添加Sm对Pt /SBA-15催化苯完全氧化反应活性和热稳定性的影响

毛建新; 袁子卿; 严红绡; 周仁贤

doi:10.11949/0438-1157.20191258

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添加Sm对Pt /SBA-15催化苯完全氧化反应活性和热稳定性的影响

催化、动力学与反应器 | 更新时间：2026-07-24

- 添加Sm对Pt /SBA-15催化苯完全氧化反应活性和热稳定性的影响
- Effects of Sm addition on reactivity and thermal stability of Pt/SBA-15 for catalytic complete oxidation of benzene
- 化工学报 2020年71卷第1期页码：306-313
- 作者机构：
  
  浙江大学化学系催化研究所，浙江杭州 310007
- 作者简介：
  
  毛建新（1967—），男，博士，副教授，jxmao@zju.edu.cn
- 基金信息：
  
  国家重点研发计划项目(2016YFC0204300)
- DOI：10.11949/0438-1157.20191258
  中图分类号： TQ 426;TQ 032;O 643.32⁺2
- 收稿：2019-10-23，
  
  修回：2019-10-31，
  
  网络首发：2020-08-12，
  
  纸质出版：2020-01-05
- 稿件说明：
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毛建新, 袁子卿, 严红绡, 周仁贤. 添加Sm对Pt /SBA-15催化苯完全氧化反应活性和热稳定性的影响[J]. 化工学报, 2020, 71(1): 306-313

MAO Jianxin, YUAN Ziqing, YANG Hongxiao, ZHOU Renxian. Effects of Sm addition on reactivity and thermal stability of Pt/SBA-15 for catalytic complete oxidation of benzene[J]. CIESC Journal, 2020, 71(1): 306-313
毛建新, 袁子卿, 严红绡, 周仁贤. 添加Sm对Pt /SBA-15催化苯完全氧化反应活性和热稳定性的影响[J]. 化工学报, 2020, 71(1): 306-313 DOI： 10.11949/0438-1157.20191258.

MAO Jianxin, YUAN Ziqing, YANG Hongxiao, ZHOU Renxian. Effects of Sm addition on reactivity and thermal stability of Pt/SBA-15 for catalytic complete oxidation of benzene[J]. CIESC Journal, 2020, 71(1): 306-313 DOI： 10.11949/0438-1157.20191258.

摘要

以Pt/SBA-15为催化剂，考察催化剂载体中添加Sm对于苯的完全氧化反应活性和热稳定性影响。采用了一种简便的记录起燃温度曲线和催化剂热稳定性评价方法，即向装载好催化剂的固定床反应器中持续通入恒定流量的反应气，逐步阶段性升高反应温度，同时在线检测出口尾气的浓度变化

得到起燃温度曲线后，继续提高反应温度，然后恒定在某一设定的温度(如550℃)持续运行较长时间

期间定时在线取样分析，如果有必要还可以连续考察降温情况下催化剂的反应活性情况。研究结果表明，几种催化剂低温活性次序为：Pt/SBA-15≈Pt/4%Sm

/SBA-15

Pt/Sm

4%Sm

/SBA-15

而对于高温稳定性则是Pt/4%Sm

/SBA-15

Pt/1.2%Sm

/SBA-15

Pt/SBA-15，Pt/Sm-SBA-15(SG)

Pt/SBA-15(SG)。总之，Sm的添加虽然未能提高Pt/SBA-15的低温催化活性，但是能明显提高催化剂在高温情况下活性的稳定性。1%Pt/4%Sm

/SBA-15同时具备较好的低温催化活性和高温稳定性，具有较好的应用前景。

Abstract

The Sm addition effects on the reactivity and thermal stability of Pt/SBA-15 for catalytic complete oxidation of benzene were investigated. A simple method for recording the burning-off curves and the evaluation for the thermal stability of catalysts was adopted

that is

a constant flow of reaction gas was continuously introduced into a fixed bed reactor loaded with catalyst. The reaction temperature was increased step by step

and the on-line outlet concentrations of benzene were detected after time interval sampling. The burning-off curves could be recorded during this stage. After that

the reaction temperature was increased continuously

and kept at a certain value (

e.g.

550℃)

the on-line sampling analysis was kept at a set time. If necessary

the reaction temperature could be decreased step by step to check the activity variation of the catalyst. The results indicated that the activity order for four catalysts at lower temperature stage was Pt/SBA-15≈Pt/4%Sm

/SBA-15

Pt/Sm

4%Sm

/SBA-15

while the stability order at high temperature was Pt/4%Sm

/SBA-15

Pt/1.2%Sm

/SBA-15

Pt/SBA-15，Pt/Sm-SBA-15(SG)

Pt/SBA-15(SG). In conclusion

Sm can not improve the catalytic activity of Pt / SBA-15 at low temperature

but can significantly improve the stability of the catalyst at high temperature. At the same time

1% Pt/4% Sm

/ SBA-15 has good catalytic activity at low temperature and high temperature stability

and has a good application prospect.

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references

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