静电纺丝法制备高活性多孔Ni/SiO<sub>2</sub>甲烷化催化剂

何璐铭; 辛忠; 高文莉; 顾佳; 孟鑫

doi:10.11949/0438-1157.20200251

您当前的位置：

首页 >

文章列表页 >

静电纺丝法制备高活性多孔Ni/SiO₂甲烷化催化剂

南京大学化工学院院庆专栏 | 更新时间：2026-07-24

- 静电纺丝法制备高活性多孔Ni/SiO₂甲烷化催化剂
- Highly efficient porous Ni/SiO₂ catalysts prepared by electrospinning method for CO methanation
- 化工学报 2020年71卷第11期页码：5007-5015
- 作者机构：
  
  1.华东理工大学化工学院，上海市多相结构材料化学工程重点实验室，上海 200237
  2.华东理工大学化学工程联合国家;重点实验室，上海 200237
- 作者简介：
  
  何璐铭（1994—），男，硕士研究生，yjhyhlm@163.com
  辛忠（1962—），男，博士，教授，xzh@ecust.edu.cn
- 基金信息：
  
  国家自然科学基金项目(U1203293;21776091;21808062);中央高校基本科研业务费专项资金(22A1817025);上海市领军人才计划项目(2013)
- DOI：10.11949/0438-1157.20200251
  中图分类号： TQ 546.4
- 收稿：2020-03-12，
  
  修回：2020-06-09，
  
  网络首发：2020-11-03，
  
  纸质出版：2020-11-05
- 稿件说明：
移动端阅览
何璐铭, 辛忠, 高文莉, 顾佳, 孟鑫. 静电纺丝法制备高活性多孔Ni/SiO₂甲烷化催化剂[J]. 化工学报, 2020, 71(11): 5007-5015 DOI: 10.11949/0438-1157.20200251.

HE Luming, XIN Zhong, GAO Wenli, GU Jia, MENG Xin. Highly efficient porous Ni/SiO₂ catalysts prepared by electrospinning method for CO methanation[J]. CIESC Journal, 2020, 71(11): 5007-5015 DOI: 10.11949/0438-1157.20200251.
何璐铭, 辛忠, 高文莉, 顾佳, 孟鑫. 静电纺丝法制备高活性多孔Ni/SiO₂甲烷化催化剂[J]. 化工学报, 2020, 71(11): 5007-5015 DOI: 10.11949/0438-1157.20200251. DOI：

HE Luming, XIN Zhong, GAO Wenli, GU Jia, MENG Xin. Highly efficient porous Ni/SiO₂ catalysts prepared by electrospinning method for CO methanation[J]. CIESC Journal, 2020, 71(11): 5007-5015 DOI: 10.11949/0438-1157.20200251. DOI：

摘要

以三嵌段共聚物P123为模板剂，采用静电纺丝法制备了多孔Ni/SiO

催化剂，考察其在CO甲烷化中的催化性能。采用N

物理吸脱附测试、扫描电子显微镜（SEM）、X射线衍射（XRD）、H

-程序升温还原（H

-TPR）、透射电子显微镜（TEM）、热重分析（TGA）对催化剂的结构性质进行表征。结果表明，静电纺丝法制备的多孔Ni/SiO

催化剂活性组分Ni在SiO

载体纤维上高度分散，比表面积大，Ni颗粒尺寸小，金属与载体相互作用强，在CO甲烷化反应中表现出优异的催化活性和稳定性。在温度450℃，压力0.1 MPa，质量空速15000 ml/（g·h）条件下，多孔Ni/SiO

催化剂CO转化率最高可达96.4%，CH

选择性可达86.4%。此方法为工业上制备高催化活性且无须二次成型的甲烷化催化剂提供了新思路。

Abstract

Porous Ni/SiO

catalysts were prepared by electrospinning using P123 as template and the catalytic performance in CO methanation was evaluated. The synthesized catalyst was characterized by N

physisorption measurements

scanning electron microscopy (SEM)

X-ray diffraction (XRD)

hydrogen temperature-programmed reduction (H

-TPR)

transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The results showed that Ni particles were highly dispersed on the silica nanofibers. The presence of pore structure in electrospun fibers immensely increased the specific surface area. Moreover

the porous Ni/SiO

catalyst exhibited small particle size and strong metal-support interaction

which led to excellent catalytic activity with 96.4% CO conversion and 86.4% CH

selectivity at 450 °C under 0.1 MPa with a WHSV of 15000 ml/(g·h). The 100-hour lifetime test indicated that the porous Ni/SiO

catalyst had excellent stability. This method provides a new idea for the industrial preparation of methanation catalysts with high catalytic activity and without secondary molding.

