免黏结剂V2O5和Fe2O3柔性电极的构建及在超级电容器中的应用

胡兵兵; 杨束; 李彦; 徐川岚; 陈鹏; 于晶晶; 余丹梅; 陈昌国

doi:10.11949/0438-1157.20191307

您当前的位置：

首页 >

文章列表页 >

免黏结剂V₂O₅和Fe₂O₃柔性电极的构建及在超级电容器中的应用

材料化学工程与纳米技术 | 更新时间：2025-11-25

- 免黏结剂V₂O₅和Fe₂O₃柔性电极的构建及在超级电容器中的应用
- Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor
- 化工学报 2020年71卷第10期页码：4836-4846
- 作者机构：
  
  重庆大学化学化工学院，重庆 401331
- 作者简介：
  
  胡兵兵（1993—），男，博士研究生，20151802054@cqu.edu.cn
  余丹梅（1965—），女，博士，教授，yudanmei-1@163.com
- 基金信息：
  
  国家自然科学基金项目(21406021)
- DOI：10.11949/0438-1157.20191307
  中图分类号： TB 321;TQ 152
- 收稿：2019-11-01，
  
  修回：2020-03-02，
  
  纸质出版：2020-10-05
- 稿件说明：
移动端阅览
胡兵兵, 杨束, 李彦, 徐川岚, 陈鹏, 于晶晶, 余丹梅, 陈昌国. 免黏结剂V₂O₅和Fe₂O₃柔性电极的构建及在超级电容器中的应用[J]. 化工学报, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307.

HU Bingbing, YANG Shu, LI Yan, XU Chuanlan, CHEN Peng, YU Jingjing, YU Danmei, CHEN Changguo. Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor[J]. CIESC Journal, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307.
胡兵兵, 杨束, 李彦, 徐川岚, 陈鹏, 于晶晶, 余丹梅, 陈昌国. 免黏结剂V₂O₅和Fe₂O₃柔性电极的构建及在超级电容器中的应用[J]. 化工学报, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307. DOI：

HU Bingbing, YANG Shu, LI Yan, XU Chuanlan, CHEN Peng, YU Jingjing, YU Danmei, CHEN Changguo. Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor[J]. CIESC Journal, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307. DOI：

摘要

近年来，越来越多的研究致力于开发新型、超高能量密度、高法拉第反应活性的电极材料，尤其将其应用于新一代超级电容器储能系统。通过水热法直接在柔性基质碳布上生长海胆状V

纳米球和十四面体Fe

纳米盒子。V

微观结构和储能性能可通过改变水热时间进行调控。海胆状V

纳米球正极材料具有最高比容量535 F·g

-1

。以十四面体Fe

纳米盒子作为负极材料组装的新型结构V

-CC//Fe

-CC柔性超级电容器，在功率密度为699.49 W·kg

-1

时，能量密度可达46.06 W·h·kg

-1

。而且具有良好的机械柔韧性，在180°弯曲循环测试5000次，比容量保持率仍高达83.4%。研究为开发下一代超高能量密度、柔性电子器件提供了一种通用而有效的策略。

Abstract

In recent years

more and more research has been devoted to the development of new electrode materials with ultra-high energy density and high Faraday reaction activity

especially applying them to a new generation of supercapacitor energy storage systems. In this study

sea urchin-shaped V

nanospheres and tetrakaidecahedron Fe

nano boxes have been grown directly on flexible matrix carbon cloth by hydrothermal method. The hydrothermal time can control the microstructure of V

and the morphology determines the performance of energy storage

the positive electrode material of sea urchin-shaped V

nanosphere exhibits a maximum specific capacitance of 535 F·g

-1

. In addition

the tetrakaidecahedron Fe

nano box is used as the negative electrode

and a new structure V

//Fe

flexible supercapacitor is assembled. When the power density is 699.49 W·kg

-1

the energy density can reach 46.06 W·h·kg

-1

. Moreover

it also has good mechanical flexibility

and the specific capacity retention rate is still as high as 83.4% after 5000 times of 180° bending cycle tests. This work provides a general and effective strategy for developing the next generation flexible electronic devices with ultra-high energy density.

关键词

Keywords

references

Islam M S , Fisher C A . Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties [J]. Chemical Society Reviews , 2014 , 43 ( 1 ): 185 - 204 .

Simon P , Gogotsi Y , Dunn B . Where do batteries end and supercapacitors begin? [J]. Science , 2014 , 343 ( 6176 ): 1210 - 1211 .

Li Q , Xu Y , Zheng S , et al . Recent progress in some amorphous materials for supercapacitors [J]. Small , 2018 , 14 ( 28 ): e1800426 .

Peng H , Yao B , Wei X , et al . Pore and heteroatom engineered carbon foams for supercapacitors [J]. Advanced Energy Materials , 2019 , 9 ( 19 ): 1803665 .

张亚婷 , 张凯博 , 贾凯丽 , 等 . 柔性自支撑PDDA-Si/G纳米复合薄膜的制备及储锂性能 [J]. 化工学报 , 2019 , 70 ( 3 ): 1144 - 1151 .

