生活垃圾热解半焦-热解油重整过程中水分的消耗与转移

雷开元; 陈德珍

doi:10.11949/0438-1157.20190663

您当前的位置：

首页 >

文章列表页 >

生活垃圾热解半焦-热解油重整过程中水分的消耗与转移

能源和环境工程 | 更新时间：2026-07-24

- 生活垃圾热解半焦-热解油重整过程中水分的消耗与转移
- Water consumption and transfer during MSW pyrolysis char-vaporized pyrolysis oil reforming process
- 化工学报 2019年70卷第12期页码：4795-4803
- 作者机构：
  
  同济大学热能与环境工程研究所，上海 200092
- 作者简介：
  
  雷开元（1995—），男，硕士研究生，leikaiyuan0428@163.com
  陈德珍（1969—），女，博士，教授，chendezhen@tongji.edu.cn
- 基金信息：
  
  国家自然科学基金面上项目(51776141)
- DOI：10.11949/0438-1157.20190663
  中图分类号： X 705
- 收稿：2019-06-13，
  
  修回：2019-08-18，
  
  网络首发：2020-06-09，
  
  纸质出版：2019-12-05
- 稿件说明：
移动端阅览
雷开元, 陈德珍. 生活垃圾热解半焦-热解油重整过程中水分的消耗与转移[J]. 化工学报, 2019, 70(12): 4795-4803

LEI Kaiyuan, CHEN Dezhen. Water consumption and transfer during MSW pyrolysis char-vaporized pyrolysis oil reforming process[J]. CIESC Journal, 2019, 70(12): 4795-4803
雷开元, 陈德珍. 生活垃圾热解半焦-热解油重整过程中水分的消耗与转移[J]. 化工学报, 2019, 70(12): 4795-4803 DOI： 10.11949/0438-1157.20190663.

LEI Kaiyuan, CHEN Dezhen. Water consumption and transfer during MSW pyrolysis char-vaporized pyrolysis oil reforming process[J]. CIESC Journal, 2019, 70(12): 4795-4803 DOI： 10.11949/0438-1157.20190663.

摘要

热解炭原位重整城市固体废物的挥发分是改善热解产物的良好方法。在这个过程中，水蒸气在产品转化中起着重要作用。为了了解水分在重整过程中的作用，本研究中将热解液中的油相和水相分离，然后用D

O代替重整过程中的水相，以跟踪液体、气体和固体之间的氢转移。热解油/焦炭重整过程在600、700和800℃下进行。用GC-MS（气相色谱质谱法）分析重整后液体中的油相；IR-MS（同位素比质谱法）分析重整后液体和固体中的氘浓度。研究发现，在实验温度范围内，水蒸气对焦炭的气化作用非常弱，当D

O/焦炭的比例为2/1时，D

O中2％（质量）的氘在反应后残留在炭中;但水蒸气与热解油的气化反应很强烈，在800℃时，78.68％（质量）的热解液（水油混合物）被气化

且热解油中脂肪烃被大量分解，重整液的油相组分中芳香烃占到96.17%；同时，当D

O/油的比例为2/3时，D

O中59％的氘转移到合成气中。研究结果将为生活垃圾热解处理控制最终产物提供理论指导。

Abstract

The

in situ

reforming of volatiles from municipal solid waste by pyrolytic carbon is a good method for improving pyrolysis products. In this process water vapor plays an important role on product conversion. In order to understand the role of water vapor during the reforming process

oil phase and aqueous phase in the pyrolysis liquid are separated and then D

O was used to replace the aqueous phase to mix with oil so that hydrogen transfer between liquid

gas and solid can be tracked in the reforming process. The vaporized oil/char reforming process was performed at 600℃

700℃ and 800℃

respectively. The oil phase and deuterium concentration in the liquid (oil and aqueous phase together) after reforming were measured with help of GC-MS and I

R-MS(isotope ratio mass spectrometry); at the same time deuterium concentration in the solid phase was also checked. It has been found that char gasification by water vapor at all testing temperature ranges is very weak

at 700℃ 2% of deuterium in D

O was remained in the char when the ratio of D

O/char was 2/1. While oil gasification by water vapor during char-catalytic reforming process is very intense: at 800℃ 78.68% of total oil-water mixture is gasified

and the aliphatic hydrocarbons in the oil are decomposed to a large extent

but the aromatic hydrocarbons are found to account for 96.17% of the oil phase after reforming. Simultaneously 59% of deuterium in D

O was found to transfer into syngas when the ratio of D

O/oil was 2/3. The research results obtained here will provide guide for improving the final products of MSW pyrolysis.

关键词

Keywords

references

中华人民共和国国家统计局 . 中国统计年鉴2018 [M ] . 北京 : 中国统计出版社 , 2018 .

National Bureau of Statistics of People s Republic of China . China Statistical Yearbook 2018 [M ] . Beijing : China Statistics Press , 2018 .

Chen D , Yin L , Wang H , et al . Reprint of: pyrolysis technologies for municipal solid waste: a review [J ] . Waste Management , 2015 , 37 : 116 - 136 .

Zhang Q , Chang J , Wang T , et al . Review of biomass pyrolysis oil properties and upgrading research [J ] . Energy Conversion and Management , 2007 , 48 ( 1 ): 87 - 92 .

Xie Y R , Shen L H , Xiao J , et al . Influences of additives on steam gasification of biomass(1): Pyrolysis procedure [J ] . Energy & Fuels , 2009 , 23 ( 10 ): 5199 - 5205 .

