1.大连理工大学精细化工国家重点实验室,辽宁 大连 116024
2.大连理工大学化工学院暨辽宁省功能材料化工 重点实验室,辽宁 大连 116024
3.北京化工大学化学工程学院,北京100029
潘鑫(1994—),男,硕士研究生,panxin@panxin.me
王旭珍(1968—),女,博士,教授,xzwang@dlut.edu.cn
邱介山(1964—),男,教授,jqiu@dlut.edu.cn
收稿:2019-07-02,
修回:2019-08-21,
网络首发:2026-07-24,
纸质出版:2019-10-05
移动端阅览
潘鑫, 王旭珍, 冯锟, 王爽, 赵宗彬, 邱介山. 碳纳米环:生长机理、可控合成、性质和应用[J]. 化工学报, 2019, 70(10): 3722-3737
PAN Xin, WANG Xuzhen, FENG Kun, WANG Shuang, ZHAO Zongbin, QIU Jieshan. Carbon nanorings: growth mechanism, controllable synthesis, properties and applications[J]. CIESC Journal, 2019, 70(10): 3722-3737
潘鑫, 王旭珍, 冯锟, 王爽, 赵宗彬, 邱介山. 碳纳米环:生长机理、可控合成、性质和应用[J]. 化工学报, 2019, 70(10): 3722-3737 DOI: 10.11949/0438-1157.20190751.
PAN Xin, WANG Xuzhen, FENG Kun, WANG Shuang, ZHAO Zongbin, QIU Jieshan. Carbon nanorings: growth mechanism, controllable synthesis, properties and applications[J]. CIESC Journal, 2019, 70(10): 3722-3737 DOI: 10.11949/0438-1157.20190751.
碳材料是一类神奇的材料,碳原子可以通过sp、sp
2
或sp
3
杂化构筑不同微观结构的碳材料。目前,已经发现的碳的同素异形体有石墨、金刚石、富勒烯、碳纳米管、碳纳米环、石墨烯和石墨炔。富勒烯和石墨烯因性质独特、应用前景广阔,其发现者分别获得1996年和2010年诺贝尔奖。碳纳米环具有独特的环状结构、优异的机械强度及特殊的物理化学性能,也引起广泛关注。研究者从早期对碳纳米环进行理论计算、预测其性质,到现在已能够通过化学气相沉积、激光辐射、超声诱导自组装等方法制备不同尺寸的碳纳米环,并对其性质和应用进行探索。总结了近30年来有关碳纳米环的生长机理、可控合成、性质和应用等方面的研究进展,对其规模化合成与应用提出了建议与展望。
Carbon materials are a class of magical materials. Carbon atoms can be hybridized by sp
sp
2
or sp
3
to construct carbon materials with different microstructures. The allotropes of carbon that have been found so far are graphite
diamond
fullerene
carbon nanotube
carbon nanoring
graphene and graphdiyne. Due to the excellent properties and broad application prospects
the discoverers of fullerene and graphene have been honored by the Nobel Prize in 1996 and 2010
respectively. Since carbon nanorings have special structure
excellent mechanical strength with unique physical and chemistry properties
they have attracted much attention. Initially people have carried out some theoretical calculations to predict the properties of carbon nanorings
Up to now
carbon nanorings with different sizes have been successfully prepared through chemical vapor deposition
laser irradiation
ultrasonic self-assembly
etc
.
and their properties and applications have also been explored. This paper summarizes the growth mechanism
controllable synthesis
properties and applications of carbon nanorings for nearly 30 years. Furthermore
suggestions and prospects for the large-scale synthesis and application of carbon nanorings are presented.
Zhang J , Terrones M , Park C R , et al . Carbon science in 2016: status, challenges and perspectives [J ] . Carbon , 2016 , 98 : 708 - 732 .
Li Q , Yong L , Yang C , et al . Synthesis of γ -graphyne by mechanochemistry and its electronic structure [J ] . Carbon , 2018 , 136 , 248 - 254 .
Novoselov K S , Geim A K , Morozov S V , et al . Electric field effect in atomically thin carbon films [J ] . Science , 2004 , 306 ( 5696 ): 666 - 669 .
Geim A K , Novoselov K S . The rise of graphene [J ] . Nat. Mater ., 2007 , 6 ( 3 ): 183 - 191 .
Guo X L , Yu L L , Hui B L , et al . Architecture of graphdiyne nanoscale films [J ] . Chem. Commun ., 2010 , 46 ( 19 ): 3256 - 3258 .
