1. 天津大学化工学院绿色化学化工教育部重点实验室,天津 300072
2. 天津化学化工协同创新中心,天津 300072
3. 天津大学-新加坡国立大学福州联合学院,福建 福州 350207
4. 中海油天津化工研究设计院有限公司 天津 300131
张鹏(1995—),男,硕士研究生,2118207042@tju.edu.cn
姜忠义(1966—),男,博士,教授,zhyjiang@tju.edu.cn
收稿:2019-11-13,
修回:2019-11-20,
网络首发:2020-08-12,
纸质出版:2020-01-05
移动端阅览
张鹏, 陈赞, 吴洪, 张润楠, 杨磊鑫, 游昕达, 安珂, 姜忠义. 石墨烯基CO2分离膜通道微环境调控研究进展[J]. 化工学报, 2020, 71(1): 54-67 DOI: 10.11949/0438-1157.20191376.
ZHANG Peng, CHEN Zan, WU Hong, ZHANG Runnan, YANG Leixin, YOU Xinda, AN Ke, JIANG Zhongyi. Progress in research on channel microenvironment regulation of graphene-based CO2 separation membrane[J]. CIESC Journal, 2020, 71(1): 54-67 DOI: 10.11949/0438-1157.20191376.
张鹏, 陈赞, 吴洪, 张润楠, 杨磊鑫, 游昕达, 安珂, 姜忠义. 石墨烯基CO2分离膜通道微环境调控研究进展[J]. 化工学报, 2020, 71(1): 54-67 DOI: 10.11949/0438-1157.20191376. DOI:
ZHANG Peng, CHEN Zan, WU Hong, ZHANG Runnan, YANG Leixin, YOU Xinda, AN Ke, JIANG Zhongyi. Progress in research on channel microenvironment regulation of graphene-based CO2 separation membrane[J]. CIESC Journal, 2020, 71(1): 54-67 DOI: 10.11949/0438-1157.20191376. DOI:
石墨烯作为一种具有单原子层厚度的二维纳米片,凭借石墨烯基独特的物理性质,已成为高性能碳捕集膜的构筑单元。石墨烯基纳米片超薄的厚度有助于制备超薄膜以提升分离膜的通量,此外可调的物理化学性质赋予石墨烯二维通道内多样的微环境。以CO
2
分离膜内多重传质机理为出发点,重点介绍近年来石墨烯基CO
2
分离膜二维通道物理化学微环境精密调控的策略及进展,期望对石墨烯基CO
2
分离膜的理性设计和可控制备提供清晰思路。
Graphene
as a two-dimensional nanosheet with the thickness of monoatomic layer
has become a unit of high-performance carbon capture membranes due to its unique physical property. The ultrathin thickness of graphene-based membranes is conducive to the preparation of ultrathin membranes in order to improve the flux of separation membranes. Upon that
the adjustable physicochemical property endows multiple microenvironment within the two-dimensional channel of graphene. In view of the multiple mass transfer mechaisms of CO
2
separation membranes
it highlights the strategies and progress of precision controllable of physiochemical microenviroment within the two-dimensional channel of graphene in recent years. Expecting to provide a clear thinking for the reasonable design and controllable equipment of graphene-based CO
2
separation membranes.
Grätzel M . Mesoscopic solar cells for electricity and hydrogen production from sunlight [J ] . Chemistry Letters , 2004 , 34 ( 1 ): 8 - 13 .
Seneviratne S I , Donat M G , Pitman A J , et al . Allowable CO 2 emissions based on regional and impact-related climate targets [J ] . Nature , 2016 , 529 ( 7587 ): 477 .
Sholl D S , Lively R P . Seven chemical separations to change the world [J ] . Nature News , 2016 , 532 ( 7600 ): 435 .
Schnoor J L . Ocean acidification: the other problem with CO 2 [J ] . Environmental Science & Technology , 2014 , 48 : 10529-10530 .
