语种选择
您当前的位置：
首页 >
文章列表页 >
真空变温吸附捕集干烟道气中CO2的模拟研究
能源和环境工程 | 更新时间：2026-07-24
|
真空变温吸附捕集干烟道气中CO2的模拟研究
Simulation study on CO2 capture from dry flue gas by temperature vacuum swing adsorption
- 化工学报 2019年70卷第10期 页码：4032-4042
- 作者机构：
天津大学化工学院化学工程研究所，化学工程联合国家重点实验室，天津 300350
- 作者简介：
江南（1994—），男，硕士研究生，jiangnan_2017@tju.edu.cn
李国兵（1973—），男，博士，副教授，lgbbox@tju.edu.cn
- 基金信息：
DOI：10.11949/0438-1157.20190725
中图分类号： TQ 028.1收稿：2019-06-26，
修回：2019-07-31，
网络首发：2026-07-24，
纸质出版：2019-10-05
- 稿件说明：
移动端阅览
江南, 刘冰, 唐忠利, 张东辉, 李国兵. 真空变温吸附捕集干烟道气中CO2的模拟研究[J]. 化工学报, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725.
JIANG Nan, LIU Bing, TANG Zhongli, ZHANG Donghui, LI Guobing. Simulation study on CO2 capture from dry flue gas by temperature vacuum swing adsorption[J]. CIESC Journal, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725.
江南, 刘冰, 唐忠利, 张东辉, 李国兵. 真空变温吸附捕集干烟道气中CO2的模拟研究[J]. 化工学报, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725. DOI：
JIANG Nan, LIU Bing, TANG Zhongli, ZHANG Donghui, LI Guobing. Simulation study on CO2 capture from dry flue gas by temperature vacuum swing adsorption[J]. CIESC Journal, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725. DOI：
真空变温吸附捕集干烟道气中CO2的模拟研究
摘要
为减缓气候变化，减少CO
2
的排放，对真空变温吸附(TVSA)从干烟道气中捕集CO
2
进行了系统的研究。以沸石13X为吸附剂，设计了实验室规模的4塔连续进料的TVSA工艺，并建立数学模型进行数值模拟。模拟结果表明，通过四塔TVSA可获得纯度为97.54%，回收率为96.79%的CO
2
产品气，其产率为1.7 mol·
<math id="M1"><mo stretchy="false">(</mo><mi mathvariant="normal">k</mi><mi mathvariant="normal">g</mi><mtext> </mtext><mi mathvariant="normal">a</mi><mi mathvariant="normal">d</mi><mi mathvariant="normal">s</mi><mo stretchy="false">)</mo></math>
https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938074&type=
https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938073&type=
10.24466705
2.96333337
-1
·h
-1
，能耗为3.1
4
<math id="M2"><mi mathvariant="normal">M</mi><mi mathvariant="normal">J</mi><mo>·</mo><mo stretchy="false">(</mo><mi mathvariant="normal">k</mi><mi mathvariant="normal">g</mi><mtext> </mtext><mi mathvariant="normal">C</mi><msub><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn mathvariant="normal">2</mn></mrow></msub><msubsup><mrow><mo stretchy="false">)</mo></mrow><mrow/><mrow><mo>-</mo><mn mathvariant="normal">1</mn></mrow></msubsup></math>
https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938103&type=
https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938110&type=
18.96533394
4.14866638
。此外，考察了进料量、循环回流步骤时间、真空度对产品气纯度、回收率、吸附剂产率和工艺能耗的影响，并且分析了塔内压力与温度变化，详细探讨了塔内气固相浓度随轴向的分布。良好的工艺效果表明，TVSA有潜力成为一种能够生产高纯度高回收率的CO
2
产品气，并具有良好经济效益的捕碳工艺。
Abstract
To mitigate climate change and reduce CO
2
emissions
a systematic study on the capture of CO
2
from dry flue gas by temperature vacuum swing adsorption (TVSA) was conducted. With zeolite 13X as adsorbent
a four-bed TVSA with continuous feeding was designed
and a mathematical model was established for numerical simulation. Results showed that with the productivity of 1.7 mol·(kg ads)
-1
·h
-1
and energy consumption of 3.14 MJ·
<math id="M3"><mo stretchy="false">(</mo><mi mathvariant="normal">k</mi><mi mathvariant="normal">g</mi><mtext> </mtext><mi mathvariant="normal">C</mi><msub><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn mathvariant="normal">2</mn></mrow></msub><msubsup><mrow><mo stretchy="false">)</mo></mrow><mrow/><mrow><mo>-</mo><mn mathvariant="normal">1</mn></mrow></msubsup></math>
https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938107&type=
https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938077&type=
15.49400043
4.82599974
CO
2
purity of 97.54% and CO
2
recovery of 96.79% can be obtained by the four-bed TVSA process. The effect of feed flowrate
recycle time and vacuum level on purity
recovery
productivity and energy consumption was investigated. Additionally
the pressure and temperature behaviors in the column were analyzed
and the distribution of gas phase and adsorbed phase concentration in the axial direction was discussed in detail. The good performance indicated that TVSA will have the potential to be a cost-effective process capable of producing high purity and high recovery CO
2
product.