Liu J , Dai H , Hafner J H , et al . Fullerene ‘crop circles’ [J ] . Nature , 1997 , 385 ( 6619 ): 780 - 781 .
Kong X Y , Ding Y , Yang R , et al . Single-crystal nanorings formed by epitaxial self-coiling of polar nanobelts [J ] . Science , 2004 , 303 ( 5662 ): 1348 - 1351 .
Zhong K , Li J , Liu L , et al . Direct fabrication of monodisperse silica nanorings from hollow spheres — a template for core-shell nanorings [J ] . ACS Appl . Mater . Interfaces , 2016 , 8 ( 16 ): 10451 - 10458 .
Sun F Q , Yu J C , Wang X C . Construction of size-controllable hierarchical nanoporous TiO 2 ring arrays and their modifications [J ] . Chem. Mat ., 2006 , 18 ( 16 ): 3774 - 3779 .
Bayati M , Patoka P , Giersig M , et al . An approach to fabrication of metal nanoring arrays [J ] . Langmuir , 2010 , 26 ( 5 ): 3549 - 3554 .
Yabu H . Bottom-up approach to creating three-dimensional nanoring arrays composed of Au nanoparticles [J ] . Langmuir , 2013 , 29 ( 4 ): 1005 - 1009 .
Chen J , Liao W S , Chen X , et al . Evaporation-induced assembly of quantum dots into nanorings [J ] . ACS Nano , 2009 , 3 ( 1 ): 173 - 180 .
Mazzanti M . The secret is in the ring [J ] . Nat . Chem ., 2018 , 10 : 247 .
Wilder J W G , Venema L C , Rinzler A G , et al . Electronic structure of atomically resolved carbon nanotubes [J ] . Nature , 1998 , 391 ( 6662 ): 59 - 62 .
Lyn M E , He J , Koplitz B . Laser-induced production of large carbon-based toroids [J ] . Appl. Surf. Sci ., 2005 , 246 ( 1 ): 44 - 47 .
Colomer J F , Henrard L , Flahaut E , et al . Rings of double-walled carbon nanotube bundles [J ] . Nano Lett ., 2003 , 3 ( 5 ): 685 - 689 .
Ahlskog M , Seynaeve E , Vullers R J M , et al . Ring formations from catalytically synthesized carbon nanotubes [J ] . Chem . Phys . Lett ., 1999 , 300 ( 1 / 2 ): 202 - 206 .
Song L , Ci L J , Sun L F , et al . Large-scale synthesis of rings of bundled single-walled carbon nanotubes by floating chemical vapor deposition [J ] . Adv. Mater ., 2006 , 18 ( 14 ): 1817 - 1821 .
Zhou Z , Wan D , Bai Y , et al . Ring formation from the direct floating catalytic chemical vapor deposition [J ] . Physica E , 2006 , 33 ( 1 ): 24 - 27 .
刘壮 , 汪伟 , 巨晓洁 , 等 . 具有限域传质效应的碳基分离膜——从碳纳米管膜到石墨烯膜 [J ] . 化工学报 , 2018 , 69 ( 1 ): 166 - 174 .
Liu Z , Wang W , Ju X J , et al . Carbon-based membranes with confinement effect for mass transport: from carbon nano-tube membranes to graphene membranes [J ] . CIESC Journal , 2018 , 69 ( 1 ): 166 - 174 .
Martel R , Shea H R , Avouris P . Ring formation in single-wall carbon nanotubes [J ] . J. Phys. Chem. B , 1999 , 103 ( 36 ): 7551 - 7556 .
Martel R , Shea H R , Avouris P . Rings of single-walled carbon nanotubes [J ] . Nature , 1999 , 398 ( 6725 ): 299 .
Komatsu N , Shimawaki T , Aonuma S , et al . Ultrasonic isolation of toroidal aggregates of single-walled carbon nanotubes [J ] . Carbon , 2006 , 44 ( 10 ): 2091 - 2093 .
Wang X , Wang Z , Liu Y Q , et al . Ring formation and fracture of a carbon nanotube [J ] . Chem. Phys. Lett ., 2001 , 339 ( 1 ): 36 - 40 .
Sano M , Kamino A , Okamura J , et al . Ring closure of carbon nanotubes [J ] . Science , 2001 , 293 ( 5533 ): 1299 - 1301 .
Vossmeyer T , Chung S W , Gelbart W M , et al . Surprising superstructures: rings [J ] . Adv. Mater ., 1998 , 10 ( 4 ): 351 - 353 .
