熔盐法合成有序介孔碳负载的金属碳化物

孟敏珊; 赵佳华; 张鹏飞

doi:10.11949/0438-1157.20191271

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熔盐法合成有序介孔碳负载的金属碳化物

材料化学工程与纳米技术 | 更新时间：2026-07-24

- 熔盐法合成有序介孔碳负载的金属碳化物
- Synthesis of carbides supported on ordered mesoporous carbon by molten salt method
- 化工学报 2020年71卷第1期页码：409-416
- 作者机构：
  
  上海交通大学化学化工学院，上海 200240
- 作者简介：
  
  孟敏珊(1996—)，女，硕士研究生，msmeng_1123@qq.com
  张鹏飞(1986—)，男，博士，特别研究员，chemistryzpf@sjtu.edu.cn
- 基金信息：
  
  国家自然科学基金面上项目(21776174);国家千人计划青年项目;海洋工程国家重点实验室开发课题(1809);中船重工委托项目;浙江新安化工集团委托项目
- DOI：10.11949/0438-1157.20191271
  中图分类号： TQ 028.8
- 收稿：2019-09-24，
  
  修回：2019-10-24，
  
  网络首发：2020-08-12，
  
  纸质出版：2020-01-05
- 稿件说明：
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孟敏珊, 赵佳华, 张鹏飞. 熔盐法合成有序介孔碳负载的金属碳化物[J]. 化工学报, 2020, 71(1): 409-416

MENG Minshan, ZHAO Jiahua, ZHANG Pengfei. Synthesis of carbides supported on ordered mesoporous carbon by molten salt method[J]. CIESC Journal, 2020, 71(1): 409-416
孟敏珊, 赵佳华, 张鹏飞. 熔盐法合成有序介孔碳负载的金属碳化物[J]. 化工学报, 2020, 71(1): 409-416 DOI： 10.11949/0438-1157.20191271.

MENG Minshan, ZHAO Jiahua, ZHANG Pengfei. Synthesis of carbides supported on ordered mesoporous carbon by molten salt method[J]. CIESC Journal, 2020, 71(1): 409-416 DOI： 10.11949/0438-1157.20191271.

摘要

有序介孔碳是一种具有宽孔径、规则孔道结构、高比表面积和大孔容的纳米结构材料，具有很高的导电性及化学稳定性，是一种非常优良的载体材料。过渡金属碳化物因其结构相似性，具有一系列类似贵金属的性质，可作为贵金属替代材料，用于多相催化过程。但过渡金属碳化物多数粒径大、比表面积低，不利于催化活性，因此，采用熔盐法合成了多种有序介孔碳负载的过渡金属碳化物，并通过SEM、TEM、XRD、BET等方法对样品进行了一系列表征。结果表明，该方法能有效制备碳负载的TiC、Mo

C等金属碳化物，且具有较小的颗粒尺寸和较高的比表面积，将有较好的催化应用前景。

Abstract

Ordered mesoporous carbon is a kind of nanostructured material with regular pore structure

high specific surface area and large pore volume. It is also a very good carrier material. Meanwhile

transition metal carbides have a series of properties that are similar to precious metals because of their structural characteristics. They can be used as catalysts with high activity in theory for heterogeneous catalytic processes to replace precious metals. However

transition metal carbides greatly affect the catalytic activity due to their low specific su

rface area and large particle size. Therefore

a variety of ordered mesoporous carbon-supported transition metal carbides were synthesized by molten salt method

and the samples were characterized by SEM

TEM

XRD and BET. The results show that the method can form carbon-supported metal carbides such as TiC and Mo

C with small particle size and high specific surface area

which has better prospects for catalytic application.

关键词

Keywords

references

凌晓凤 , 顾娟 , 李健生 , 等 . 一步法合成载铁有序介孔碳材料的形成机理 [J ] . 化工进展 , 2012 , 31 ( 1 ): 156 - 162 .

Ling X F , Gu J , Li J S , et al . Mechanism of the synthesis of ordered Fe-containing mesoporous carbon composite materials in one-pot [J ] . Chemical Industry and Engineering Progress , 2012 , 31 ( 1 ): 156 - 162 .

赵亚丽 , 何臻 , 俞强 , 等 . 简易模板法制备有序介孔碳及其表征 [J ] . 化工进展 , 2014 , 33 ( 9 ): 2392 - 2397 .

Zhao Y L , He Z , Yu Q , et al . Preparation and characterization of ordered mesoporous carbon by simple template method [J ] . Chemical Industry and Engineering Progress , 2014 , 33 ( 9 ): 2392 - 2397 .

