盐助溶液燃烧法制备MnFe<sub>2</sub>O<sub>4</sub>催化过一硫酸盐降解双酚A

岳敏; 王璟; 韩玉泽; 张萍

doi:10.11949/0438-1157.20200493

您当前的位置：

首页 >

文章列表页 >

盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A

催化、动力学与反应器 | 更新时间：2026-07-24

- 盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A
- Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis
- 化工学报 2020年71卷第12期页码：5589-5598
- 作者机构：
  
  1.山东省水环境污染控制与资源化重点实验室，山东大学环境科学与工程学院，山东青岛266237
  2.《山东大学学报（哲社版）》编辑部，山东济南 250100
  3.山东城市建设职业学院，山东济南 250103
- 作者简介：
  
  岳敏（1976—），女，博士，副教授，sduyue@sdu.edu.cn
- 基金信息：
- DOI：10.11949/0438-1157.20200493
  中图分类号： X 522
- 收稿：2020-05-06，
  
  修回：2020-08-30，
  
  网络首发：2020-12-17，
  
  纸质出版：2020-12-05
- 稿件说明：
移动端阅览
岳敏, 王璟, 韩玉泽, 张萍. 盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A[J]. 化工学报, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493.

YUE Min, WANG Jing, HAN Yuze, ZHANG Ping. Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis[J]. CIESC Journal, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493.
岳敏, 王璟, 韩玉泽, 张萍. 盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A[J]. 化工学报, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493. DOI：

YUE Min, WANG Jing, HAN Yuze, ZHANG Ping. Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis[J]. CIESC Journal, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493. DOI：

摘要

采用盐助溶液燃烧法制备磁性铁酸锰（MnFe

），催化过一硫酸氢盐（PMS）氧化降解水溶液中的双酚A。通过XRD、BET等手段对制备的铁酸锰催化剂进行了表征。探究了MnFe

投加量、PMS投加量、溶液初始pH、淬灭剂、共存离子等因素对双酚A降解效果的影响，评估了MnFe

催化剂的循环利用性能。结果表明，MnFe

和PMS的最合理投加量分别为 0.3 g/L、0.3 mmol/L，初始pH为11.0时双酚A降解效果最好，60 min内的降解率可达99.3%。淬灭实验表明，催化体系中同时存在多种活性物质，

是主要活性物种。溶液中Cl

、HCO

和HPO

等共存离子的存在影响双酚A的降解。双酚A在60 min内的TOC去除率为34.9%，苯环断裂和开环反应是其主要降解路径。MnFe

催化剂循环使用三次后，双酚A的降解率仍保持在90.0%左右。

Abstract

Magnetic manganese ferrite (MnFe

) prepared by the salt-assisted solution combustion synthesis was used to activate peroxymonosulfate(PMS) to oxidize bisphenol A in aqueous solution. The prepared MnFe

catalyst was characterized by XRD and BET. The effects of MnFe

dosage

PMS dosage

initial pH of the solution

quencher

and co-existing ions on the degradation of bisphenol A were investigated. The reusability of the MnFe

catalyst was evaluated through cycling experiments. The results showed that the best dosages of MnFe

and PMS were 0.3 g/L and 0.3 mmol/L

respectively. When the initial pH was 11.0

the degradation rate of bisphenol A was 99.3% in 60 min. When putting some quenchers into the MnFe

/PMS catalytic system

all of them showed depression effects on degradation of bisphenol A

and the

was the main active species. The co-existing ions such as Cl

HCO

and HPO

in solution affected the degradation of bisphenol A. The TOC removal rate of bisphenol A within 60 min was 34.9%

the rupture and opening of benzene ring are the main reaction pathways. After the MnFe

catalyst was recycled three times

the degradation rate of bisphenol A remained at about 90.0%.

关键词

Keywords

references

Duan X, Su C, Zhou L, et al. Surface controlled generation of reactive radicals from persulfate by carbocatalysis on nanodiamonds[J ] . Applied Catalysis B: Environmental, 2016, 194 : 7-15.

张伟. 尖晶石型铁酸锰材料制备及性能研究[D]. 南京: 南京理工大学, 2010.

Zhang W. Preparation and properties of spinet MnFe2O4[D]. Nanjing: Nanjing University of Technology, 2010.

Lackner M. Combustion Synthesis: Novel Routes to Novel Materials[M]. Bentham Science, 2010.

González-Cortés S L, Imbert F E. Fundamentals, properties and applications of solid catalysts prepared by solution combustion synthesis (SCS)[J ] . Applied Catalysis A General, 2013, 452 (Complete): 117-131.