Geng J , Ko Y K , Youn S C , et al . Synthesis of SWNT rings by noncovalent hybridization of porphyrins and single-walled carbon nanotubes [J ] . J. Phys. Chem. B , 2008 , 112 ( 32 ): 12264 - 12271 .
Zou S , Maspoch D , Wang Y , et al . Rings of single-walled carbon nanotubes: molecular-template directed assembly and monte carlo modeling [J ] . Nano Lett ., 2007 , 7 ( 2 ): 276 - 280 .
Motavas S , Omrane B , Papadopoulos C . Large-area patterning of carbon nanotube ring arrays [J ] . Langmuir , 2009 , 25 ( 8 ): 4655 - 4658 .
Wang W , Laird E D , Gogotsi Y , et al . Bending single-walled carbon nanotubes into nanorings using a Pickering emulsion-based process [J ] . Carbon , 2012 , 50 ( 5 ): 1769 - 1775 .
Song J , Wang F , Yang X , et al . Gold nanoparticle coated carbon nanotube ring with enhanced raman scattering and photothermal conversion property for theranostic applications [J ] . J. Am. Chem. Soc ., 2016 , 138 ( 22 ): 7005 - 7015 .
Kosynkin D V , Higginbotham A L , Sinitskii A , et al . Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons [J ] . Nature , 2009 , 458 ( 7240 ): 872 - 876 .
Liu Y , Wang X , Dong Y , et al . Self-assembled sulfur/reduced graphene oxide nanoribbon paper as a free-standing electrode for high performance lithium-sulfur batteries [J ] . Chem. Commun ., 2016 , 52 ( 87 ): 12825 - 12828 .
Liu Y , Wang X , Song X , et al . Interlayer expanded MoS 2 enabled by edge effect of graphene nanoribbons for high performance lithium and sodium ion batteries [J ] . Carbon , 2016 , 109 : 461 - 471 .
Liu Y , Wang X , Wan W , et al . Multifunctional nitrogen-doped graphene nanoribbon aerogels for superior lithium storage and cell culture [J ] . Nanoscale , 2016 , 8 ( 4 ): 2159 - 2167 .
Liu Y , Yang Y , Wang X , et al . Flexible paper-like free-standing electrodes by anchoring ultrafine SnS 2 nanocrystals on graphene nanoribbons for high-performance sodium ion batteries [J ] . ACS Appl . Mater . Interfaces , 2017 , 9 ( 18 ): 15484 - 15491 .
Liu Y , Wang X , Dong Y , et al . Nitrogen-doped graphene nanoribbons for high-performance lithium ion batteries [J ] . J. Mater. Chem. A , 2014 , 2 ( 40 ): 16832 - 16835 .
Yang L , Wang X , Liu Y , et al . Layer-dependent catalysis of MoS 2 /graphene nanoribbon composites for efficient hydrodesulfurization [J ] . Catal. Sci. Technol ., 2017 , 7 ( 3 ): 693 - 702 .
Rauwald U , Shaver J , Klosterman D A , et al . Electron-induced cutting of single-walled carbon nanotubes [J ] . Carbon , 2009 , 47 ( 1 ): 178 - 185 .
Shuba M V , Paddubskaya A G , Kuzhir P P , et al . Soft cutting of single-wall carbon nanotubes by low temperature ultrasonication in a mixture of sulfuric and nitric acids [J ] . Nanotechnology , 2012 , 23 ( 49 ): 495714 .
Ziegler K J , Zhenning G , Haiqing P , et al . Controlled oxidative cutting of single-walled carbon nanotubes [J ] . J. Am. Chem. Soc ., 2005 , 127 ( 5 ): 1541 - 1547 .
Tran M Q , Tridech C , Alfrey A , et al . Thermal oxidative cutting of multi-walled carbon nanotubes [J ] . Carbon , 2007 , 45 ( 12 ): 2341 - 2350 .
Krause B , Villmow T , Boldt R , et al . Influence of dry grinding in a ball mill on the length of multiwalled carbon nanotubes and their dispersion and percolation behaviour in melt mixed polycarbonate composites [J ] . Compos. Sci. Technol ., 2011 , 71 ( 8 ): 1145 - 1153 .
Ren F , Kanaan S A , Khalkhal F , et al . Controlled cutting of single-walled carbon nanotubes and low temperature annealing [J ] . Carbon , 2013 , 63 : 61 - 70 .