Stauffer P H , Keating G N , Middleton R S , et al . Greening coal: breakthroughs and challenges in carbon capture and storage [J ] . Environmental Science & Technology , 2011 , 45 : 8597 - 8604 .
Hunt A J , Sin E H K , Marriott R , et al . Generation, capture, and utilization of industrial carbon dioxide [J ] . ChemSusChem: Chemistry & Sustainability Energy & Materials , 2010 , 3 ( 3 ): 306 - 322 .
Quadrelli R , Peterson S . The energy-climate challenge: recent trends in CO 2 emissions from fuel combustion [J ] . Environmental Science & Technology , 2007 , 35 ( 11 ): 5938 - 5952 .
Li S , Jiang X , Yang X , et al . Nanoporous framework “reservoir” maximizing low-molecular-weight enhancer impregnation into CO 2 -philic membranes for highly-efficient CO 2 capture [J ] . Journal of Membrane Science , 2019 , 570 : 278 - 285 .
Feely R A , Kleypas J A . Ocean acidification: the other CO 2 problem [J ] . Annual Review of Marine Science , 2009 , 1 : 169 - 191 .
Rashidi F , Leisen J , Kim S J , et al . All-nanoporous hybrid membranes: redefining upper limits on molecular separation properties [J ] . Angewandte Chemie International Edition , 2019 , 58 ( 1 ): 236 - 239 .
Alyobi M M M , Barnett C J , Rees P , et al . Modifying the electrical properties of graphene by reversible point-ripple formation [J ] . Carbon , 2019 , 143 : 762 - 768 .
Bagotia N , Choudhary V , Sharma D K . Synergistic effect of graphene/multiwalled carbon nanotube hybrid fillers on mechanical, electrical and EMI shielding properties of polycarbonate/ethylene methyl acrylate nanocomposites [J ] . Composites Part B: Engineering , 2019 , 159 : 378 - 388 .
Han S , Meng Q , Araby S , et al . Mechanical and electrical properties of graphene and carbon nanotube reinforced epoxy adhesives: experimental and numerical analysis [J ] . Composites Part A: Applied Science and Manufacturing , 2019 , 120 : 116 - 126 .
Puértolas J A , Castro M , Morris J A , et al . Tribological and mechanical properties of graphene nanoplatelet/PEEK composites [J ] . Carbon , 2019 , 141 : 107 - 122 .
Wang S , Wu Y , Zhang N , et al . A highly permeable graphene oxide membrane with fast and selective transport nanochannels for efficient carbon capture [J ] . Energy & Environmental Science , 2016 , 9 ( 10 ): 3107 - 3112 .
Martini L , Chen Z , Mishra N , et al . Structure-dependent electrical properties of graphene nanoribbon devices with graphene electrodes [J ] . Carbon , 2019 , 146 : 36 - 43 .
Qian C , Zhu T , Zheng W , et al . Improving dielectric properties and thermostability of CaCu 3 Ti 4 O 12 /polyimide composites by employing surface hydroxylated CaCu 3 Ti 4 O 12 particles [J ] . ACS Applied Polymer Materials , 2019 , 1 ( 6 ): 1263 - 1271 .
Li H , Song Z , Zhang X , et al . Ultrathin, molecular-sieving graphene oxide membranes for selective hydrogen separation [J ] . Science , 2013 , 342 ( 6154 ): 95 - 98 .
Novoselov K S , Geim A K , Morozov S V , et al . Electric field effect in atomically thin carbon films [J ] . Science , 2004 , 306 ( 5696 ): 666 - 669 .
Zhang C , Zhang W , Mu Y , et al . Facile fabrication of holey graphene oxide paper bonded with sulfonic acid for highly efficient proton conduction [J ] . Ionics , 2019 , 25 ( 2 ): 573 - 581 .
田甜 , 吕敏 , 田旸 , 等 . 石墨烯的生物安全性研究进展 [J ] . 科学通报 , 2014 , 59 ( 20 ): 1 .