Azuara M , Fonts I , Bimbela F , et al . Catalytic post-treatment of the vapors from sewage sludge pyrolysis by means of γ-Al 2 O 3 : effect on the liquid product properties [J ] . Fuel Processing Technology , 2015 , 130 : 252 - 262 .

Huang Q , Lu P , Hu B , et al . Cracking of model tar species from the gasification of municipal solid waste using commercial and waste-derived catalysts [J ] . Energy & Fuels , 2016 , 30 ( 7 ): 5740 - 5748 .

李佳珊 . 城市生活垃圾热解过程中重金属残留实验研究 [D ] . 沈阳 : 东北大学 , 2009 .

Li J S . Experimental study on heavy metal residues in pyrolysis of municipal solid waste [D ] . Shenyang : Northeastern University , 2009 .

Liu S , Yin W , Wu R , et al . Fundamentals of catalytic tar removal over in situ and ex situ chars in two-stage gasification of coal [J ] . Energy & Fuels , 2014 , 28 ( 1 ): 58 - 66 .

Min Z , Yimsiri P , Asadullah M , et al . Catalytic reforming of tar during gasification (Ⅱ): Char as a catalyst or as a catalyst support for tar reforming [J ] . Fuel , 2011 , 90 ( 7 ): 2545 - 2552 .

Wang N , Chen D , Arena U , et al . Hot char-catalytic reforming of volatiles from MSW pyrolysis [J ] . Applied Energy , 2017 , 191 : 111 - 124 .

King H H , Stock L M . Aspects of the chemistry of donor solvent coal dissolution. The hydrogen-deuterium exchange reactions of tetralin-d 12 with Illinois No. 6 coal, coal products and related compounds [J ] . Fuel , 1982 , 61 ( 3 ): 257 - 264 .

Cronauer D C , Mcneil R I , Young D C , et al . Hydrogen/deuterium transfer in coal liquefaction [J ] . Fuel , 1982 , 61 ( 7 ): 610 - 619 .

Brandes S D , Graff R A , Gorbaty M L , et al . Modification of coal by subcritical steam: an examination of modified Illinois No. 6 coal [J ] . Energy & Fuels , 1989 , 3 ( 4 ): 494 - 498 .

Wilson M A , Vassallo A M , Collin P J , et al . Deuterium as a tracer in coal liquefaction (2): Non-catalytic studies [J ] . Fuel Processing Technology , 1984 , 8 ( 3 ): 213 - 229 .

Collin P J , Wilson M A . Use of INEPT and GASPE n.m.r. pulse sequences: assignment of position of incorporation of deuterium into tetralin during coal hydrogenation [J ] . Fuel , 1983 , 62 ( 11 ): 1243 - 1246 .

Skowronski R P , Ratto J J , Goldberg I B , et al . Hydrogen incorporation during coal liquefaction [J ] . Fuel , 1984 , 63 ( 4 ): 440 - 448 .

Wang L , Pan T , Liu P , et al . Hydrogen transfer route during hydrothermal treatment lignite using isotope tracer method and improving pyrolysis tar yield [J ] . Energy & Fuels , 2016 , 30 ( 6 ): 121 - 134 .

连奕新 , 杨意泉 , 方维平 . 钴钼基水煤气变换催化剂及其催化反应工艺 [J ] . 石油化工 , 2011 , 40 ( 4 ): 347 - 357 .

Lian Y X , Yang Y Q , Fang W P . Cobalt-molybdenum-based water gas shift catalyst and catalytic reaction process thereof [J ] . Petrochemical Industry , 2011 , 40 ( 4 ): 347 - 357 .

Lima A A G , Nele M , Moreno E L , et al . Composition effects on the activity of Cu-ZnO-Al 2 O 3 based catalysts for the water gas shift reaction: a statistical approach [J ] . Applied Catalysis A General , 1998 , 171 ( 1 ): 31 - 43 .

Klinghoffer N B , Castaldi M J , Nzihou A . Influence of char composition and inorganics on catalytic activity of char from biomass gasification [J ] . Fuel , 2015 , 157 : 37 - 47 .

Badger G M , Kimber R W L , Spotswood T M . Mode of formation of 3, 4-benzopyrene in human environment [J ] . Nature , 1960 , 187 ( 4738 ): 663 - 665 .

Nelson P F , Smith I W , Tyler R J , et al . Pyrolysis of coal at high temperatures [J ] . Energy & Fuels , 1988 , 2 ( 4 ): 391 - 400 .

Stock L M , Wasielewski M R . The trifluoromethyl group in chemistry and spectroscopy . Carbon-fluorine hyperconjugation [M ] //Taft R W. Progress in Physical Organic Chemistry . John Wiley & Sons, Inc ., 1981 : 253 - 313 .

翟建荣 , 钟梅 , 马凤云 , 等 . 水蒸气对煤焦油模化物裂解行为及析碳的影响 [J ] . 化工学报 , 2019 , 70 ( 8 ): 2898 - 2908 .

Zhai J R , Zhong M , Ma F Y , et al . Effect of steam atmosphere on cracking behavior and carbon deposition of coal tar model compounds [J ] . CIESC Journal , 2019 , 70 ( 8 ): 2898 - 2908 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

重氧水分离级联中氘和氧18浓度分布及其影响

聚丙烯废塑料热解制可再生燃料中试研究

Ca（OH）2/CaO间接反应器储释热循环性能优化

压力波强化横掠管束传热实验研究

高速高温箔片端面密封热气弹耦合性能分析