Wang X X , Wang J N . Preparation of short and water-dispersible carbon nanotubes by solid-state cutting [J ] . Carbon , 2008 , 46 ( 1 ): 117 - 125 .
张文忠 , 蔡晓兰 , 周蕾 , 等 . 碳纳米管短切技术的研究进展 [J ] . 机械工程材料 , 2014 , 38 ( 9 ): 6 - 11 .
Zhang W Z , Cai X L , Zhou L , et al . Research progress on carbon nanotubes cutting technologies [J ] . Materials for Mechanical Engineering , 2014 , 38 ( 9 ): 6 - 11 .
陈永 , 刘畅 , 成会明 . 多壁纳米碳管的超声短切处理 [J ] . 炭素技术 , 2007 , 26 ( 5 ): 20 - 23 .
Chen Y , Liu C , Cheng H M . Shortening of multi-walled carbon nanotubes by ultrasonication [J ] . Carbon Techniques , 2007 , 26 ( 5 ): 20 - 23 .
Weydemeyer E J , Sawdon A J , Peng C A . Controlled cutting and hydroxyl functionalization of carbon nanotubes through autoclaving and sonication in hydrogen peroxide [J ] . Chem. Commun ., 2015 , 51 ( 27 ): 5939 - 5942 .
Sun J , Liu H , Chen X , et al . Carbon nanorings and their enhanced lithium storage properties [J ] . Adv . Mater ., 2013 , 25 ( 8 ): 1125 - 1130, 1124 .
Lewis S E . Cycloparaphenylenes and related nanohoops [J ] . Chem. Soc. Rev ., 2015 , 44 ( 8 ): 2221 - 2304 .
周启峰 , 江波 , 杨海波 . 可作为碳纳米管片段的共轭芳烃大环的设计合成 [J ] . 化学进展 , 2018 , ( 5 ): 628 - 638 .
Zhou Q F , Jiang B , Yang H B . Design and synthesis of conjugated aromatic macrocyclic rings that can serve as carbon nanotube segments [J ] . Progress in Chemistry , 2018 , ( 5 ): 628 - 638 .
Segawa Y , Yagi A , Matsui K , et al . Design and synthesis of carbon nanotube segments [J ] . Angew . Chem . -Int . Edit ., 2016 , 55 ( 17 ): 5136 - 5158 .
Jasti R , Bhattacharjee J , Neaton J B , et al . Synthesis, characterization, and theory of [9 ] -,[12 ] -, and [ 18 18 ] cycloparaphenylene: carbon nanohoop structures [J ] . J. Am. Chem. Soc ., 2008 , 130 ( 52 ): 17646 - 17647 .
Takaba H , Omachi H , Yamamoto Y , et al . Selective synthesis of [ 12 12 ] cycloparaphenylene [J ] . Angew . Chem . -Int . Edit ., 2009 , 48 ( 33 ): 6112 - 6116 .
Yamago S , Watanabe Y , Iwamoto T . Synthesis of [ 8 8 ] cycloparaphenylene from a square-shaped tetranuclear platinum complex [J ] . Angew . Chem . -Int . Edit ., 2010 , 49 ( 4 ): 757 - 759 .
Huang Z A , Chen C , Yang X D , et al . Synthesis of oligoparaphenylene-derived nanohoops employing an anthracene photodimerization-cycloreversion Strategy [J ] . J. Am. Chem. Soc ., 2016 , 138 ( 35 ): 11144 - 11147 .
Lu D , Zhuang G , Wu H , et al . A large π-extended carbon nanoring based on nanographene units: bottom-up synthesis, photophysical properties, and selective complexation with fullerene C 70 [J ] . Angew . Chem . -Int . Edit ., 2017 , 56 ( 1 ): 158 - 162 .
Huang Q , Zhuang G , Jia H , et al . Photoconductive curved-nanographene/fullerene supramolecular heterojunctions [J ] . Angew . Chem . -Int . Edit ., 2019 , 58 ( 19 ): 6244 - 6249 .
Lu D , Wu H , Dai Y , et al . A cycloparaphenylene nanoring with graphenic hexabenzocoronene sidewalls [J ] . Chem. Commun ., 2016 , 52 ( 44 ): 7164 - 7167 .
Guo L , Yang X , Cong H . Synthesis of macrocyclic oligoparaphenylenes derived from anthracene photodimer [J ] . Chin . J. Chem ., 2018 , 36 ( 12 ): 1135 - 1138 .