Tian T , Lyu M , Tian Y , et al . Research progress on biosafety of graphene [J ] . Science Bulletin , 2014 , 59 ( 20 ): 1 .
Choi K , Droudian A , Wyss R M , et al . Multifunctional wafer-scale graphene membranes for fast ultrafiltration and high permeation gas separation [J ] . Science Advances , 2018 , 4 ( 11 ): eaau0476 .
Liu Y , Su Y , Guan J , et al . 2D heterostructure membranes with sunlight-driven self-cleaning ability for highly efficient oil-water separation [J ] . Advanced Functional Materials , 2018 , 28 ( 13 ): 1706545 .
Yang J , Gong D , Li G , et al . Self-assembly of thiourea-crosslinked graphene oxide framework membranes toward separation of small molecules [J ] . Advanced Materials , 2018 , 30 ( 16 ): 1705775 .
Han S , Sun J , He S , et al . The application of graphene-based biomaterials in biomedicine [J ] . American Journal of Translational Research , 2019 , 11 ( 6 ): 3246 .
Li H , Song Z , Zhang X , et al . Ultrathin, molecular-sieving graphene oxide membranes for selective hydrogen separation [J ] . Science , 2013 , 342 ( 6154 ): 95 - 98 .
Deng B , Liu Z , Peng H . Toward mass production of CVD graphene films [J ] . Advanced Materials , 2019 , 31 ( 9 ): 1800996 .
Lin L , Peng H , Liu Z . Synthesis challenges for graphene industry [J ] . Nature Materials , 2019 , 18 ( 6 ): 520 .
Yang K , Huang L , Wang Y , et al . Graphene oxide/nanometal composite membranes for nanofiltration: synthesis, mass transport mechanism, and applications [J ] . New Journal of Chemistry , 2019 , 43 ( 7 ): 2846 - 2860 .
Mi B . Graphene oxide membranes for ionic and molecular sieving [J ] . Science , 2014 , 343 ( 6172 ): 740 - 742 .
Pramanik N B , Regen S L . Layer-by-layer assembly of a polymer of intrinsic microporosity: targeting the CO 2 /N 2 separation problem [J ] . Chemical Communications , 2019 , 55 ( 30 ): 4347 - 4350 .
He G , Huang S , Villalobos L F , et al . High-permeance polymer-functionalized single-layer graphene membranes that surpass the postcombustion carbon capture target [J ] . Energy & Environmental Science , 2019 , 12 : 3305 - 3312 .
Sun C , Wen B , Bai B . Application of nanoporous graphene membranes in natural gas processing: molecular simulations of CH 4 /CO 2 , CH 4 /H 2 S and CH 4 /N 2 separation [J ] . Chemical Engineering Science , 2015 , 138 : 616 - 621 .
Shan M , Xue Q , Jing N , et al . Influence of chemical functionalization on the CO 2 /N 2 separation performance of porous graphene membranes [J ] . Nanoscale , 2012 , 4 ( 17 ): 5477 - 5482 .
Zhao J , Zhao X , Jiang Z , et al . Biomimetic and bioinspired membranes: preparation and application [J ] . Progress in Polymer Science , 2014 , 39 ( 9 ): 1668 - 1720 .
Kumar M , Grzelakowski M , Zilles J , et al . Highly permeable polymeric membranes based on the incorporation of the functional water channel protein Aquaporin Z [J ] . Proceedings of the National Academy of Sciences , 2007 , 104 ( 52 ): 20719 - 20724 .
Cao L , He X , Jiang Z , et al . Channel-facilitated molecule and ion transport across polymer composite membranes [J ] . Chemical Society Reviews , 2017 , 46 ( 22 ): 6725 - 6745 .
Su Y , Kravets V G , Wong S L , et al . Impermeable barrier films and protective coatings based on reduced graphene oxide [J ] . Nature Communications , 2014 , 5 : 4843 .