韩少博. 盐助燃烧合成宏量制备超细ZrB2、TiB2、WC粉体及其形成机理[D]. 兰州: 兰州理工大学, 2013.

Han S B. Macroscopic quantity preparation and the formation mechanism of ultrafine ZrB2, TiB2, WC powders by salt-assisted combustion synthesis[D]. Lanzhou: Lanzhou University of Technology, 2013.

Michałowicz J. Bisphenol A—sources, toxicity and biotransformation[J ] . Environmental Toxicology and Pharmacology, 2014, 37 (2): 738-758.

Mercea P. Physicochemical processes involved in migration of bisphenol A from polycarbonate[J ] . Journal of Applied Polymer Science, 2009, 112 (2): 579-593.

Gentilcore D, Porreca I, Rizzo F, et al. Bisphenol A interferes with thyroid specific gene expression[J ] . Toxicology, 2013, 304 : 21-31.

吴皓, 孙东, 蔡卓平, 等. 双酚 A 的内分泌干扰效应研究进展[J ] . 生态科学, 2017, 36 (3): 200-206.

Wu H, Sun D, Cai Z P, et al. Advances in endocrine disrupting effects of bisphenol A[J ] . Ecological Science, 2017, 36 (3): 200-206.

Du J K, Bao J G, Liu Y, et al. Efficient activation of peroxymonosulfate by magnetic Mn-MGO for degradation of bisphenol A[J ] . Journal of Hazardous Materials, 2016, 320 : 150-159.

黄智辉, 纪志永, 陈希, 等. 过硫酸盐高级氧化降解水体中有机污染物研究进展[J ] . 化工进展, 2019, 38 (5): 2461-2470.

Huang Z H, Ji Z Y, Chen X, et al. Degradation of organic pollutants in water by persulfate advanced oxidation[J ] . Chemical Industry and Engineering Progress, 2019, 38 (5): 2461-2470.

唐海, 沙俊鹏, 欧阳龙, 等. Fe(Ⅱ)活化过硫酸盐氧化破解剩余污泥[J ] . 化工学报, 2015, 66 (2): 785-792.

Tang H, Sha J P, Ouyang L, et al. P ersulfate activated by Fe(Ⅱ) for oxidation and disintegration of excess sludge[J ] . CIESC Journal, 2015, 66 (2): 785-792.

聂明华, 徐文丽, 张文静, 等. Fe2+和零价铁活化过一硫酸盐降解酸性橙7[J ] . 环境科学学报, 2018, 38 (10): 3997-4005.

Nie M H, Xu W L, Zhang W J, et al. Degradation of acid orange 7 by peroxymonosulfate activated by Fe2+ and zerovalent iron[J ] . Acta Scientiae Circumstantiae, 2018, 38 (9): 3997-4005.

Huang G X, Wang C Y, Yang C W, et al. Degradation of bisphenol A by peroxymonosulfate catalytically activated with Mn1.8Fe1.2O4 nanospheres: synergism between Mn and Fe[J ] . Environmental Science & Technology, 2017, 51 : 12611-12618.

Ren Y, Lin L, Ma J, et al. Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe2O4 (M=Co, Cu, Mn, and Zn) as heterogeneous catalysts in the water[J ] . Applied Catalysis B: Environmental, 2015, 165 : 572-578.

李强, 唐海, 张昊楠, 等. α-Fe2O3砂芯微球制备及紫外辅助下活化PMS降解AO7[J ] . 中国环境科学, 2019, 39 (9): 3832-3839.

Li Q, Tang H, Zhang H N, et al. Preparation of α-Fe2O3 sand core microspheres for the activation of UV-assisted peroxymonosulfate on the degradation of AO7[J ] . China Environmental Science, 2019, 39 (9): 3832-3839.

骆靖宇, 李学艳, 李青松, 等. 紫外活化过硫酸钠去除水体中的三氯卡班[J ] . 中国环境科学, 2017, 37 (9): 3324-3331.

Luo J Y, Li X Y, Li Q S, et al. Degradation of triclocarban aqueous solution through UV irradiation-activated sodium persulfate process[J ] . China Environmental Science, 2017, 37 (9): 3324-3331.

李蒋, 王雁, 张秀芳, 等. Co3O4/BiVO4复合阳极活化过一硫酸盐强化光电催化降解双酚A[J ] . 环境科学, 2018, 39 (8): 3713-3718.

Li J, Wang Y, Zhang X F, et al. Enhancement of photoelectrocatalytic degradation of bisphenol A with peroxymonosulfate activated by a Co3O4/BiVO4 composite photoanode[J ] . Environmental Science, 2018, 39 (8): 3713-3718.

