功能化离子液体在二氧化碳吸收分离中的应用

崔国凯; 吕书贞; 王键吉

doi:10.11949/0438-1157.20191288

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功能化离子液体在二氧化碳吸收分离中的应用

综述与专论 | 更新时间：2026-07-24

- 功能化离子液体在二氧化碳吸收分离中的应用
- Functional ionic liquids for carbon dioxide capture and separation
- 化工学报 2020年71卷第1期页码：16-25
- 作者机构：
  
  河南师范大学化学化工学院，绿色化学介质与反应教育部重点实验室，精细化学品绿色制造河南省协同创新中心，河南新乡 453007
- 作者简介：
  
  崔国凯（1984—），男，博士，副教授，chemcgk@163.com
  王键吉（1955—），男，博士，教授，jwang@htu. cn
- 基金信息：
  
  国家自然科学基金项目(U1704251;21733011)
- DOI：10.11949/0438-1157.20191288
  中图分类号： O 642.1
- 收稿：2019-10-30，
  
  修回：2019-11-13，
  
  网络首发：2020-08-12，
  
  纸质出版：2020-01-05
- 稿件说明：
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崔国凯, 吕书贞, 王键吉. 功能化离子液体在二氧化碳吸收分离中的应用[J]. 化工学报, 2020, 71(1): 16-25

CUI Guokai, LYU Shuzhen, WANG Jianji. Functional ionic liquids for carbon dioxide capture and separation[J]. CIESC Journal, 2020, 71(1): 16-25
崔国凯, 吕书贞, 王键吉. 功能化离子液体在二氧化碳吸收分离中的应用[J]. 化工学报, 2020, 71(1): 16-25 DOI： 10.11949/0438-1157.20191288.

CUI Guokai, LYU Shuzhen, WANG Jianji. Functional ionic liquids for carbon dioxide capture and separation[J]. CIESC Journal, 2020, 71(1): 16-25 DOI： 10.11949/0438-1157.20191288.

摘要

吸收及分离二氧化碳是降低碳排放和应对全球气候变化的主要策略之一，这就必然要求全球科技工作者注重开发具有选择性高效吸收分离二氧化碳的新材料和新路线。作为近20多年来发展的一类代表性的新材料，离子液体（尤其是功能化离子液体）具有独特的物理化学性质，例如几乎没有蒸气压、液态温度范围大、热稳定性和化学稳定性好、电化学窗口宽、不可燃、结构-性质可调控等。这些性质使离子液体在二氧化碳吸收及分离领域受到广泛关注。重点综述了近5年（2015~2019）来功能化离子液体吸收分离二氧化碳的研究进展，主要内容包括单位点离子液体、多位点离子液体、基于功能化离子液体的混合物、功能化离子液体杂化材料对二氧化碳的吸收分离。同时，对目前该领域的发展所面临的主要问题和进一步的研究工作进行了分析讨论。

Abstract

Carbon dioxide capture and separation (CCS) is one of the main strategies to reduce carbon emissions and cope with global climate change. It is of great significance to develop highly selective absorbents and new routes to efficiently absorb and separate CO

. Recently

ionic liquids (ILs)

especially functional ionic liquids

have been developed as a kind of representative material in the last 20 years due to their unique properties

such as ultra low vapor pressure

wide liquid temperature range

high thermal and chemical stability

wide electrochemical steady window

non-flammability

and tunable structure and properties. Thus

many attentions have been drawn on the absorption and separation of CO

by using ILs. The current review focuses on the studies on functional ILs for CO

capture and separation during the last five years (2015—20

19)

including recent progress on the applications of single site functional ILs

multiple sites functional ILs

functional IL-based mixtures

and functional IL-based hybrid materials in CCS. Finally

the challenges in the absorption and separation of CO

from flue gas as well as further researches in this field have been discussed.

关键词

Keywords

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