电化学反应器隔膜材料的分子设计与介尺度策略

李存璞; 王建川; 魏子栋

doi:10.11949/0438-1157.20200759

您当前的位置：

首页 >

文章列表页 >

电化学反应器隔膜材料的分子设计与介尺度策略

综述与专论 | 更新时间：2025-11-25

- 电化学反应器隔膜材料的分子设计与介尺度策略
- Mesoscopic strategies and molecular design of diaphragm for electrochemical reactors
- 化工学报 2020年71卷第10期页码：4490-4501
- 作者机构：
  
  重庆大学化学化工学院，重庆 400044
- 作者简介：
  
  李存璞(1986—)，男，博士，副教授，lcp@cqu.edu.cn
  魏子栋(1963—)，男，博士，教授，zdwei@cqu.edu.cn
- 基金信息：
  
  国家自然科学基金项目(91834301;21606027)
- DOI：10.11949/0438-1157.20200759
  中图分类号： TK 91.8
- 收稿：2020-06-16，
  
  修回：2020-07-23，
  
  纸质出版：2020-10-05
- 稿件说明：
移动端阅览
李存璞, 王建川, 魏子栋. 电化学反应器隔膜材料的分子设计与介尺度策略[J]. 化工学报, 2020, 71(10): 4490-4501

LI Cunpu, WANG Jianchuan, WEI Zidong. Mesoscopic strategies and molecular design of diaphragm for electrochemical reactors[J]. CIESC Journal, 2020, 71(10): 4490-4501
李存璞, 王建川, 魏子栋. 电化学反应器隔膜材料的分子设计与介尺度策略[J]. 化工学报, 2020, 71(10): 4490-4501 DOI： 10.11949/0438-1157.20200759.

LI Cunpu, WANG Jianchuan, WEI Zidong. Mesoscopic strategies and molecular design of diaphragm for electrochemical reactors[J]. CIESC Journal, 2020, 71(10): 4490-4501 DOI： 10.11949/0438-1157.20200759.

摘要

电化学反应器中隔膜材料是将正极和负极在电子通路上隔开但在离子传输通路上保持畅通的特殊材料。作为电化学反应器三个关键材料之一，隔膜材料还需耐强酸/强碱和高电压等环境。围绕电化学反应器中隔膜材料，从分子设计的角度针对材料电化学性能与化学稳定性的调控、电化学装置的介观传质性能的促进和改善等研究思路与进展进行了综述，为相关研究提供性能导向的分子设计参考。

Abstract

The diaphragm material in the electrochemical reactor is a special material that separates the positive electrode and the negative electrode on the electronic path but keeps the ion transport path open. As one of the three critical materials in the electrochemical reactor

the separating diaphragm must be stable in the crucial acidic/basic

strong electric field strength

and other complex micro-environments. In this review

we focus on the molecular design of the separating diaphragm inside the electrochemical reactors. The mesoscopic strategies to regulate electrochemical properties and chemical stabilities of the separating diaphragm were discussed. The purpose of this review is to set up a link between the molecular structure of the separating diaphragm and the performances of the electrochemical reactors in terms of mesoscopic strategies.

关键词

Keywords

references

Zhou G , Li L , Wang D W , et al . A flexible sulfur-graphene-polypropylene separator integrated electrode for advanced Li-S batteries [J]. Advanced Materials , 2015 , 27 ( 4 ): 641 - 647 .

Yao H , Yan K , Li W , et al . Improved lithium-sulfur batteries with a conductive coating on the separator to prevent the accumulation of inactive S-related species at the cathode–separator interface [J]. Energy & Environmental Science , 2014 , 7 ( 10 ): 3381 - 3390 .

Chung S H , Manthiram A . Bifunctional separator with a light-weight carbon-coating for dynamically and statically stable lithium-sulfur batteries [J]. Advanced Functional Materials , 2014 , 24 ( 33 ): 5299 - 5306 .

Gu X , Tong C , Lai C , et al . A porous nitrogen and phosphorous dual doped graphene blocking layer for high performance Li-S batteries [J]. Journal of Materials Chemistry A , 2015 , 3 ( 32 ): 16670 - 16678 .