孙昕, 孙杰, 李鹏飞, 等. 超声活化过硫酸盐降解水中典型嗅味[J ] . 环境科学, 2019, 40 (4): 1811-1818

Sun X, Sun J, Li P F, et al. Ultrasonically activated persulfate degrades typical odors in water[J ] . Environmental Science, 2019, 40 (4): 1811-1818.

Li S, Zhang G, Wang P, et al. Microwave-enhanced Mn-Fenton process for the removal of BPA in water[J ] . Chemical Engineering Journal, 2016, 294 : 371-379.

朱思瑞, 高乃云, 鲁仙, 等. 热激活过硫酸盐氧化降解水中双酚A[J ] . 中国环境科学, 2017, 37 (1): 188-194.

Zhu S R, Gao N N, Lu X, et al. Degradation of bisphenol A in aqueous solution by thermally activated sulfate oxidation[J ] . China Environmental Science, 2017, 37 (1): 188-194.

Duan X, Sun H, Kang J, et al. Insights into heterogeneous catalysis of persulfate activation on dimensional-structured nanocarbons[J ] . ACS Catalysis, 2015, 5 : 4629-4636.

Ianoş R, Lazău I, Păcurariu C, et al. Application of new organic fuels in the direct MgAl2O4 combustion synthesis[J ] . European Journal of Inorganic Chemistry, 2008, 2008 (6): 931-938.

Li W, Li J, Guo J. Synthesis and characterization of nanocrystalline CoAl2O4 spinel powder by low temperature combustion[J ] . Journal of the European Ceramic Society, 2003, 23 (13): 2289-2295.

钱逸泰. 结晶化学导论[M]. 合肥: 中国科学技术大学出版社, 2005.

Qian Y T. Introduction to Crystalline Chemistry[M]. Hefei: China University of Science and Technology Press, 2005.

Maruthamuthu P, Neta P. Radiolytic chain decomposition of peroxomonophosphoric and peroxomonosulfuric acids[J ] . Journal of Physical Chemistry, 1977, 81 (10): 937-940.

Ooutsiou A, Frontistis Z, Ribeiro R S, et al. Activation of sodium persulfate by magnetic carbon xerogels (CX/CoFe) for the oxidation of bisphenol A: process variables effects, matrix effects and reaction pathways[J ] . Water Research, 2017, 124 : 97-107.

Anipsitakis G P, Dionysiou D D. Radical generation by the interaction of transition metals with common oxidants[J ] . Environmental Science and Technology, 2004, 38 (13): 3705-3712.

Guo H, Jiang N, Wang H, et al. Enhanced catalytic performance of graphene-TiO2 nanocomposites for synergetic degradation of fluoroquinolone antibiotic in pulsed discharge plasma system[J ] . Applied Catalysis B: Environmental, 2019, 248 : 552-566.

Liu C, Liu L Y, Tian X, et al. Coupling metal-organic frameworks and g-CN to derive Fe@N-doped graphene-like carbon for peroxymonosulfate activation: upgrading framework stability and performance[J ] . Applied Catalysis B: Environmental, 2019, 255 : 117763.

Ghanbari F, Moradi M. Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: review[J ] . Chemical Engineering Journal, 2017, 310 : 41-62.

Oh W D, Dong Z, Hu Z T, et al. A novel quasi-cubic CuFe2O4 –Fe2O3 catalyst prepared at low temperature for enhanced oxidation of bisphenol A via peroxymonosulfate activation[J ] . J. Mater. Chem. A, Royal Society of Chemistry, 2015, 3 (44): 22208-22217.

孙红文, 吕俊岗, 翟洪艳. Fenton法与光Fenton法降解2, 4-D的研究[J ] . 环境化学, 2005, 24 (4): 365-369.

Sun H W, Lyu J G, Zhai H Y. Study on degradation of 2, 4-D by Fenton and photo-Fenton reaction[J ] . Environmental Chemistry, 2005, 24 (4): 365-369.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

Cl-强化Fe（Ⅱ）/PMS体系降解PBTC同步回收磷

制备条件对改性电石渣低温共脱除COS和CS2的影响

缺陷型金属氧化物脱除气体污染物研究进展

CNT-Co/Bi2O3催化剂光催化协同过硫酸盐活化高效降解四环素

6N电子级氘气的制备与纯化技术研究

盐助溶液燃烧法制备MnFe2O4催化过一硫酸盐降解双酚A

Degradation of bisphenol A by peroxymonosulfate activated by MnFe2O4 prepared by salt-assisted solution combustion synthesis

DOI：10.11949/0438-1157.20200493

摘要

Abstract

关键词

Keywords

references

盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A

Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis