新型酚基深共熔溶剂的物性表征及NH<sub>3</sub>捕集性能研究

程宁宁; 曾丽花; 邓毓麟; 彭海龙; 黄宽

doi:10.11949/0438-1157.20200796

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新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究

南京大学化工学院院庆专栏 | 更新时间：2026-07-24

- 新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究
- Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents
- 化工学报 2020年71卷第11期页码：5043-5051
- 作者机构：
  
  1.南昌大学资源环境与化工学院，江西南昌 330031
  2.南昌大学鄱阳湖环境资源与利用教育部重点实验室，江西南昌 330031
- 作者简介：
  
  程宁宁（1997—），女，硕士研究生，1318229157@qq.com
  黄宽（1990—），男，博士，教授，huangk@ncu.edu.cn
- 基金信息：
  
  国家自然科学基金项目(22008033);江西省自然科学基金项目(20192ACB21016)
- DOI：10.11949/0438-1157.20200796
  中图分类号： TQ 028.8
- 收稿：2020-06-22，
  
  修回：2020-09-02，
  
  网络首发：2020-11-03，
  
  纸质出版：2020-11-05
- 稿件说明：
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程宁宁, 曾丽花, 邓毓麟, 彭海龙, 黄宽. 新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究[J]. 化工学报, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796.

CHENG Ningning, ZENG Lihua, DENG Yulin, PENG Hailong, HUANG Kuan. Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents[J]. CIESC Journal, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796.
程宁宁, 曾丽花, 邓毓麟, 彭海龙, 黄宽. 新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究[J]. 化工学报, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796. DOI：

CHENG Ningning, ZENG Lihua, DENG Yulin, PENG Hailong, HUANG Kuan. Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents[J]. CIESC Journal, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796. DOI：

摘要

污染问题一直是化工、环保等领域关注的重点问题，对工业尾气中的NH

进行捕集和回收具有十分重要的意义。以氯化1-乙基-3-甲基咪唑（［Emim］Cl）为氢键受体，苯酚、间苯二酚和间苯三酚为氢键

供体，构建了一类新型酚基深共熔溶剂。详细测定了酚基深共熔溶剂在不同温度下的密度和黏度，并采用经验方程对密度和黏度数据进行了关联。此外，系统考察了酚基深共熔溶剂对NH

的吸收-解吸性能和吸收选择性，发现其具有较高的NH

吸收容量，被吸收的NH

可在加热和减压的条件下释放出来，经过多次循环NH

吸收容量基本保持不变。而酚基深共熔溶剂的CO

吸收容量则较低，因而具有优异的NH

/CO

吸收选择性。最后，借助光谱表征和量子化学计算，深入探究了NH

在酚基深共熔溶剂中吸收的相互作用机制。

Abstract

pollution has always been a key concern in chemical industry

environmental protection and other fields. The capture and recovery of NH

in industrial exhaust gas is of great significance. A novel class of phenol-based deep eutectic solvents (DESs) were constructed by using 1-ethyl-3-methylimidazolium chloride ([Emim

]

Cl) as the hydrogen bond acceptor

while phenol (Phe)

resorcinol (Res) and phloroglucinol (Phl) as the hydrogen bond donors. The densities and viscosities of phenol-based DESs at different temperatures were determined in detail

and the density and viscosity data were correlated by empirical equations. In addition

the NH

absorption-desorption performance and absorption selectivity of phenol-based DESs were systematically investigated. It is found that the capacities of phenol-based DESs for NH

absorption are quite high

and the absorbed NH

can be released by heating and evacuating

with the capacities for NH

absorption remaining almost unchanged after several cycles. However

the capacities of phenol-based DESs for CO

absorption are quite low

indicating the excellent performance of phenol-based DESs for NH

/CO

selective absorption. Finally

the interaction mechanism of NH

absorption in phenol-based DESs was studied in depth with the help of spectral characterizations and quantum chemistry calculations.

关键词

Keywords

references

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新型酚基深共熔溶剂的物性表征及NH3捕集性能研究

Physical properties characterizations and NH3 capture performance investigation of novel phenol-based deep eutectic solvents

DOI：10.11949/0438-1157.20200796

摘要

Abstract

关键词

Keywords

references

新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究

Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents