . Highly compressible 3D periodic graphene aerogel microlattices [J ] . Nature Communications , 2015 , 6 : 6962 .

Shao Y L , El-Kady M F , Lin C W , et al . 3D freeze-casting of cellular graphene films for ultrahigh-power-density supercapacitors [J ] . Advanced Materials , 2016 , 28 ( 31 ): 6719 - 6726 .

Chen Z P , Ren W C , Gao L B , et al . Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition [J ] . Nature Materials , 2011 , 10 : 424 - 428 .

Zhao J , Lai H W , Lyu Z Y , et al . Hydrophilic hierarchical nitrogen-doped carbon nanocages for ultrahigh supercapacitive performance [J ] . Advanced Materials , 2015 , 27 ( 23 ): 3541 - 3545 .

Li N , Yang G Z , Sun Y , et al . Free-standing and transparent graphene membrane of polyhedron box-shaped basic building units directly grown using a NaCl template for flexible transparent and stretchable solid-state supercapacitors [J ] . Nano Letters , 2015 , 15 ( 5 ): 3195 - 3203 .

Wang X B , Zhang Y J , Zhi C Y , et al . Three-dimensional strutted graphene grown by substrate-free sugar blowing for high-power-density supercapacitors [J ] . Nature Communications , 2013 , 4 : 2905 .

El-Kady M F , Strong V , Dubin S , et al . Laser scribing of high-performance and flexible graphene-based electrochemical capacitors [J ] . Science , 2012 , 335 ( 6074 ): 1326 - 1330 .

Jiang X F , Li R Q , Hu M , et al . Zinc-tiered synthesis of 3D graphene for monolithic electrodes [J ] . Advanced Materials , 2019 , 31 ( 25 ): 1901186 .

Wang C W , Wang Y , Graser J , et al . Solution-based carbohydrate synthesis of individual solid, hollow, and porous carbon nanospheres using spray pyrolysis [J ] . ACS Nano , 2013 , 7 ( 12 ): 11156 - 11165 .

Ge J , Yao H B , Hu W , et al . Facile dip coating processed graphene/MnO 2 nanostructured sponges as high performance supercapacitor electrodes [J ] . Nano Energy , 2013 , 2 ( 4 ): 505 - 513 .

Xie L J , Su F Y , Xie L F , et al . Self-assembled 3D graphene-based aerogel with Co 3 O 4 nanoparticles as high-performance asymmetric supercapacitor electrode [J ] . ChemSusChem , 2015 , 8 ( 17 ): 2917 - 2926 .

Qiu B C , Xing M Y , Zhang J L . Stöber-like method to synthesize ultralight, porous, stretchable Fe 2 O 3 /graphene aerogels for excellent performance in photo-Fenton reaction and electrochemical capacitors [J ] . Journal of Materials Chemistry A , 2015 , 3 ( 24 ): 12820 - 12827 .

Meng X Q , Zhu J W , Bi H P , et al . Three-dimensional nickel hydroxide/graphene composite hydrogels and their transformation to NiO/graphene composites for energy storage [J ] . Journal of Materials Chemistry A , 2015 , 3 ( 43 ): 21682 - 21689 .

Patil U M , Nam M S , Sohn J S , et al . Controlled electrochemical growth of Co(OH) 2 flakes on 3D multilayered graphene foam for high performance supercapacitors [J ] . Journal of Materials Chemistry A , 2014 , 2 ( 44 ): 19075 - 19083 .

Park H , Kim J W , Hong S Y , et al . Microporous polypyrrole-coated graphene foam for high-performance multifunctional sensors and flexible supercapacitors [J ] . Advanced Functional Materials , 2018 , 28 ( 33 ): 1707013 .

Zhang Q E , Zhou A A , Wang J J , et al . Degradation-induced capacitance: a new insight into the superior capacitive performance of polyaniline/graphene composites [J ] . Energy & Environmental Science , 2017 , 10 ( 11 ): 2372 - 2382 .