Zhang Y T , Zhang K B , Jia K L , et al . Preparation and lithium storage properties of flexible self-standing PDDA-Si/G nanocomposite film [J]. CIESC Journal , 2019 , 70 ( 3 ): 1144 - 1151 .

Wang Q , Zhang Y , Jiang H , et al . Designed mesoporous hollow sphere architecture metal (Mn, Co, Ni) silicate: a potential electrode material for flexible all solid-state asymmetric supercapacitor [J]. Chemical Engineering Journal , 2019 , 362 : 818 - 829 .

Zuo W , Li R , Zhou C , et al . Battery-supercapacitor hybrid devices: recent progress and future prospects [J]. Advance Science , 2017 , 4 ( 7 ): 1600539 .

Kim H S , Cook J B , Lin H , et al . Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO 3- x [J]. Nature Materials , 2017 , 16 ( 4 ), 454 - 460 .

Zhang Y , Wang C , Jiang H , et al . Cobalt-nickel silicate hydroxide on amorphous carbon derived from bamboo leaves for hybrid supercapacitors [J]. Chemical Engineering Journal , 2019 , 375 : 121938 .

禹兴海 , 罗齐良 , 潘剑 , 等 . 一种生物炭基柔性固态超级电容器的制备及性能研究 [J]. 化工学报 , 2019 , 70 ( 9 ): 3590 - 3600 .

Yu X H , Luo Q L , Pan J , et al . Preparation and properties of flexible supercapacitor based on biochar and solid gel-electrolyte [J]. CIESC Journal , 2019 , 70 ( 9 ): 3590 - 3600 .

Shi P , Li L , Hua L , et al . Design of amorphous manganese oxide@multiwalled carbon nanotube fiber for robust solid-state supercapacitor [J]. ACS Nano , 2017 , 11 ( 1 ): 444 - 452 .

Wang J , Zhang X , Wei Q , et al . 3D self-supported nanopine forest-like Co 3 O 4 @CoMoO 4 core–shell architectures for high-energy solid state supercapacitors [J]. Nano Energy , 2016 , 19 : 222 - 233 .

Chen C , Wang S , Luo X , et al . Reduced ZnCo 2 O 4 @NiMoO 4 •H 2 O heterostructure electrodes with modulating oxygen vacancies for enhanced aqueous asymmetric supercapacitors [J]. Journal of Power Sources , 2019 , 409 : 112 - 122 .

Hosseini H , Shahrokhian S . Advanced binder-free electrode based on core–shell nanostructures of mesoporous Co 3 V 2 O 8 -Ni 3 V 2 O 8 thin layers@porous carbon nanofibers for high-performance and flexible all-solid-state supercapacitors [J]. Chemical Engineering Journal , 2018 , 341 : 10 - 26 .

Chen C , Yan D , Luo X , et al . Construction of core-shell NiMoO 4 @Ni-Co-S nanorods as advanced electrodes for high-performance asymmetric supercapacitors [J]. ACS Appllied Material & Interfaces , 2018 , 10 ( 5 ): 4662 - 4671 .

Costentin C , Porter T R , Saveant J M . How do pseudocapacitors store energy? Theoretical analysis and experimental illustration [J]. ACS Appllied Material & Interfaces , 2017 , 9 ( 10 ): 8649 - 8658 .

Yang J , Liu W , Niu H , et al . Ultrahigh energy density battery-type asymmetric supercapacitors: NiMoO 4 nanorod-decorated graphene and graphene/Fe 2 O 3 quantum dots [J]. Nano Research , 2018 , 11 ( 9 ): 4744 - 4758 .

Wei X , Zhang Y , He H , et al . Carbon-incorporated NiO/Co 3 O 4 concave surface microcubes derived from a MOF precursor for overall water splitting [J]. Chemical Communication , 2019 , 55 ( 46 ): 6515 - 6518 .

Hu B B , Xiang Q , Cen Y , et al . In situ constructing flexible V 2 O 5 @GO composite thin film electrode for superior electrochemical energy storage [J]. Journal of the Electrochemical Society , 2018 , 165 ( 16 ): A3738 - A3747 .

Yang Y , Tang Y , Fang G , et al . Li + intercalated V 2 O 5 • n H 2 O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode [J]. Energy & Environmental Science , 2018 , 11 ( 11 ): 3157 - 3162 .

Zhang N , Jia M , Dong Y , et al . Hydrated layered vanadium oxide as a highly reversible cathode for rechargeable aqueous zinc batteries [J]. Advanced Functional Materials , 2019 , 29 ( 10 ): 1807331 .

Ma J , Guo X , Yan Y , et al . FeO x -based materials for electrochemical energy storage [J]. Advanced Science , 2018 , 5 ( 6 ): 1700986 .

Zeng Y , Yu M , Meng Y , et al . Iron-based supercapacitor electrodes: advances and challenges [J]. Advanced Energy Materials , 2016 , 6 ( 24 ): 1601053 .