Li Z , Jaroniec M . Colloidal imprinting: a novel approach to the synthesis of mesoporous carbons [J ] . Journal of the American Chemical Society , 2001 , 123 ( 37 ): 9208 - 9209 .

Ariyadejwanich P , Tanthapanichakoon W , Nakagawa K , et al . Preparation and characterization of mesoporous activated carbon from waste tires [J ] . Carbon , 2003 , 41 ( 1 ): 157 - 164 .

Ohkubo T , Miyawaki J , Kaneko K , et al . Adsorption properties of templated mesoporous carbon (CMK-1) for nitrogen and supercritical methane: experiment and GCMC simulation [J ] . The Journal of Physical Chemistry B , 2002 , 106 ( 25 ): 6523 - 6528 .

Qin H , Jian R , Bai J , et al . Influence of molecular weight on structure and catalytic characteristics of ordered mesoporous carbon derived from lignin [J ] . ACS Omega , 2018 , 3 ( 1 ): 1350 - 1356 .

Li K , Jie S , Yuan L , et al . The synthesis of N, S-codoped ordered mesoporous carbon as an efficient metal-free catalyst for selective oxidation of arylalkanes [J ] . Catalysis Communications , 2018 , 112 : 39 - 42 .

Oyama S T . The Chemistry of Transition Metal Carbides and Nitrides [M ] . Dordrecht : Springer , 1996 .

石宝宝 , 贾志军 , 王毅 , 等 . 新型二维过渡金属碳化物研究进展 [J ] . 化工新型材料 , 2017 , 45 ( 12 ): 16 - 20 .

Shi B B , Jia Z J , Wang Y , et al . Research progress of new two-dimensional transition metal carbides [J ] . New Chemical Materials , 2017 , 45 ( 12 ): 16 - 20 .

甘赠国 , 黄志宇 , 庞纪峰 , 等 . 过渡金属碳化物的催化研究进展 [J ] . 精细石油化工进展 , 2007 , 8 ( 6 ): 37 - 41 .

Gan Z G , Huang Z Y , Pang J F , et al . Research development on catalysis of transition metal carbides [J ] . Advances in Fine Petrochemicals , 2007 , 8 ( 6 ): 37 - 41 .

章永凡 , 李俊篯 , 丁开宁 , 等 . 过渡金属碳化物(111)面电子结构的理论研究 [J ] . 物理化学学报 , 2003 , 19 ( 1 ): 40 - 45 .

Zhang Y F , Li J Q , Ding K N , et al . Theoretical studies on the geometries and electronic structures of the (111) surfaces of transition-metai carbides [J ] . Acta Phys . -Chim . Sin ., 2003 , 19 ( 1 ): 40 - 45 .

Zhang T , Guo X , Zhao Z . Glucose-assisted preparation of a nickel-molybdenum carbide bimetallic catalyst for chemoselective hydrogenation of nitroaromatics and hydrodeoxygenation of m ‑cresol [J ] . ACS Applied Nano Materials , 2018 , 1 ( 7 ): 3579 - 3589 .

Lin Z , Wan W , Yao S , et al . Cobalt-modified molybdenum carbide as a selective catalyst for hydrodeoxygenation of furfural [J ] . Applied Catalysis B Environmental , 2018 , 233 : 160 - 166 .

靳广洲 , 朱建华 , 俱虎良 , 等 . 碳化钼催化剂的制备及噻吩加氢脱硫性能 [J ] . 化工学报 , 2006 , 57 ( 4 ): 799 - 804 .

Jin G Z , Zhu J H , Ju H L , et al . Preparation of molybdenum carbide catalyst and its hydrodesulfurization performance for thiophene [J ] . Journal of Chemical Industry and Engineering (China) , 2006 , 57 ( 4 ): 799 - 804 .

Ordan yan S S , Nesmelov D D , Ovsienko A I . Phase formation during reactive sintering of the B4C–SiC–Si (Al) composite (review) [J ] . Refractories and Industrial Ceramics , 2018 , 58 ( 6 ): 1 - 7 .

Gaziev G A , Krylov O V , Roginskii S Z , et al . Dehydrogenation of cyclohexane on certain carbides borides and silicides [J ] . Dokl . Akad . Nauk SSSR , 1961 , 140 ( 4 ): 863 - 867 .

Levy R L , Boudart M . Platinum-like behavior of tungsten carbide in surface catalysis [J ] . Science , 1973 , 181 ( 4099 ): 547 - 549 .

章永凡 , 林伟 , 王文峰 , 等 . 3d过渡金属碳化物相稳定性和化学键的第一性原理研究 [J ] . 化学学报 , 2004 , 62 ( 11 ): 1041 - 1048 .