关键词
Keywords
references
Ben-Mansour R , Habib M A , Bamidele O E , et al . Carbon capture by physical adsorption: materials, experimental investigations and numerical modeling and simulations—a review [J ] . Applied Energy , 2016 , 161 : 225 - 255 .
Wang L , Yang Y , Shen W , et al . CO 2 capture from flue gas in an existing coal-fired power plant by two successive pilot-scale VPSA units [J ] . Industrial & Engineering Chemistry Research , 2013 , 52 ( 23 ): 7947 - 7955 .
刘冰 , 孙伟娜 , 安亚雄 , 等 . 带循环的二阶变压吸附碳捕集工艺模拟、实验及分析 [J ] . 化工学报 , 2018 , 69 ( 11 ): 4788 - 4797 .
Liu B , Sun W N , An Y X , et al . Simulation, experimentation and analyzation of two stage pressure swing adsorption process for CO 2 capture [J ] . CIESC Journal , 2018 , 69 ( 11 ): 4788 - 4797 .
Duarte G S , Schürer B , Voss C , et al . Adsorptive separation of CO 2 from flue gas by temperature swing adsorption processes [J ] . ChemBioEng Reviews , 2017 , 4 ( 5 ): 277 - 288 .
Leperi K T , Snurr R Q , You F . Optimization of two-stage pressure/vacuum swing adsorption with variable dehydration level for postcombustion carbon capture [J ] . Industrial & Engineering Chemistry Research , 2016 , 55 ( 12 ): 3338 - 3350 .
Ho H , Iizuka A , Shibata E . Carbon capture and utilization technology without carbon dioxide purification and pressurization: a review on its necessity and available technologies [J ] . Industrial & Engineering Chemistry Research , 2019 , 58 ( 21 ): 8941 - 8954 .
阎海宇 , 付强 , 周言 , 等 . 真空变压吸附捕集烟道气中二氧化碳的模拟、实验及分析 [J ] . 化工学报 , 2016 , 67 ( 6 ): 2371 - 2379 .
Yan H Y , Fu Q , Zhou Y , et al . Simulation, experimentation and analyzation of vacuum pressure swing adsorption process for CO 2 capture from dry flue gas [J ] . CIESC Journal , 2016 , 67 ( 6 ): 2371 - 2379 .
Shi W , Yang H , Shen Y , et al . Two-stage PSA/VSA to produce H 2 with CO 2 capt ure via steam methane reforming (SMR) [J ] . International Journal of Hydrogen Energy , 2018 , 43 ( 41 ): 19057 - 19074 .
Shen Y , Shi W , Zhang D , et al . The removal and capture of CO 2 from biogas by vacuum pressure swing process using silica gel [J ] . Journal of CO 2 Utilization , 2018 , 27 : 259 - 271 .
Yan H , Fu Q , Zhou Y , et al . CO 2 capture from dry flue gas by pressure vacuum swing adsorption: a systematic simulation and optimization [J ] . International Journal of Greenhouse Gas Control , 2016 , 51 : 1 - 10 .
Li D , Zhou Y , Shen Y , et al . Experiment and simulation for separating CO 2 /N 2 by dual-reflux pressure swing adsorption process [J ] . Chemical Engineering Journal , 2016 , 297 : 315 - 324 .
Tian C , Fu Q , Ding Z , et al . Experiment and simulation study of a dual-reflux pressure swing adsorption process for separating N 2 /O 2 [J ] . Separation and Purification Technology , 2017 , 189 : 54 - 65 .
Nastaj J , Ambrożek B . Modeling of drying of gaseous mixtures in TSA system with fixed bed of solid desiccants [J ] . Drying Technology , 2012 , 30 ( 10 ): 1062 - 1071 .
Ahn H , Lee C . Adsorption dynamics of water in layered bed for air-drying TSA process [J ] . AIChE Journal , 2003 , 49 ( 6 ): 1601 - 1609 .
Ambrożek B , Zwarycz-Makles K . Theoretical and experimental studies of the recovery of volatile organic compounds from waste air streams in the thermal swing adsorption system with closed-loop regeneration of adsorbent [J ] . Energy Conversion and Management , 2014 , 85 : 646 - 654 .
He J , Deng S , Zhao L , et al . A numerical analysis on energy-efficiency performance of temperature swing adsorption for CO 2 capture [J ] . Energy Procedia , 2017 , 142 : 3200 - 3207 .
Marx D , Joss L , Hefti M , et al . Temperature swing adsorption for postcombustion CO 2 capture: single- and multicolumn experiments and simulations [J ] . Industrial & Engineering Chemistry Research , 2016 , 55 ( 5 ): 1401 - 1412 .
Clausse M , Merel J , Meunier F . Numerical parametric study on CO 2 capture by indirect thermal swing adsorption [J ] . International Journal of Greenhouse Gas Control , 2011 , 5 ( 5 ): 1206 - 1213 .