Fic K , Lota G , Meller M , et al . Novel insight into neutral medium as electrolyte for high-voltage supercapacitors [J ] . Energy & Environmental Science , 2012 , 5 ( 2 ): 5842 - 5850 .

Wu Q , Yang L J , Wang X Z , et al . Carbon-based nanocages: a new platform for advanced energy storage and conversion [J ] . Advanced Materials , 2020 , 32 ( 27 ): 1904177 .

Wang J G , Kang F Y , Wei B Q . Engineering of MnO 2 -based nanocomposites for high-performance supercapacitors [J ] . Progress in Materials Science , 2015 , 74 : 51 - 124 .

Wei B , Wang L , Wang Y , et al . In situ growth of manganese oxide on 3D graphene by a reverse microemulsion method for supercapacitors [J ] . Journal of Power Sources , 2016 , 307 : 129 - 137 .

Wagner C D , Zatko D A , Raymond R H . Use of the oxygen KLL Auger lines in identification of surface chemical states by electron spectroscopy for chemical analysis [J ] . Analytical Chemistry , 1980 , 52 ( 9 ): 1445 - 1451 .

Beng J T , Kenneth J K , Peter M A S . XPS studies of solvated metal atom dispersed catalysts. Evidence for layered cobalt-manganese particles on alumina and silica [J ] . Journal of the American Chemical Society , 1991 , 113 ( 3 ): 855 - 861 .

Meng X , Lu L , Sun C . Green synthesis of three-dimensional MnO 2 /graphene hydrogel composite as a high-performance electrode material for supercapacitors [J ] . ACS Applied Materials & Interfaces , 2018 , 10 : 11474 - 11481 .

Simon P , Gogotsi Y . Materials for electrochemical capacitors [J ] . Nature Materials , 2008 , 7 : 845 - 854 .

Zhu X L , Zhang P , Xu S , et al . Free-standing three-dimensional graphene/manganese oxide hybrids as binder-free electrode materials for energy storage applications [J ] . ACS Applied Materials & Interfaces , 2014 , 6 ( 14 ): 11665 - 11674 .

Li Y , Wang G , Ye K , et al . Facile preparation of three-dimensional multilayer porous MnO 2 /reduced graphene oxide composite and its supercapacitive performance [J ] . Journal of Power Sources , 2014 , 271 : 582 - 588 .

Li Z P , Mi Y J , Liu X H , et al . Flexible graphene/MnO 2 composite papers for supercapacitor electrodes [J ] . Journal of Materials Chemistry , 2011 , 21 ( 38 ): 14706 - 14711 .

Yang B Y , Jin X , Wang Y , et al . In-situ growth of flower-like MnO 2 /graphene hydrogel mesoporous electrode material for supercapacitors [J ] . Integrated Ferroelectrics , 2020 , 206 ( 1 ): 87 - 95 .

Zhao Z Y , Shen T , Liu Z H , et al . Facile fabrication of binder-free reduced graphene oxide/MnO 2 /Ni foam hybrid electrode for high-performance supercapacitors [J ] . Journal of Alloys and Compounds , 2020 , 812 : 152124 .

Chai Y Q , Li Z P , Wang J Q , et al . Construction of hierarchical holey graphene/MnO 2 composites as potential electrode materials for supercapacitors [J ] . Journal of Alloys and Compounds , 2019 , 775 : 1206 - 1212 .

Rogier C , Pognon G , Bondavalli P , et al . Electrodeposition of MnO 2 on spray-coated nanostructured carbon framework as high performance material for energy storage [J ] . Surface & Coatings Technology , 2020 , 384 : 125310 .

Ma C X , Wang R X , Tetik H , et al . Hybrid nanomanufacturing of mixed-dimensional manganese oxide/graphene aerogel macroporous hierarchy for ultralight efficient supercapacitor electrodes in self-powered ubiquitous nanosystems [J ] . Nano Energy , 2019 , 66 : 104124 .

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