Shen J , Zhang M , Liu G , et al . Facile tailoring of the two-dimensional graphene oxide channels for gas separation [J ] . RSC Advances , 2016 , 6 ( 59 ): 54281 - 54285 .
Kim H W , Yoon H W , Yoon S M , et al . Selective gas transport through few-layered graphene and graphene oxide membranes [J ] . Science , 2013 , 342 ( 6154 ): 91 - 95 .
Yeh C N , Raidongia K , Shao J , et al . On the origin of the stability of graphene oxide membranes in water [J ] . Nature Chemistry , 2015 , 7 ( 2 ): 166 .
Hung W S , Tsou C H , De Guzman M , et al . Cross-linking with diamine monomers to prepare composite graphene oxide-framework membranes with varying d-spacing [J ] . Chemistry of Materials , 2014 , 26 ( 9 ): 2983 - 2990 .
Ma S , Tang Z , Fan Y , et al . Surfactant-modified graphene oxide membranes with tunable structure for gas separation [J ] . Carbon , 2019 , 152 : 144 - 150 .
Robeson L M . The upper bound revisited [J ] . Journal of Membrane Science , 2008 , 320 ( 1 / 2 ): 390 - 400 .
Wong K C , Goh P S , Ismail A F . Gas separation performance of thin film nanocomposite membranes incorporated with polymethyl methacrylate grafted multi-walled carbon nanotubes [J ] . International Biodeterioration & Biodegradation , 2015 , 102 : 339 - 345 .
Zhao Y , Jung B T , Ansaloni L , et al . Multiwalled carbon nanotube mixed matrix membranes containing amines for high pressure CO 2 /H 2 separation [J ] . Journal of Membrane Science , 2014 , 459 : 233 - 243 .
Shen J , Liu G , Huang K , et al . Membranes with fast and selective gas-transport channels of laminar graphene oxide for efficient CO 2 capture [J ] . Angewandte Chemie International Edition , 2015 , 127 ( 2 ): 588 - 592 .
Park H B , Kamcev J , Robeson L M , et al . Maximizing the right stuff: the trade-off between membrane permeability and selectivity [J ] . Science , 2017 , 356 ( 6343 ): eaab0530 .
Karunakaran M , Shevate R , Kumar M , et al . CO 2 -selective PEO-PBT (PolyActive™)/graphene oxide composite membranes [J ] . Chemical Communications , 2015 , 51 ( 75 ): 14187 - 14190 .
Shen J , Zhang M , Liu G , et al . Size effects of graphene oxide on mixed matrix membranes for CO 2 separation [J ] . AIChE Journal , 2016 , 62 ( 8 ): 2843 - 2852 .
Quan S , Li S W , Xiao Y C , et al . CO 2 -selective mixed matrix membranes (MMMs) containing graphene oxide (GO) for enhancing sustainable CO 2 capture [J ] . International Journal of Greenhouse Gas Control , 2017 , 56 : 22 - 29 .
Dai Z , Noble R D , Gin D L , et al . Combination of ionic liquids with membrane technology: a new approach for CO 2 separation [J ] . Journal of Membrane Science , 2016 , 497 : 1 - 20 .
Li X , Cheng Y , Zhang H , et al . Efficient CO 2 capture by functionalized graphene oxide nanosheets as fillers to fabricate multipermselective mixed matrix membranes [J ] . ACS Appl . Mater . Interfaces , 2015 , 7 : 5528 - 5537 .
Ali A , Pothu R , Siyal S H , et al . Graphene-based membranes for CO 2 separation [J ] . Materials Science for Energy Technologies , 2019 , 2 ( 1 ): 83 - 88 .
Lin H , Freeman B D . Materials selection guidelines for membranes that remove CO 2 from gas mixtures [J ] . Journal of Molecular Structure , 2005 , 739 ( 1 / 2 / 3 ): 57 - 74 .
Wang S , Xie Y , He G , et al . Graphene oxide membranes with heterogeneous nanodomains for efficient CO 2 separations [J ] . Angewandte Chemie International Edition , 2017 , 56 ( 45 ): 14246 - 14251 .
Long C , Gongping L , Wanqin J . Recent progress in two-dimensional-material membranes for gas separation [J ] . Acta Physico-Chimica Sinica , 2019 , 35 ( 10 ): 1090 - 1098 .
Liao J , Wang Z , Gao C , et al . Fabrication of high-performance facilitated transport membranes for CO 2 separation [J ] . Chemical Science , 2014 , 5 ( 7 ): 2843 - 2849 .
Guo D , Thee H , da Silva G , et al . Borate-catalyzed carbon dioxide hydration via the carbonic anhydrase mechanism [J ] . Environmental Science & Technology , 2011 , 45 ( 11 ): 4802 - 4807 .
Kim H W , Yoon H W , Yoo B M , et al . High-performance CO 2 -philic graphene oxide membranes under wet-conditions [J ] . Chemical Communications , 2014 , 50 ( 88 ): 13563 - 13566 .
Fam W , Mansouri J , Li H , et al . Improving CO 2 separation performance of thin film composite hollow fiber with Pebax® 1657/ionic liquid gel membranes [J ] . Journal of Membrane Science , 2017 , 537 : 54 - 68 .
Torralba-Calleja E , Skinner J , Gutiérrez-Tauste D . CO 2 capture in ionic liquids: a review of solubilities and experimental methods [J ] . Journal of Chemistry , 2013 , 2013 : 473584 .
Vaidya P D , Kenig E Y . CO 2 -alkanolamine reaction kinetics: a review of recent studies [J ] . Chemical Engineering & Technology: Industrial Chemistry-Plant Equipment-Process Engineering-Biotechnology , 2007 , 30 ( 11 ): 1467 - 1474 .
Li X , Cheng Y , Zhang H , et al . Efficient CO 2 capture by functionalized graphene oxide nanosheets as fillers to fabricate multi-permselective mixed matrix membranes [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 9 ): 5528 - 5537 .
Xin Q , Li Z , Li C , et al . Enhancing the CO 2 separation performance of composite membranes by the incorporation of amino acid-functionalized graphene oxide [J ] . Journal of Materials Chemistry A , 2015 , 3 ( 12 ): 6629 - 6641 .
Dai Y , Ruan X , Yan Z , et al . Imidazole functionalized graphene oxide/PEBAX mixed matrix membranes for efficient CO 2 capture [J ] . Separation and Purification Technology , 2016 , 166 : 171 - 180 .
Bara J E , Camper D E , Gin D L , et al . Room-temperature ionic liquids and composite materials: platform technologies for CO 2 capture [J ] . Accounts of Chemical Research , 2009 , 43 ( 1 ): 152 - 159 .
Yang Z Z , Zhao Y N , He L N . CO 2 chemistry: task-specific ionic liquids for CO 2 capture/activation and subsequent conversion [J ] . RSC Advances , 2011 , 1 ( 4 ): 545 - 567 .
Huang S , Dakhchoune M , Luo W , et al . Single-layer graphene membranes by crack-free transfer for gas mixture separation [J ] . Nature Communications , 2018 , 9 : 2632 .
Peng D , Liu Y , Wang S , et al . Faci litated transport membranes by incorporating different divalent metal ions as CO 2 carriers [J ] . RSC Advances , 2016 , 6 ( 69 ): 65282 - 65290 .
Wang S , Liu Y , Zhang M , et al . Comparison of facilitat transport behavior and separation properties of membranes with imidazole groups and zinc ions as CO 2 carriers [J ] . Journal of Membrane Science , 2016 , 505 : 44 - 52 .
Ren Y , Peng D , Wu H , et al . Enhanced carbon dioxide flux by catechol-Zn 2+ synergistic manipulation of graphene oxide membranes [J ] . Chemical Engineering Science , 2019 , 195 : 230 - 238 .
0
浏览量
1
下载量
2
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010102001995号