载体对铁基催化剂结构及CO<sub>2</sub>加氢制烯烃反应性能的影响特性

刘洋洋; 孙超; Singh Malhi Haripal; 位重洋; 张振洲; 涂维峰

doi:10.11949/0438-1157.20200653

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载体对铁基催化剂结构及CO₂加氢制烯烃反应性能的影响特性

催化、动力学与反应器 | 更新时间：2025-11-25

- 载体对铁基催化剂结构及CO₂加氢制烯烃反应性能的影响特性
- Effects of identities of supports on Fe-based catalyst and their consequences on activities of CO₂ hydrogenation to olefins
- 化工学报 2020年71卷第10期页码：4652-4662
- 作者机构：
  
  1.郑州大学先进功能材料制造教育部工程研究中心，河南郑州 450001
  2.郑州大学化工学院，河南郑州 450001
- 作者简介：
  
  刘洋洋（1995—），男，硕士研究生，yangyangliu_zzu51@163.com
  张振洲（1987—），男，博士，讲师，zhangzhenzhou@zzu.edu.cn
  涂维峰（1986—），男，博士，副教授，于2005.9—2013.6在重庆大学分别获得学士、硕士和博士学位，weifengtu@zzu.edu.cn
- 基金信息：
  
  国家自然科学基金项目(21606208);河南省高校科技创新团队支持计划资助(18IRTSTHN)
- DOI：10.11949/0438-1157.20200653
  中图分类号： O 643.3
- 收稿：2020-05-25，
  
  修回：2020-08-14，
  
  纸质出版：2020-10-05
- 稿件说明：
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刘洋洋, 孙超, Malhi Haripal Singh, 位重洋, 张振洲, 涂维峰. 载体对铁基催化剂结构及CO₂加氢制烯烃反应性能的影响特性[J]. 化工学报, 2020, 71(10): 4652-4662 DOI: 10.11949/0438-1157.20200653.

LIU Yangyang, SUN Chao, Singh Malhi Haripal, WEI Chongyang, ZHANG Zhenzhou, TU Weifeng. Effects of identities of supports on Fe-based catalyst and their consequences on activities of CO₂ hydrogenation to olefins[J]. CIESC Journal, 2020, 71(10): 4652-4662 DOI: 10.11949/0438-1157.20200653.
刘洋洋, 孙超, Malhi Haripal Singh, 位重洋, 张振洲, 涂维峰. 载体对铁基催化剂结构及CO₂加氢制烯烃反应性能的影响特性[J]. 化工学报, 2020, 71(10): 4652-4662 DOI: 10.11949/0438-1157.20200653. DOI：

LIU Yangyang, SUN Chao, Singh Malhi Haripal, WEI Chongyang, ZHANG Zhenzhou, TU Weifeng. Effects of identities of supports on Fe-based catalyst and their consequences on activities of CO₂ hydrogenation to olefins[J]. CIESC Journal, 2020, 71(10): 4652-4662 DOI: 10.11949/0438-1157.20200653. DOI：

摘要

铁基催化剂CO

加氢直接合成烯烃是实现CO

减排及CO

转化与利用的最佳途径之一。目前铁基催化剂的CO

加氢活性及反应过程中铁基催化剂结构强度仍然较低，成为CO

加氢制烯烃产业化生产的重要挑战。通过浸渍法制备一系列负载型铁基催化剂，研究载体材料性质对铁基催化剂结构及CO

加氢直接合成烯烃的影响特性。研究发现，载体可诱导铁基催化剂在CO

加氢反应过程中形成的铁物种，同时影响铁基催化剂表面碳物种的有序度，调变对CO

吸附及活化能力；研究结果表明ZrO

负载的Fe催化剂展现出最佳的CO

加氢合成烯烃催化性能，在温度320℃和反应压力2.0 MPa时，CO

转化率

30%，C

烃类产物中烯烃选择性高达85%以上，烯烷比为8.2，且CO选择性较低为17.1%。

Abstract

The direct synthesis of olefins by CO

hydrogenation with iron-based catalysts is one of the best ways to achieve CO

emission reduction and CO

conversion and utilization. At present

the CO

hydrogenation activity and structural strength of the iron-based catalysts are still relatively low during CO

hydrogenation process

which has become an important challenge for the industrialization of CO

hydrogenation to olefins. In this work

a series of the supported iron-based catalyst was prepared by the impregnation method to study the influence of the properties of support materials on the structure of iron-based catalysts and the reactivities of the direct synthesis of olefins from CO

hydrogenation. This work found that the support induced the iron species formed during the process of CO

hydrogenation

simultaneously affected the order degree of carbon species on the surface of iron-based catalyst

and tuned the capability of CO

adsorption and the activities of CO

activation. The results shown that the Fe-based catalyst supported on ZrO

exhibited the best catalytic performance for CO

hydrogenation to olefins at 320℃ and 2.0 MPa. The CO

conversion (

30%) and the selectivity of olefins in C

—C

hydrocarbon products were as high as over 85%

the ratio of olefins to paraffins was 8.2

and the CO selectivity was 17.1%.

关键词

Keywords

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载体对铁基催化剂结构及CO2加氢制烯烃反应性能的影响特性

Effects of identities of supports on Fe-based catalyst and their consequences on activities of CO2 hydrogenation to olefins

DOI：10.11949/0438-1157.20200653

摘要

Abstract

关键词

Keywords

references

载体对铁基催化剂结构及CO₂加氢制烯烃反应性能的影响特性

Effects of identities of supports on Fe-based catalyst and their consequences on activities of CO₂ hydrogenation to olefins