Wang J G , Liu H , Liu H , et al . Interfacial constructing flexible V 2 O 5 @polypyrrole core-shell nanowire membrane with superior supercapacitive performance [J]. ACS Appllied Material & Interfaces , 2018 , 10 ( 22 ): 18816 - 18823 .

Xia H , Hong C , Li B , et al . Facile synthesis of hematite quantum-dot/functionalized graphene-sheet composites as advanced anode materials for asymmetric supercapacitors [J]. Advanced Functional Materials , 2015 , 25 ( 4 ): 627 - 635 .

Jiang H , Cai X , Qian Y , et al . V 2 O 5 embedded in vertically aligned carbon nanotube arrays as free-standing electrodes for flexible supercapacitors [J]. Journal of Materials Chemistry A , 2017 , 5 ( 45 ): 23727 - 23736 .

Liu H , Tang Y , Wang C , et al . A lyotropic liquid-crystal-based assembly avenue toward highly oriented vanadium pentoxide/graphene films for flexible energy storage [J]. Advanced Functional Materials , 2017 , 27 ( 12 ): 1606269 .

Li H , Wei C , Wang L , et al . Hierarchical vanadium oxide microspheres forming from hyperbranched nanoribbons as remarkably high performance electrode materials for supercapacitors [J]. Journal of Materials Chemistry A , 2015 , 3 ( 45 ): 22892 - 22901 .

Lee M , Balasingam S K , Hu Y J , et al . One-step hydrothermal synthesis of graphene decorated V 2 O 5 nanobelts for enhanced electrochemical energy storage [J]. Scientific Reports , 2015 , 5 : 8151 .

Li Y , Xu J , Feng T , et al . Fe 2 O 3 nanoneedles on ultrafine nickel nanotube arrays as efficient anode for high-performance asymmetric supercapacitors [J]. Advanced Functional Materials , 2017 , 27 : 1606728 .

Fang K , Chen J , Zhou X , et al . Decorating biomass-derived porous carbon with Fe 2 O 3 ultrathin film for high-performance supercapacitors [J]. Electrochimica Acta , 2018 , 261 : 198 - 205 .

Wang H , Xu C , Chen Y , et al . MnO 2 nanograsses on porous carbon cloth for flexible solid-state asymmetric supercapacitors with high energy density [J]. Energy Storage Materials 2017 , 8 : 127 - 133 .

Wang L , Yang H , Liu X , et al . Constructing hierarchical tectorum-like α-Fe 2 O 3 /PPy nanoarrays on carbon cloth for solid-state asymmetric supercapacitors [J]. Angewandte Chemie-International Edition , 2018 , 56 ( 4 ): 1105 - 1110 .

Salanne M , Rotenberg B , Naoi K , et al . Efficient storage mechanisms for building better supercapacitors [J]. Nature Energy , 2016 , 1 ( 6 ): 16070 .

Chen Y , Zhang Z , Huang , Z , et al . Effects of oxygen-containing functional groups on the supercapacitor performance of incompletely reduced graphene oxides [J]. International Journal of Hydrogen Energy , 2017 , 42 ( 10 ): 7186 - 7194 .

Xing L L , Zhao G G , Huang K J , et al . A yolk-shell V 2 O 5 structure assembled from ultrathin nanosheets and coralline-shaped carbon as advanced electrodes for a high-performance asymmetric supercapacitor [J]. Dalton Transactions , 2018 , 47 ( 7 ): 2256 - 2265 .

Qian T , Xu N , Zhou J , et al . Interconnected three-dimensional V 2 O 5 /polypyrrole network nanostructures for high performance solid-state supercapacitors [J]. Journal of Materials Chemistry A , 2015 , 3 ( 2 ): 488 - 493 .

Liu Q , Li Z F , Liu Y , et al . Graphene-modified nanostructured vanadium pentoxide hybrids with extraordinary electrochemical performance for Li-ion batteries [J]. Nature Communication , 2015 , 6 ( 1 ): 6127 .

Gu T , Wei B . High-performance all-solid-state asymmetric stretchable supercapacitors based on wrinkled MnO 2 /CNT and Fe 2 O 3 /CNT macrofilms [J]. Journal of Materials Chemistry A , 2016 , 4 ( 31 ): 12289 - 12295 .

Serrapede M , Rafique A , Fontana , M et al . Fiber-shaped asymmetric supercapacitor exploiting rGO/Fe 2 O 3 aerogel and electrodeposited MnO x nanosheets on carbon fibers [J]. Carbon , 2019 , 144 : 91 - 100 .

Lin Z , Yan X , Lang J , et al . Adjusting electrode initial potential to obtain high-performance asymmetric supercapacitor based on porous vanadium pentoxide nanotubes and activated carbon nanorods [J]. Journal of Power Sources , 2015 , 279 : 358 - 364 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

一步法合成二维Ti3C2及其电化学性能研究

高倍率容量层状双金属氢氧化物超级电容材料的研究进展

纳米多孔NiO类空心微球负极材料的制备与储锂性能

水系Zn/MnO2体系中H+/Zn2+界面传输调控及反应机理研究进展

乳化炸药爆轰法合成La2Ti2O7的表征及OER性能研究