无患子果皮提取物的纳微米聚集体对钢的高效缓蚀

罗雪; 黄海军; 罗自萍; 王治永; 穆小静; 李红茹; 王新潮; 张胜涛; 高放

doi:10.11949/0438-1157.20200065

您当前的位置：

首页 >

文章列表页 >

无患子果皮提取物的纳微米聚集体对钢的高效缓蚀

表面与界面工程 | 更新时间：2025-11-25

- 无患子果皮提取物的纳微米聚集体对钢的高效缓蚀
- High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts
- 化工学报 2020年71卷第10期页码：4760-4772
- 作者机构：
  
  1.重庆大学化学化工学院，重庆 400044
  2.菏泽学院药学院，山东菏泽 274015
- 作者简介：
  
  罗雪（1994—），女，硕士研究生，xueluo1994@163.com
  黄海军（1993—），男，博士研究生，hhjbfn@163.com
  高放（1971—），男，博士，教授，fanggao1971@gmail.com
- 基金信息：
  
  国家自然科学基金项目(21376282;21676035;21878029);重庆大学研究生创新基金资助项目(CYB18046);中国博士后科学基金项目(22012T50762;2011M501388);重庆市自然科学基金项目(cstc2018jcyjAX0668)
- DOI：10.11949/0438-1157.20200065
  中图分类号： TG 178
- 收稿：2020-01-16，
  
  修回：2020-04-13，
  
  纸质出版：2020-10-05
- 稿件说明：
移动端阅览
罗雪, 黄海军, 罗自萍, 王治永, 穆小静, 李红茹, 王新潮, 张胜涛, 高放. 无患子果皮提取物的纳微米聚集体对钢的高效缓蚀[J]. 化工学报, 2020, 71(10): 4760-4772

LUO Xue, HUANG Haijun, LUO Ziping, WANG Zhiyong, MU Xiaojing, LI Hongru, WANG Xinchao, ZHANG Shengtao, GAO Fang. High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts[J]. CIESC Journal, 2020, 71(10): 4760-4772
罗雪, 黄海军, 罗自萍, 王治永, 穆小静, 李红茹, 王新潮, 张胜涛, 高放. 无患子果皮提取物的纳微米聚集体对钢的高效缓蚀[J]. 化工学报, 2020, 71(10): 4760-4772 DOI： 10.11949/0438-1157.20200065.

LUO Xue, HUANG Haijun, LUO Ziping, WANG Zhiyong, MU Xiaojing, LI Hongru, WANG Xinchao, ZHANG Shengtao, GAO Fang. High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts[J]. CIESC Journal, 2020, 71(10): 4760-4772 DOI： 10.11949/0438-1157.20200065.

摘要

为寻求绿色、可持续与具备大规模应用潜能的天然植物提取物作为缓蚀剂，选择具有表面活性剂性质的无患子果皮提取物作为研究对象。通过简便乙醇回流萃取获得无患子果皮提取物。在室温条件下，无患子果皮提取物在DMF（

，

-二甲基甲酰胺）/HCl水溶液的混合溶液（体积比50/50，1.0 mol/L HCl 溶液）中能够发生自组装产生有序的纳微米聚集材料。傅里叶变换红外光谱（FT-IR）与X射线光电子能谱（XPS）研究表明了无患子果皮提取物聚集体能够对Q235钢表面产生化学吸附作用。利用电化学方法研究了无患子果皮提取物聚集体吸附在钢表面后，在1.0 mol/L盐酸水溶液中的缓蚀性能。结果表明无患子果皮提取物聚集体能够有效抑制钢被盐酸腐蚀，最大缓蚀效率达到90%以上。

Abstract

To seek green

sustainable and natural plant extracts with the potential for large-scale application as corrosion inhibitors

this article selects the extracts of the

Sapindus mukorossi Gaertn

peels with surfactant properties as the research object. Hence

this article uses

Sapindus mukorossi Gaertn

peel extracts (SMGPE) with surfactant properties as the study candidate. This survey presents efficient extraction of

Sapindus mukorossi Gaertn

peels by simply refluxing ethanol solution. It is shown that SMGPE can process orderly nano-micro meters aggregation in DMF/HCl (volume ratio: 50/50

1.0 mol/L HCl solution) mixed solution through self-organization at the room temperature.The results show that the predominantly strong chemical adsorption of formed SMGPE aggregates on the studied Q235 steel specimens is suggested through the detection of FT-IR

Raman as well as XPS spectroscopy. This study further determines the corrosion inhibition effect of the stable SMGPE aggregates for the studied steel specimens in 1.0 mol/L HCl aqueous solution based on electrochemical method. The results suggest that the SMGPE aggregates can inhibit corrosion of the steel specimens in HCl solution efficiently

and the greatest corrosion inhibition efficiency is over 90%.