Xu W , Yang X D , Fan X B , et al . Synthesis and characterization of a pentiptycene-derived dual oligoparaphenylene nanohoop [J ] . Angew . Chem . -Int . Edit ., 2019 , 58 ( 12 ): 3943 - 3947 .
Segawa Y , Kuwayama M , Hijikata Y , et al . Topological molecular nanocarbons: all-benzene catenane and trefoil knot [J ] . Science , 2019 , 365 ( 6450 ): 272 - 276
Povie G , Segawa Y , Nishihara T , et al . Synthesis of a carbon nanobelt [J ] . Science , 2017 , 356 ( 6334 ): 172 - 175 .
Cheung K Y , Gui S , Deng C , et al . Synthesis of armchair and chiral carbon nanobelts [J ] . Chem , 2019 , 5 ( 4 ): 838 - 847 .
Matsui K , Segawa Y , Itami K . All-benzene carbon nanocages: size-selective synthesis, photophysical properties, and crystal structure [J ] . J. Am. Chem. Soc ., 2014 , 136 ( 46 ): 16452 - 16458 .
Kayahara E , Iwamoto T , Takaya H , et al . Synthesis and physical properties of a ball-like three-dimensional pi-conjugated molecule [J ] . Nat . Commun ., 2013 , 4 : 2694 .
Cui S , Zhuang G , Lu D , et al . A three-dimensional capsule-like carbon nanocage as a segment model of capped zigzag[ 12 12 ,0 ] carbon nanotubes: synthesis, characterization, and complexation with C 70 [J ] . Angew . Chem . -Int . Edit ., 2018 , 57 ( 30 ): 9330 - 9335 .
Liu L , Liu F , Zhao J . Curved carbon nanotubes: from unique geometries to novel properties and peculiar applications [J ] . Nano Res ., 2014 , 7 ( 5 ): 626 - 657 .
Ihara S , Itoh S , Kitakami J I . Toroidal forms of graphitic carbon [J ] . Phys. Rev. B , 1993 , 47 ( 19 ): 12908 - 12911 .
Itoh S , Ihara S . Toroidal forms of graphitic carbon(Ⅱ): Elongated tori [J ] . Phys. Rev. B , 1993 , 48 ( 11 ): 8323 - 8328 .
Itoh S , Ihara S . Isomers of the toroidal forms of graphitic carbon [J ] . Phys. Rev. B , 1994 , 49 ( 19 ): 13970 - 13974 .
Chen W , Li H . How does carbon nanoring deform to spiral induced by carbon nanotube? [J ] . Sci Rep , 2014 , 4 : 3865 .
Chen N , Lusk M T , Van Duin A C T , et al . Mechanical properties of connected carbon nanorings via molecular dynamics simulation [J ] . Phys . Rev . B, 2 005 , 72 ( 8 ): 085416 .
Smith B W , Luzzi D E . Formation mechanism of fullerene peapods and coaxial tubes: a path to large scale synthesis [J ] . Chem. Phys. Lett ., 2000 , 321 ( 1 ): 169 - 174 .
Yu K L , Zou J J , Ben Y H , et al . Synthesis of NiO-embedded carbon nanotubes using corona discharge enhanced chemical vapor deposition [J ] . Diam. Relat. Mat ., 2006 , 15 ( 9 ): 1217 - 1222 .
Wang Z , Zhao Z , Qiu J . Carbon nanotube templated synthesis of CeF 3 nanowires [J ] . Chem. Mat ., 2007 , 19 ( 14 ): 3364 - 3366 .
Haddon R C . Electronic properties of carbon toroids [J ] . Nature , 1997 , 388 ( 6637 ): 31 - 32 .
Liu L Z , Zhang L , Gao H L , et al . Structure, energetics, and heteroatom doping of armchair carbon nanotori [J ] . Carbon , 2011 , 49 ( 13 ): 4518 - 4523 .
Latil S , Roche S , Rubio A . Persistent currents in carbon nanotube based rings [J ] . Phys . Rev . B, 2 003 , 67 ( 16 ): 165420 .
Chen H B , Xu N , Ding J W . Effects of inter-wall interaction and outer-wall disorder on persistent current in a carbon nanotorus [J ] . Solid State Commun ., 2008 , 146 ( 1 / 2 ): 12 - 16 .
Chen H B , Ding J W . Persistent current in finite-width ring with surface disorder [J ] . Physica B: Condensed Matter , 2008 , 403 ( 12 ): 2015 - 2020 .
0
浏览量
1
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010102001995号