关键词

Keywords

references

周芳 , 姜波 . 煤制天然气工艺流程优化探讨 [J ] . 化工设计 , 2016 , 26 ( 3 ): 7 - 10 .

Zhou F , Jiang B . Discussion on coal-to-natural gas process flow optimization [J ] . Chemical Engineering Design , 2016 , 26 ( 3 ): 7 - 10 .

Roensch S , Schneider J , Matthischke S , et al . Review on methanation — from fundamentals to current projects [J ] . Fuel , 2016 , 166 : 276 - 296 .

胡大成 , 高加俭 , 贾春苗 , 等 . 甲烷化催化剂及反应机理的研究进展 [J ] . 过程工程学报 , 2011 , 11 ( 5 ): 880 - 893 .

Hu D C , Gao J J , Jia C M , et al . Research advances in methanation catalysts and their catalytic mechanisms [J ] . The Chinese Journal of Process Engineering , 2011 , 11 ( 5 ): 880 - 893 .

Bai X B , Wang S , Sun T J , et al . The sintering of Ni/Al 2 O 3 methanation catalyst for substitute natural gas production [J ] . Reaction Kinetics Mechanisms and Catalysis , 2014 , 112 ( 2 ): 437 - 451 .

Bartholomew C H . Mechanisms of catalyst deactivation [J ] . Applied Catalysis A: General , 2001 , 212 ( 1/2 ): 17 - 60 .

Enger B C , Holmen A . Nickel and Fischer-Tropsch synthesis [J ] . Catalysis Reviews-Science and Engineering , 2012 , 54 ( 4 ): 437 - 488 .

Klaigaew K , Samart C , Chaiya C , et al . Effect of preparation methods on activation of cobalt catalyst supported on silica fiber for Fischer-Tropsch synthesis [J ] . Chemical Engineering Journal , 2015 , 278 : 166 - 173 .

Mhadmhan S , Natewong P , Prasongthum N , et al . Investigation of Ni/SiO 2 fiber catalysts prepared by different methods on hydrogen production from ethanol steam reforming [J ] . Catalysts , 2018 , 8 ( 8 ): 1 - 18 .

Ren J , Li H D , Jin Y Y , et al . Silica/titania composite-supported Ni catalysts for CO methanation: effects of Ti species on the activity, anti-sintering, and anti-coking properties [J ] . Applied Catalysis B: Environmental , 2017 , 201 : 561 - 572 .

Jin G J , Gu F N , Liu Q , et al . Highly stable Ni/SiC catalyst modified by Al 2 O 3 for CO methanation reaction [J ] . RSC Advances , 2016 , 6 ( 12 ): 9631 - 9639 .

张加赢 , 辛忠 , 孟鑫 , 等 . 基于MCM-41的镍基甲烷化催化剂活性与稳定性 [J ] . 化工学报 , 2014 , 65 ( 1 ): 160 - 168 .

Zhang J Y , Xin Z , Meng X , et al . Activity and stability of nickel based MCM-41 methanation catalysts for production of synthetic natural gas [J ] . CIESC Journal , 2014 , 65 ( 1 ): 160 - 168 .

Tao M , Meng X , Xin Z , et al . Synthesis and characterization of well dispersed nickel-incorporated SBA-15 and its high activity in syngas methanation reaction [J ] . Applied Catalysis A: General , 2016 , 516 : 127 - 134 .

Cheng C B , Shen D K , Xiao R , et al . Methanation of syngas (H 2 /CO) over the different Ni-based catalysts [J ] . Fuel , 2017 , 189 : 419 - 427 .

Zeng Y , Ma H F , Zhang H T , et al . Highly efficient NiAl 2 O 4 -free Ni/γ-Al 2 O 3 catalysts prepared by solution combustion method for CO methanation [J ] . Fuel , 2014 , 137 : 155 - 163 .

Xue J J , Xie J W , Liu W Y , et al . Electrospun nanofibers: new concepts, materials, and applications [J ] . Accounts of Chemical Research , 2017 , 50 ( 8 ): 1976 - 1987 .

刘力菲 , 李伟 , 黄潇楠 . 静电纺丝纳米纤维的制备与应用 [J ] . 首都师范大学学报(自然科学版) , 2017 , 38 ( 1 ): 58 - 63 .

Liu L F , Li W , Huang X N . Preparation and application of the electrospinning nanofibers [J ] . Journal of Capital Normal University (Natural Science Edition) , 2017 , 38 ( 1 ): 58 - 63 .

Zou R , Wen S P , Zhang L Q , et al . Preparation of Rh-SiO 2 fiber catalyst with superior activity and reusability by electrospinning [J ] . RSC Advances , 2015 , 5 ( 121 ): 99884 - 99891 .