关键词

Keywords

references

Wang H , Akid R . Encapsulated cerium nitrate inhibitors to provide high-performance anti-corrosion sol-gel coatings on mild steel [J]. Corrosion Science , 2008 , 50 : 1142 - 1148 .

Yu J , Zhang Y , Jin X , et al . Fabrication and optical emission spectroscopy of enhanced corrosion-resistant CPEO films on Q235 low carbon steel [J]. Surface and Coatings Technology , 2019 , 363 : 411 - 418 .

Yi C . Corrosion inhibition effect of 2-hydroxy phosphonoacetic acid and pyrophosfate on Q235 steel, electrochemical noise and EIS analysis [J]. International Journal of Electrochemical Science , 2019 , 14 : 6759 - 6772 .

Wang C . Synthesis, crystal structure and corrosion inhibition effect of s-benzyl- O , O '-bis( p - tert -butyl phenyl)dithiophosphate for Q235 steel in 1.0 M HCl [J]. International Journal of Electrochemical Science , 2019 , 31 ( 6 ): 3443 - 3454 .

Guo L , Obot I B , Zheng X W , et al . Theoretical insight into an empirical rule about organic corrosion inhibitors containing nitrogen, oxygen, and sulfur atoms [J]. Applied Surface Science , 2017 , 406 : 301 - 306 .

Qiang Y J , Fu S L , Zhang S T , et al . Designing and fabricating of single and double alkyl-chain indazole derivatives self-assembled monolayer for corrosion inhibition of copper [J]. Corrosion Science , 20181 , 40 : 111 - 121 .

Qiang Y J , Zhang S T , Tan B , et al . Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution [J]. Corrosion Science , 2018 , 133 : 6 - 16 .

Umoren S A . Biomaterials for corrosion protection: evaluation of mustard seed extract as eco-friendly corrosion inhibitor for X60 steel in acid media [J]. Journal of Adhesion Science and Technology , 2016 , 30 : 1858 - 1879 .

Li L , Xu W , Lei J , et al . Experimental and theoretical investigations of Michelia alba leaves extract as a green highly-effective corrosion inhibitor for different steel materials in acidic solution [J]. RSC Advances , 2015 , 5 : 93724 - 93732 .

Mobin M , Aslam R , Zehra S , et al . Bio-/environment-friendly cationic gemini surfactant as novel corrosion inhibitor for mild steel in 1 M HCl solution [J]. Journal of Surfactants and Detergents , 2016 , 20 : 57 - 74 .

El Achouri M , Kertit S , Gouttaya H M , et al . Corrosion inhibition of iron in 1 M HCl by some gemini surfactants in the series of alkanediyl-α, ω-bis-(dimethyl tetradecyl ammonium bromide) [J]. Progress in Organic Coatings , 2001 , 43 : 267 - 273 .

Huang H C , Liao S C , Chang F R , et al . Molluscicidal saponins from apindus mukorossi, inhibitory agents of golden apple snails, pomacea canaliculata [J]. Journal of Food Agriculture and Environment , 2003 , 51 : 4916 - 4919 .

魏敏平 . 无患子抑菌成分的分离纯化及其应用研究 [D]. 无锡 : 江南大学 , 2018 .

Wei M P . Study on the separation and purification of antibacterial components from Sapindus mukurossi and its application [D]. Wuxi : Jiangnan University , 2018 .

徐圆圆 , 贾黎明 , 陈仲 , 等 . 无患子三萜皂苷研究进展 [J]. 化学通报 , 2018 , 12 ( 81 ): 1078 - 1088 .

Xu Y Y , Jia L M , Chen Z , et al . Advances on Triterpenoid Saponin of Sapindus mukorossi [J]. Chemistry , 2018 , 12 ( 81 ): 1078 - 1088 .

周礼彬 . 川滇无患子总皂苷化学成分及表面活性的应用性能研究 [D]. 昆明 : 云南中医学院 , 2017 .

Zhou L B . Study on the chemical components and the application of surface active properties of the total saponins from sapindus delavayi [D]. Kunming : Yunnan University of Traditional Chinese Medicine , 2017 .

Li X , Deng S , Fu H . Inhibition of the corrosion of steel in HCl, H 2 SO 4 solutions by bamboo leaf extract [J]. Corrosion Science , 2012 , 62 : 163 - 175 .

Chidiebere M A , Oguzie E E , Liu L , et al . Ascorbic acid as corrosion inhibitor for Q235 mild steel in acidic environments [J]. Journal of Industrial and Engineering Chemistry , 2015 , 26 : 182 - 192 .

Mallaiya K , Subramaniam R , Srikandan S S , et al . Electrochemical characterization of the protective film formed by the unsymmetrical Schiff's base on the mild steel surface in acid media [J]. Electrochimica. Acta , 2011 , 56 : 3857 - 3863 .