Jin Z , Xie K , Hong X , et al . Application of lithiated Nafion ionomer film as functional separator for lithium sulfur cells [J]. Journal of Power Sources , 2012 , 218 : 163 - 167 .

Hao Z , Yuan L , Li Z , et al . High performance lithium-sulfur batteries with a facile and effective dual functional separator [J]. Electrochimica Acta , 2016 , 200 : 197 - 203 .

Luo X , Lu X , Zhou G , et al . Ion-selective polyamide acid nanofiber separators for high-rate and stable lithium–sulfur batteries [J]. ACS Applied Materials & Interfaces , 2018 , 10 ( 49 ): 42198 - 42206 .

Peng Q , Yu F , Wang W , et al . Ultralight polyethylenimine/porous carbon modified separator as an effective polysulfide-blocking barrier for lithium-sulfur battery [J]. Electrochimica Acta , 2019 , 299 : 749 - 755 .

Yu X , Wu H , Koo J H , et al . Tailoring the pore size of a polypropylene separator with a polymer having intrinsic nanoporosity for suppressing the polysulfide shuttle in lithium-sulfur batteries [J]. Advanced Energy Materials , 2020 , 10 ( 1 ): 1902872 .

Zhang Z , Lai Y , Zhang Z , et al . Al 2 O 3 -coated porous separator for enhanced electrochemical performance of lithium sulfur batteries [J]. Electrochimica Acta , 2014 , 129 : 55 - 61 .

Zhang J , Rao Q , Jin B , et al . Cerium oxide embedded bilayer separator enabling fast polysulfide conversion for high-performance lithium-sulfur batteries [J]. Chemical Engineering Journal , 2020 , 388 : 124120 .

Shao H , Wang W , Zhang H , et al . Nano-TiO 2 decorated carbon coating on the separator to physically and chemically suppress the shuttle effect for lithium-sulfur battery [J]. Journal of Power Sources , 2018 , 378 : 537 - 545 .

Song X , Chen G , Wang S , et al . Self-assembled close-packed MnO 2 nanoparticles anchored on a polyethylene separator for lithium-sulfur batteries [J]. ACS Applied Materials & Interfaces , 2018 , 10 ( 31 ): 26274 - 26282 .

Hong X J , Song C L , Yang Y , et al . Cerium based metal-organic frameworks as an efficient separator coating catalyzing the conversion of polysulfides for high performance lithium–sulfur batteries [J]. ACS Nano , 2019 , 13 ( 2 ): 1923 - 1931 .

Cai W , Li G , Zhang K , et al . Conductive nanocrystalline niobium carbide as high‐efficiency polysulfides tamer for lithium‐sulfur batteries [J]. Advanced Functional Materials , 2018 , 28 ( 2 ): 1704865 .

Ghazi Z A , He X , Khattak A M , et al . MoS 2 /celgard separator as efficient polysulfide barrier for long-life lithium-sulfur batteries [J]. Advanced Materials , 2017 , 29 ( 21 ): 1606817 .

Wang P , Bao J , Lv K , et al . Rational design of a gel-polymer-inorganic separator with uniform lithium-ion deposition for highly stable lithium-sulfur batteries [J]. ACS Applied Materials & Interfaces , 2019 , 11 ( 39 ): 35788 - 35795 .

Hwang J Y , Kim H M , Lee S K , et al . High-energy, high-rate, lithium-sulfur batteries: synergetic effect of hollow TiO 2 -webbed carbon nanotubes and a dual functional carbon‐paper interlayer [J]. Advanced Energy Materials , 2016 , 6 ( 1 ): 1501480 .

Dong Q , Shen R , Li C , et al . Construction of soft base tongs on separator to grasp polysulfides from shuttling in lithium-sulfur batteries [J]. Small , 2018 , 14 ( 52 ): e1804277 .

Sun J , Sun Y , Pasta M , et al . Entrapment of polysulfides by a black‐phosphorus‐modified separator for lithium-sulfur batteries [J]. Advanced Materials , 2016 , 28 ( 44 ): 9797 - 9803 .

Song R , Fang R , Wen L , et al . A trilayer separator with dual function for high performance lithium-sulfur batteries [J]. Journal of Power Sources , 2016 , 301 : 179 - 186 .

Dong Q , Wang T , Gan R , et al . Balancing the seesaw: investigation of a separator to grasp polysulfides with diatomic chemisorption [J]. ACS Applied Materials & Interfaces , 2020 , 12 ( 18 ): 20596 - 20604 .

Varcoe J R , Atanassov P , Dekel D R , et al . Anion-exchange membranes in electrochemical energy systems [J]. Energy & Environmental Science , 2014 , 7 ( 10 ): 3135 - 3191 .

Wang Y J , Qiao J , Baker R , et al . Alkaline polymer electrolyte membranes for fuel cell applications [J]. Chemical Society Reviews , 2013 , 42 ( 13 ): 5768 - 5787 .

Yang Y , Wang J , Zheng J , et al . A stable anion exchange membrane based on imidazolium salt for alkaline fuel cell [J]. Journal of Membrane Science , 2014 , 467 : 48 - 55 .

Dai P , Mo Z H , Xu R W , et al . Cross-linked quaternized poly(styrene- b -(ethylene- co- butylene)- b -styrene) for anion exchange membrane: synthesis, characterization and properties [J]. ACS Applied Materials & Interfaces , 2016 , 8 ( 31 ): 20329 - 20341 .

Dong X , Lv D , Zheng J , et al . Pyrrolidinium-functionalized poly(arylene ether sulfone)s for anion exchange membranes: using densely concentrated ionic groups and block design to improve membrane performance [J]. Journal of Membrane Science , 2017 , 535 : 301 - 311 .

Hao J , Gao X , Jiang Y , et al . Crosslinked high-performance anion exchange membranes based on poly(styrene- b -(ethylene- co -butylene)- b -styrene) [J]. Journal of Membrane Science , 2018 , 551 : 66 - 75 .

Strasser D J , Graziano B J , Knauss D M . Base stable poly(diallylpiperidinium hydroxide) multiblock copolymers for anion exchange membranes [J]. Journal of Materials Chemistry A , 2017 , 5 ( 20 ): 9627 - 9640 .

Wang Z , Li Z , Chen N , et al . Crosslinked poly (2,6-dimethyl-1,4-phenylene oxide) polyelectrolyte enhanced with poly (styrene- b -(ethylene- co -butylene)- b -styrene) for anion exchange membrane applications [J]. Journal of Membrane Science , 2018 , 564 : 492 - 500 .

Zhang K , Gong S , Zhao B , et al . Bent-twisted block copolymer anion exchange membrane with improved conductivity [J]. Journal of Membrane Science , 2018 , 550 : 59 - 71 .

Zhang X , Chen P , Shi Q , et al . Block poly(arylene ether sulfone) copolymers bearing quaterinized aromatic pendants: synthesis, property and stability [J]. International Journal of Hydrogen Energy , 2017 , 42 ( 42 ): 26320 - 26332 .

Guo D , Lai A N , Lin C X , et al . Imidazolium-functionalized poly(arylene ether sulfone) anion-exchange membranes densely grafted with flexible side chains for fuel cells [J]. ACS Applied Materials & Interfaces , 2016 , 8 ( 38 ): 25279 - 25288 .

Han J , Zhu L , Pan J , et al . Elastic long-chain multication cross-linked anion exchange membranes [J]. Macromolecules , 2017 , 50 ( 8 ): 3323 - 3332 .

Jannasch P , Weiber E A . Configuring anion-exchange membranes for high conductivity and alkaline stability by using cationic polymers with tailored side chains [J]. Macromolecular Chemistry and Physics , 2016 , 217 ( 10 ): 1108 - 1118 .

Lai A N , Zhuo Y Z , Lin C X , et al . Side-chain-type phenolphthalein-based poly(arylene ether sulfone nitrile)s anion exchange membrane for fuel cells [J]. Journal of Membrane Science , 2016 , 502 : 94 - 105 .

Pan J , Han J , Zhu L , et al . Cationic side-chain attachment to poly(phenylene oxide) backbones for chemically stable and conductive anion exchange membranes [J]. Chemistry of Materials , 2017 , 29 ( 12 ): 5321 - 5330 .

Zeng L , Zhao T S . An effective strategy to increase hydroxide-ion conductivity through microphase separation induced by hydrophobic-side chains [J]. Journal of Power Sources , 2016 , 303 : 354 - 362 .

Zhang M , Shan C , Liu L , et al . Facilitating anion transport in polyolefin-based anion exchange membranes via bulky side chains [J]. ACS Applied Materials & Interfaces , 2016 , 8 ( 35 ): 23321 - 23330 .

Wang L , Bellini M , Miller H A , et al . A high conductivity ultrathin anion-exchange membrane with 500+ h alkali stability for use in alkaline membrane fuel cells that can achieve 2 W/cm 2 at 80℃ [J]. Journal of Materials Chemistry A , 2018 , 6 ( 31 ): 15404 - 15412 .

Pan J , Chen C , Li Y , et al . Constructing ionic highway in alkaline polymer electrolytes [J]. Energy & Environmental Science , 2014 , 7 ( 1 ): 354 - 360 .

Cheng X , Wang J , Liao Y , et al . Enhanced conductivity of anion-exchange membrane by incorporation of quaternized cellulose nanocrystal [J]. ACS Applied Materials & Interfaces , 2018 , 10 ( 28 ): 23774 - 23782 .

Wang Y , Wan H , Wang D , et al . Preparation and characterization of a semi-interpenetrating network alkaline anion exchange membrane [J]. Fibers and Polymers , 2018 , 19 ( 1 ): 11 - 21 .

Xue J , Liu L , Liao J , et al . Semi-interpenetrating polymer networks by azide-alkyne cycloaddition as novel anion exchange membranes [J]. Journal of Materials Chemistry A , 2018 , 6 ( 24 ): 11317 - 11326 .

Chen C , Chen B , Hong R . Preparation and properties of alkaline anion exchange membrane with semi‐interpenetrating polymer networks based on poly (vinylidene fluoride- co -hexafluoropropylene) [J]. Journal of Applied Polymer Science , 2018 , 135 ( 5 ): 45775 .

Zhang K , Mcdonald M B , Genina I E A , et al . A highly conductive and mechanically robust OH – conducting membrane for alkaline water electrolysis [J]. Chemistry of Materials , 2018 , 30 ( 18 ): 6420 - 6430 .

Pan J , Zhu L , Han J , et al . Mechanically tough and chemically stable anion exchange membranes from rigid-flexible semi-interpenetrating networks [J]. Chemistry of Materials , 2015 , 27 ( 19 ): 6689 - 6698 .

Guo D , Zhuo Y Z , Lai A N , et al . Interpenetrating anion exchange membranes using poly(1-vinylimidazole) as bifunctional crosslinker for fuel cells [J]. Journal of Membrane Science , 2016 , 518 : 295 - 304 .

Zeng L , He Q , Liao Y , et al . Anion exchange membrane based on interpenetrating polymer network with ultrahigh ion conductivity and excellent stability for alkaline fuel cell [J]. Research , 2020 , DOI: 10.34133/2020/4794706 http://dx.doi.org/10.34133/2020/4794706 .

Zhu L , Pan J , Wang Y , et al . Multication side chain anion exchange membranes [J]. Macromolecules , 2016 , 49 ( 3 ): 815 - 824 .

Zhu L , Yu X , Hickner M A . Exploring backbone-cation alkyl spacers for multi-cation side chain anion exchange membranes [J]. Journal of Power Sources , 2018 , 375 : 433 - 441 .

Han J , Zhu L , Pan J , et al . Elastic long-chain multication cross-linked anion exchange membranes [J]. Macromolecules , 2017 , 50 ( 8 ): 3323 - 3332 .

Yang Y , Fu N , Dong Q , et al . Self‐aggregation to construct hydroxide highways in anion exchange membranes [J]. Advanced Materials Interfaces , 2020 , 7 ( 14 ): 1902143 .

Hao J , Jiang Y , Gao X , et al . Functionalization of polybenzimidazole-crosslinked poly(vinylbenzyl chloride) with two cyclic quaternary ammonium cations for anion exchange membranes [J]. Journal of Membrane Science , 2018 , 548 : 1 - 10 .

Chen D , Hickner M A . Ion clustering in quaternary ammonium functionalized benzylmethyl containing poly(arylene ether ketone)s [J]. Macromolecules , 2013 , 46 ( 23 ): 9270 - 9278 .

Gong X , He G , Yan X , et al . Electrospun nanofiber enhanced imidazolium-functionalized polysulfone composite anion exchange membranes [J]. RSC Advances , 2015 , 5 ( 115 ): 95118 - 95125 .

Lee W H , Kim Y S , Bae C . Robust hydroxide ion conducting poly(biphenyl alkylene)s for alkaline fuel cell membranes [J]. ACS Macro Letters , 2015 , 4 ( 8 ): 814 - 818 .

Wang K , Gao L , Liu J , et al . Comb-shaped ether-free poly (biphenyl indole) based alkaline membrane [J]. Journal of Membrane Science , 2019 , 588 : 117216 .

Olsson J S , Pham T H , Jannasch P . Tuning poly (arylene piperidinium) anion-exchange membranes by copolymerization, partial quaternization and crosslinking [J]. Journal of Membrane Science , 2019 , 578 : 183 - 195 .

Hao J , Jiang Y , Gao X , et al . Functionalization of polybenzimidazole-crosslinked poly (vinylbenzyl chloride) with two cyclic quaternary ammonium cations for anion exchange membranes [J]. Journal of Membrane Science , 2018 , 548 : 1 - 10 .

Chu X , Liu L , Huang Y , et al . Practical implementation of bis-six-membered N -cyclic quaternary ammonium cations in advanced anion exchange membranes for fuel cells: synthesis and durability [J]. Journal of Membrane Science , 2019 , 578 : 239 - 250 .

Ren R , Zhang S , Miller H A , et al . Facile preparation of an ether-free anion exchange membrane with pendant cyclic quaternary ammonium groups [J]. ACS Applied Energy Materials , 2019 , 2 ( 7 ): 4576 - 4581 .

Wang J , Zhao Y , Setzler B P , et al . Poly (aryl piperidinium) membranes and ionomers for hydroxide exchange membrane fuel cells [J]. Nature Energy , 2019 , 4 ( 5 ): 392 - 398 .

Shukla G , Shahi V K . Poly (arylene ether ketone) copolymer grafted with amine groups containing a long alkyl chain by chloroacetylation for improved alkaline stability and conductivity of anion exchange membrane [J]. ACS Applied Energy Materials , 2018 , 1 ( 3 ): 1175 - 1182 .

Li S , Zhu X , Liu D , et al . A highly durable long side-chain polybenzimidazole anion exchange membrane for AEMFC [J]. Journal of Membrane Science , 2018 , 546 : 15 - 21 .

Li N , Wang L , Hickner M . Cross-linked comb-shaped anion exchange membranes with high base stability [J]. Chemical Communications , 2014 , 50 ( 31 ): 4092 - 4095 .

Arges C G , Zhang L . Anion exchange membranes􀆳 evolution toward high hydroxide ion conductivity and alkaline resiliency [J]. ACS Applied Energy Materials , 2018 , 1 ( 7 ): 2991 - 3012 .

Chen J , Li C , Wang J , et al . A general strategy to enhance the alkaline stability of anion exchange membranes [J]. Journal of Materials Chemistry A , 2017 , 5 ( 13 ): 6318 - 6327 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于准二维模型的PEMFC冷启动特性研究

多室微生物脱盐燃料电池的构建与脱盐产电性能优化研究

考虑扩散层表面润湿性的流道内两相流对燃料电池性能影响研究

工作温度对PEMFC水分布、质子传输及性能影响分析

基于泡沫碳扩散层的直接甲醇燃料电池改性研究