Li W H , Zhang A F , Jiang X , et al . The anti-sintering catalysts: Fe-Co-Zr polymetallic fibers for CO 2 hydrogenation to C 2 = -C 4 = -rich hydrocarbons [J ] . Journal of CO 2 Utilization , 2018 , 23 : 219 - 225 .

Zhao Y Y , Wang H Y , Lu X F , et al . Fabrication of refining mesoporous silica nanofibers via electrospinning [J ] . Materials Letters , 2008 , 62 ( 1 ): 143 - 146 .

Wang X Q , Dou L Y , Yang L , et al . Hierarchical structured MnO 2 @SiO 2 nanofibrous membranes with superb flexibility and enhanced catalytic performance [J ] . Journal of Hazardous Materials , 2017 , 324 : 203 - 212 .

辛忠 , 何璐铭 , 孟鑫 . 一种镍基纯硅型分子筛催化剂及其制备方法与应用 : 202010147006.7 [P ] . 2020-03-05 .

Xin Z , He L M , Meng X . A nickel-based pure silicon molecular sieve catalyst and its preparation and application : 202010147006.7 [P ] . 2020-03-05 .

Kang H G , Zhu Y H , Yang X L , et al . A novel catalyst based on electrospun silver-doped silica fibers with ribbon morphology [J ] . Journal of Colloid and Interface Science , 2010 , 341 ( 2 ): 303 - 310 .

Fang C , Zhang D S , Shi L Y , et al . Highly dispersed CeO 2 on carbon nanotubes for selective catalytic reduction of NO with NH 3 [J ] . Catalysis Science & Technology , 2013 , 3 ( 3 ): 803 - 811 .

Guo X Z , Yang H , Cao M . Nucleation and crystallization behavior of Li 2 O-Al 2 O 3 -SiO 2 system glass-ceramic containing little fluorine and no-fluorine [J ] . Journal of Non-Crystalline Solids , 2005 , 351 ( 24/25/26 ): 2133 - 2137 .

赵醒 , 胡彦杰 , 蒋洁超 , 等 . 过渡金属原位掺杂Pt/TiO 2 的喷雾燃烧制备及其CO氧化性能 [J ] . 华东理工大学学报(自然科学版) , 2018 , 44 ( 6 ): 823 - 830 .

Zhao X , Hu Y J , Jiang J C , et al . Transition metal in situ doping Pt/TiO 2 by flame spray pyrolysis for CO oxidation [J ] . Journal of East China University of Science and Technology (Natural Science Edition) , 2018 , 44 ( 6 ): 823 - 830 .

Zhao B R , Chen Z P , Chen Y J , et al . Syngas methanation over Ni/SiO 2 catalyst prepared by ammonia-assisted impregnation [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 44 ): 27073 - 27083 .

Gao J J , Wang Y L , Ping Y , et al . A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas [J ] . RSC Advances , 2012 , 2 ( 6 ): 2358 - 2368 .

Borodko Y , Somorjai G A . Catalytic hydrogenation of carbon oxides — a 10-year perspective [J ] . Applied Catalysis A: General , 1999 , 186 ( 1/2 ): 355 - 362 .

Tao M , Xin Z , Meng X , et al . Highly dispersed nickel within mesochannels of SBA-15 for CO methanation with enhanced activity and excellent thermostability [J ] . Fuel , 2017 , 188 : 267 - 276 .

Shinde V M , Madras G . CO methanation toward the production of synthetic natural gas over highly active Ni/TiO 2 catalyst [J ] . AIChE Journal , 2014 , 60 ( 3 ): 1027 - 1035 .

Liu S S , Jin Y Y , Han Y , et al . Highly stable and coking resistant Ce promoted Ni/SiC catalyst towards high temperature CO methanation [J ] . Fuel Processing Technology , 2018 , 177 : 266 - 274 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

蒸氨时间对Cu/SiO2催化草酸二甲酯加氢制乙二醇反应性能的影响

空气驱动的膜电解技术促进硅灰石矿化CO2产白炭黑的研究

Si掺杂对Cu/ZrO2催化CO2加氢制甲醇性能的影响

SiO2@BiOCl-Bi24O31Cl10核壳微球的合成及光催化

纤维状BPO4/SiO2催化剂的制备及其丙烷氧化脱氢性能

静电纺丝法制备高活性多孔Ni/SiO2甲烷化催化剂

Highly efficient porous Ni/SiO2 catalysts prepared by electrospinning method for CO methanation

DOI：10.11949/0438-1157.20200251

摘要

Abstract

关键词

Keywords

references

静电纺丝法制备高活性多孔Ni/SiO₂甲烷化催化剂

Highly efficient porous Ni/SiO₂ catalysts prepared by electrospinning method for CO methanation