钾离子电池正极材料的研究进展

张志波; 彭琨尧; 耿茂宁; 赵昕悦; 刘思; 朱昌宝

doi:10.11949/0438-1157.20200612

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钾离子电池正极材料的研究进展

综述与专论 | 更新时间：2025-11-25

- 钾离子电池正极材料的研究进展
- Recent progress on cathode materials for potassium-ion batteries
- 化工学报 2020年71卷第10期页码：4429-4444
- 作者机构：
  
  中山大学材料科学与工程学院，广东广州 510006
- 作者简介：
  
  张志波(1995—)，男，博士研究生，zhangzhb7@mail2.sysu.edu.cn
  朱昌宝(1982—)，男，博士，教授，于2001.9—2005.6在重庆大学获得学士学位，zhuchb6@mail.sysu.edu.cn
- 基金信息：
  
  国家重点研发项目(2018YFB0905400);国家自然科学基金项目(51702376);中山大学高校基本科研业务费青年教师重点培育项目(19lgzd02);广东省珠江人才计划项目(2019QN01L117)
- DOI：10.11949/0438-1157.20200612
  中图分类号： TM 911;O 646
- 收稿：2020-05-19，
  
  修回：2020-07-28，
  
  纸质出版：2020-10-05
- 稿件说明：
移动端阅览
张志波, 彭琨尧, 耿茂宁, 赵昕悦, 刘思, 朱昌宝. 钾离子电池正极材料的研究进展[J]. 化工学报, 2020, 71(10): 4429-4444

ZHANG Zhibo, PENG Kunyao, GENG Maoning, ZHAO Xinyue, LIU Si, ZHU Changbao. Recent progress on cathode materials for potassium-ion batteries[J]. CIESC Journal, 2020, 71(10): 4429-4444
张志波, 彭琨尧, 耿茂宁, 赵昕悦, 刘思, 朱昌宝. 钾离子电池正极材料的研究进展[J]. 化工学报, 2020, 71(10): 4429-4444 DOI： 10.11949/0438-1157.20200612.

ZHANG Zhibo, PENG Kunyao, GENG Maoning, ZHAO Xinyue, LIU Si, ZHU Changbao. Recent progress on cathode materials for potassium-ion batteries[J]. CIESC Journal, 2020, 71(10): 4429-4444 DOI： 10.11949/0438-1157.20200612.

摘要

由于资源和成本优势，以及工作原理与锂离子电池的相似性，钾离子电池在未来的大规模储能应用中有着光明的发展前景。然而相比于锂、钠离子，钾离子半径较大，这不仅影响了其在电极中的输运，而且容易对电极材料的结构造成一些不可逆的破坏，进而导致较差的电化学性能。对于钾离子电池，负极可采用与锂离子电池相同的石墨负极，而正极材料是目前的研发高性能钾离子电池的关键。因此，本文在总结了最常见的四类钾离子电池正极材料的相关进展，并分别探讨了各自的优势、问题及相应的改性方法的基础上，展望了钾离子电池正极材料未来的发展。

Abstract

Due to resource and cost advantages

as well as the similarity of working principles with lithium-ion batteries

potassium-ion batteries (PIBs) have a bright future in large-scale energy storage applications. However

the ion size of potassium is larger than that of lithium and sodium ions

which not only affects the transport in the electrode

but also tends to cause irreversible damage to electrode structure

resulting poor electrochemical performance. For PIBs

the graphite that already applied in lithium-ion batteries can be used as anode

thus the cathode materials are the key to develop the high-performance potassium ion batteries. This review summarized the progress of various types of cathode materials for PIBs

and discussed their advantages

problems and corresponding modification methods. Finally

the main challenges and perspectives are also discussed to provide the future direction of cathode materials for PIBs.

关键词

Keywords

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