Zarrouk A , Hammouti B , Lakhlifi T , et al . New 1 H -pyrrole-2, 5-dione derivatives as efficient organic inhibitors of carbon steel corrosion in hydrochloric acid medium: electrochemical, XPS and DFT studies [J]. Corrosion Science , 2015 , 90 : 572 - 584 .

Kharbach Y , Qachchachi F Z , Haoudi A , et al . Anticorrosion performance of three newly synthesized isatin derivatives on carbon steel in hydrochloric acid pickling environment: electrochemical, surface and theoretical studies [J]. Journal of Molecular Liquids , 2017 , 246 : 302 - 316 .

Bouanis M , Tourabi M , Nyassi A , et al . Corrosion inhibition performance of 2, 5-bis(4-dimethylaminophenyl)-1, 3, 4-oxadiazole for carbon steel in HCl solution: gravimetric, electrochemical and XPS studies [J]. Applied Surface Science , 2016 , 389 : 952 - 966 .

Boumhara K , Tabyaoui M , Jama C , et al . Artemisia Mesatlantica essential oil as green inhibitor for carbon steel corrosion in 1 M HCl solution: electrochemical and XPS investigations [J]. Journal of Industrial and Engineering Chemistry , 2015 , 29 : 146 - 155 .

Ji G , Anjum S , Sundaram S , et al . Musa paradisica peel extract as green corrosion inhibitor for mild steel in HCl solution [J]. Corrosion Science , 2015 , 90 : 107 - 117 .

Hussin M H , Jain K M , Razali N N , et al . The effect of Tinospora crispa extracts as a natural mild steel corrosion inhibitor in 1 M HCl solution [J]. Arabian Journal of Chemistry , 2016 , 9 : 616 - 624 .

Singh A K , Quraishi M A . Investigation of adsorption of isoniazid derivatives at mild steel/hydrochloric acid interface: electrochemical and weight loss methods [J]. Materials Chemistry and Physics , 2010 , 123 : 666 – 677 .

Sudheer , Quraishi M A . Electrochemical and theoretical investigation of triazole derivatives on corrosion inhibition behavior of copper in hydrochloric acid medium [J]. Corrosion Science , 2013 , 70 : 161 - 169 .

Huang H J , Fu Y , Li F , et al . Orderly self-assembly of new ionic copolymers for efficiently protecting copper in aggressive sulfuric acid solution [J]. Chemical Engineering Journal , 2020 , 384 : 123293 .

Wang Z Q , Gong Y L , Zhang L , et al . Self-assembly of new dendrimers basing on strong π-π intermolecular interaction for application to protect copper [J]. Chemical Engineering Journal , 2018 , 342 : 238 - 250 .

Ostovari A , Hoseinieh S M , Peikari M , et al . Corrosion inhibition of mild steel in 1 M HCl solution by henna extract: a comparative study of the inhibition by henna and its constituents (Lawsone, Gallic acid, α-d-Glucose and Tannic acid) [J]. Corrosion Science , 2009 , 51 : 1935 - 1949 .

Sığırcık G , Yildirim D , Tüken T . Synthesis and inhibitory effect of N , N '-bis(1-phenylethanol)ethylenediamine against steel corrosion in HCl media [J]. Corrosion Science , 2017 , 120 : 184 - 193 .

Li L , Zhang X , Lei J , et al . Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel [J]. Corrosion Science , 2012 , 63 : 82 - 90 .

Biswas A , Pal S , Udayabhanu G . Experimental and theoretical studies of Xanthan gum and its graft co-polymer as corrosion inhibitor for mild steel in 15% HCl [J]. Applied Surface Science , 2015 , 353 : 173 - 183 .

Chauhan D S , Ansari K R , Sorour A A , et al . Thiosemicarbazide and thiocarbohydrazide functionalized chitosan as ecofriendly corrosion inhibitors for carbon steel in hydrochloric acid solution [J]. International Journal of Biological Macromolecules , 2018 , 107 : 1747 - 1757 .

Hu Z , Meng Y , Ma X , et al . Experimental and theoretical studies of benzothiazole derivatives as corrosion inhibitors for carbon steel in 1 M HCl [J]. Corrosion Science , 2016 , 112 : 563 - 575 .

Obot I B , Obi-Egbedi N O . Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation [J]. Corrosion Science , 2010 , 52 : 198 - 204 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

规整有机分子自聚集体对铜的高效缓蚀的研究

磁处理与缓蚀剂2-巯基苯并噻唑结合对铜的缓蚀效能与机理

弱磁场强化零价铁对水中U(Ⅵ)去除效能

4种吡嗪类缓蚀剂及其在Cu(111)面吸附行为的密度泛函理论研究

噻二唑衍生物分子结构与其缓蚀性能的关系