Zhang Y F , Lin W , Wang W F , et al . A first principle study on the phase stability and chemical bonding of the 3d transition metal carbides [J ] . Acta Chimica Sinica , 2004 , 62 ( 11 ): 1041 - 1048 .

Aegerter P A , Quigley W W C , Simpson G J , et al . Thiophene hydrodesulfurization over alumina-supported molybdenum carbide and nitride catalysts: adsorption sites, catalytic activities, and nature of the active surface [J ] . Journal of Catalysis , 1996 , 164 ( 1 ): 109 - 121 .

Li S , Lee J S , Hyeon T , et al . Catalytic hydrodenitrogenation of indole over molybdenum nitride and carbides with different structures [J ] . Applied Catalysis A General , 1999 , 184 ( 1 ): 1 - 9 .

Nagai M , Kurakami T , Omi S . Activity of carbided molybdena–alumina for CO 2 hydrogenation [J ] . Catalysis Today , 1998 , 45 ( 1 ): 235 - 239 .

Xiao T C , Hanif A , York A P E , et al . Study on the mechanism of partial oxidation of methane to synthesis gas over molybdenum carbide catalyst [J ] . Physical Chemistry Chemical Physics , 2002 , 4 ( 18 ): 4549 - 4554 .

Sehested J , Jacobsen C J H , Rokni S , et al . Activity and stability of molybdenum carbide as a catalyst for CO 2 reforming [J ] . Journal of Catalysis , 2001 , 201 ( 2 ): 206 - 212 .

Ranhotra G S , Bell A T , Reimer J A . Catalysis over molybdenum carbides and nitrides(Ⅱ): Studies of CO hydrogenation and C 2 H 6 hydrogenolysis [J ] . Journal of Catalysis , 1987 , 108 ( 1 ): 40 - 49 .

Hemming F , Wehrer P , Katrib A , et al . Reactivity of hexanes (2MP, MCP and CH) on W, W 2 C and WC powders(Ⅱ): Approach to the reaction mechanisms using concepts of organometallic chemistry [J ] . Journal of Molecular Catalysis A Chemical , 1997 , 124 ( 1 ): 39 – 56 .

Yuan S D , Hamid S B D , Li Y X , et al . Preparation of Mo 2 C/H ZSM-5 and its catalytic performance for the conversion of n -butane into aromatics [J ] . Journal of Molecular Catalysis A Chemical , 2002 , 184 ( 1 ): 257 - 266 .

Zhang H , Cheng Y T , Vispute T P , et al . Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5: the hydrogen to carbon effective ratio [J ] . Energy & Environmental Science , 2011 , 4 ( 6 ): 2297 - 2307 .

Ye J , Zhang S , Lee W E . Molten salt synthesis and characterization of SiC coated carbon black particles for refractory castable applications [J ] . Journal of the European Ceramic Society , 2013 , 33 ( 10 ): 2023 - 2029 .

Liu X , Antonietti M , Giordano C . Manipulation of phase and microstructure at nanoscale for SiC in molten salt synthesis [J ] . Chemistry of Materials , 2013 , 25 ( 10 ): 2021 - 2027 .

Li X , Dong Z , Westwood A , et al . Low-temperature preparation of single crystal titanium carbide nanofibers in molten salts [J ] . Crystal Growth & Design , 2011 , 11 ( 7 ): 3122 - 3129 .

Chen D , Zhao J H , Zhang P F , et al . Mechanochemical synthesis of metal–organic frameworks [J ] . Polyhedron , 2019 , 162 : 59 - 64 .

Zhao J H , Shu Y , Zhang P F . Solid-state CTAB-assisted synthesis of mesoporous Fe 3 O 4 and Au@Fe 3 O 4 by mechanochemistry [J ] . Chinese Journal of Catalysis , 2019 , 40 ( 7 ): 1078 - 1084

Wang X Q , Lee J S , Tsouris C , et al . Preparation of activated mesoporous carbons for electrosorption of ions from aqueous solutions [J ] . Journal of Materials Chemistry , 2010 , 20 ( 22 ): 4602 - 4608 .

Liu Z , Ling X Y , Su X , et al . Carbon-supported Pt and PtRu nanoparticles as catalysts for a direct methanol fuel cell [J ] . The Journal of Physical Chemistry B , 2004 , 108 ( 24 ): 8234 - 8240 .

Tian Z Q , Jiang S P , Liang Y M , et al . Synthesis and characterization of platinum catalysts on multiwalled carbon nanotubes by intermittent microwave irradiation for fuel cell applications [J ] . The Journal of Physical Chemistry B , 2006 , 110 ( 11 ): 5343 - 5350 .

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