Su F , Lu C . CO 2 capture from gas stream by zeolite 13X using a dual-column temperature/vacuum swing adsorption [J ] . Energy & Environmental Science , 2012 , 5 ( 10 ): 9021 .
Wang L , Liu Z , Li P , et al . Experimental and modeling investigation on post-combustion carbon dioxide capture using zeolite 13X-APG by hybrid VTSA process [J ] . Chemical Engineering Journal , 2012 , 197 : 151 - 161 .
Lian Y , Deng S , Li S , et al . Numerical analysis on CO 2 capture process of temperature swing adsorption (TSA): optimization of reactor geometry [J ] . International Journal of Greenhouse Gas Control , 2019 , 85 : 187 - 198 .
Ntiamoah A , Ling J , Xiao P , et al . CO 2 capture by temperature swing adsorption: use of hot CO 2 -rich gas for regeneration [J ] . Industrial & Engineering Chemistry Research , 2016 , 55 ( 3 ): 703 - 713 .
Zhao R , Deng S , Zhao L , et al . Performance analysis of temperature swing adsorption for CO 2 capture using thermodynamic properties of adsorbed phase [J ] . Applied Thermal Engineering , 2017 , 123 : 205 - 215 .
Tlili N , Grévillot G , Vallières C . Carbon dioxide capture and recovery by means of TSA and/or VSA [J ] . International Journal of Greenhouse Gas Control , 2009 , 3 ( 5 ): 519 - 527 .
Yang H , Yin C , Jiang B , et al . Optimization and analysis of a VPSA process for N 2 /CH 4 separation [J ] . Separation and Purification Technology , 2014 , 134 : 232 - 240 .
Zhou Y , Fu Q , Shen Y , et al . Upgrade of low-concentration oxygen-bearing coal bed methane by a vacuum pressure swing adsorption process: performance study and safety analysis [J ] . Energy & Fuels , 2016 , 30 ( 2 ): 1496 - 1509 .
Zhou Y , Shen Y , Fu Q , et al . CO enrichment from low-concentration syngas by a layered-bed VPSA process [J ] . Industrial & Engineering Chemistry Research , 2017 , 56 ( 23 ): 6741 - 6754 .
Joss L , Gazzani M , Hefti M , et al . Temperature swing adsorption for the recovery of the heavy component: an equilibrium-based shortcut model [J ] . Industrial & Engineering Chemistry Research , 2015 , 54 ( 11 ): 3027 - 3038 .
Nikolaidis G N , Kikkinides E S , Georgiadis M C . An integrated two-stage P/VSA process for postcombustion CO 2 capture using combinations of adsorbents zeolite 13X and Mg-MOF-74 [J ] . Industrial & Engineering Chemistry Research , 2017 , 56 ( 4 ): 974 - 988 .
Shen C , Liu Z , Li P , et al . Two-stage VPSA process for CO 2 capture from flue gas using activated carbon beads [J ] . Industrial & Engineering Chemistry Research , 2012 , 51 ( 13 ): 5011 - 5021 .
Wang L , Liu Z , Li P , et al . CO 2 capture from flue gas by two successive VPSA units using 13XAPG [J ] . Adsorption , 2012 , 18 ( 5 / 6 ): 445 - 459 .
查看原文
0
浏览量
1
下载量
1
CSCD
Alert me when the article has been cited
文章被引用时，请邮件提醒。
提交
工具集
下载
- 网络PDF下载
- Meta-XML下载
参考文献导出
- BibTeX下载
- Endnote下载
- RefMan 下载
- NoteExpress下载
- NoteFirst下载
分享
分享给微信好友或者朋友圈
收藏
添加至我的专辑
关联资源
相关文章
煤化工废盐中杂质对NaCl和Na2SO4溶剂化影响研究
基于成核理论改进的减压波计算模型
四元体系NH4+， Mg2+， Ca2+ // SO42--H2O多温相平衡研究及其应用
改性KHCO3/CO2协同抑制CH4/H2预混气体爆炸火焰实验研究
硫功能化M2N型MXene的钠离子多层吸附性能增强机制
相关作者
程文婷
王恩琪
程芳琴
殷布泽
黄维和
欧阳欣
赵雪峰
孟岚
相关机构
山西大学资源与环境工程研究所
固体废弃物资源化国家工程研究中心
中国石油大学（华东）储运与建筑工程学院，山东省油气与新能源储运安全重点实验室
中国石油天然气股份有限公司
国家管网集团科学技术研究总院分公司
选择翻译语言
- 地址：北京市东城区青年湖南街13号
- 技术支持由北京北大方正电子有限公司提供 京ICP备12046843号-3
京公网安备11010102001995号 - 本系统建议在Chrome、 IE9+ 以上版本浏览器阅读本站内容，360浏览器请切换至极速模式
- Cookies帮助我们提供服务并提供个性化体验。使用本网站，即表示您同意我们使用Cookies
0
批量引用
导出至
BibTeXEndnoteRefManNoteExpressNoteFirst
回到顶部