超疏水多孔材料的研究进展

陈立; 周才龙; 杜京城; 周威; 谭陆西; 董立春

doi:10.11949/0438-1157.20191305

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超疏水多孔材料的研究进展

综述与专论 | 更新时间：2025-11-25

- 超疏水多孔材料的研究进展
- Progress of superhydrophobic porous materials
- 化工学报 2020年71卷第10期页码：4502-4519
- 作者机构：
  
  重庆大学化学化工学院，化工过程强化与反应国家地方联合工程实验室，重庆 400044
- 作者简介：
  
  陈立（1994—），男，博士研究生，201718021067@cqu.edu.cn
  周才龙（1987—），男，博士，讲师，cezcl@cqu.edu.cn
- 基金信息：
  
  国家自然科学基金项目(21776025);重庆市自然科学基金项目(cstc2019jcyj-msxmX0309);中央高校基本科研业务费项目(2019CDXYHG0013;2019CDQYHG023)
- DOI：10.11949/0438-1157.20191305
  中图分类号： TB 383
- 收稿：2019-11-01，
  
  修回：2019-12-24，
  
  纸质出版：2020-10-05
- 稿件说明：
移动端阅览
陈立, 周才龙, 杜京城, 周威, 谭陆西, 董立春. 超疏水多孔材料的研究进展[J]. 化工学报, 2020, 71(10): 4502-4519

CHEN Li, ZHOU Cailong, DU Jingcheng, ZHOU Wei, TAN Luxi, DONG Lichun. Progress of superhydrophobic porous materials[J]. CIESC Journal, 2020, 71(10): 4502-4519
陈立, 周才龙, 杜京城, 周威, 谭陆西, 董立春. 超疏水多孔材料的研究进展[J]. 化工学报, 2020, 71(10): 4502-4519 DOI： 10.11949/0438-1157.20191305.

CHEN Li, ZHOU Cailong, DU Jingcheng, ZHOU Wei, TAN Luxi, DONG Lichun. Progress of superhydrophobic porous materials[J]. CIESC Journal, 2020, 71(10): 4502-4519 DOI： 10.11949/0438-1157.20191305.

摘要

多孔材料如金属有机框架材料（MOFs）、共价有机框架材料（COFs）、有机多孔聚合物（POPs）等由于构筑单元的多样性、可设计性，孔道的可调控性和功能化，已经被广泛用于分离、催化、气体储存以及药物释放等领域。尽管如此，这些多孔材料固有的结构特征让它们普遍对水气非常敏感，最严重时多孔结构在水溶液环境下会坍塌。为解决此类问题，制备疏水的多孔材料是一个非常好的策略。然而，设计超疏水多孔材料具有一定的挑战。介绍了具有（超）疏水性能的MOFs、COFs和POPs的发展现状，对超疏水多孔材料合成思路和结构特点进行了分析，对这类材料在催化、油水分离、气体吸附和分离等方面的应用进行了总结，并进一步探讨了此类材料存在的问题和发展方向。

Abstract

Porous materials such as metal organic framework materials (MOFs)

covalent organic framework materials (COFs)

organic porous polymers (POPs)

etc

have been used widely used in the fields of separation

catalysis

gas storage and drug release due to their diversity

designability

controllability and functionalization of pores. Despite these promising applications

some of the porous materials suffer from moisture-sensitivity and instability in aqueous media due to their inherent structural features. To overcome this problem

endowing them with hydrophobicity is an effective strategy. However

designing superhydrophobic porous materials has certain challenges. In this work

the progress of MOFs

COFs and POPs with (super-)hydrophobic property is introduced. Issues related to their design strategy

structures

and practical applications such as catalysis

oil/water separation and gas storage and separation were analyzed. Additionally

the current problems and the future research directions of the hydrophobic porous materials were discussed.

关键词

Keywords

references

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