离子液体法再生纤维素纤维制造技术及发展趋势

王均凤; 聂毅; 王斌琦; 康召青; 周乐; 潘凤娇; 张香平

doi:10.11949/0438-1157.20190621

您当前的位置：

首页 >

文章列表页 >

离子液体法再生纤维素纤维制造技术及发展趋势

综述与专论 | 更新时间：2026-07-24

- 离子液体法再生纤维素纤维制造技术及发展趋势
- Manufacturing technology and development direction on regenerated cellulose fibers using ionic liquids
- 化工学报 2019年70卷第10期页码：3836-3846
- 作者机构：
  
  1.郑州中科新兴产业技术研究院（中科院过程所郑州分所），河南郑州 450000
  2.中国科学院过程工程研究所多相复杂系统国家重点实验室，北京 100190
- 作者简介：
  
  王均凤（1974—），女，博士，副研究员，junfwang@ipe.ac.cn
  张香平（1969—），女，博士，研究员，xpzhang@ipe.ac.cn
- 基金信息：
  
  国家自然科学基金项目(21576262;21776276);北京市自然科学基金项目(2182070)
- DOI：10.11949/0438-1157.20190621
  中图分类号： TQ 028.8
- 收稿：2019-06-04，
  
  修回：2019-07-12，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-10-05
- 稿件说明：
移动端阅览
王均凤, 聂毅, 王斌琦, 康召青, 周乐, 潘凤娇, 张香平. 离子液体法再生纤维素纤维制造技术及发展趋势[J]. 化工学报, 2019, 70(10): 3836-3846

WANG Junfeng, NIE Yi, WANG Binqi, KANG Zhaoqing, ZHOU Le, PAN Fengjiao, ZHANG Xiangping. Manufacturing technology and development direction on regenerated cellulose fibers using ionic liquids[J]. CIESC Journal, 2019, 70(10): 3836-3846
王均凤, 聂毅, 王斌琦, 康召青, 周乐, 潘凤娇, 张香平. 离子液体法再生纤维素纤维制造技术及发展趋势[J]. 化工学报, 2019, 70(10): 3836-3846 DOI： 10.11949/0438-1157.20190621.

WANG Junfeng, NIE Yi, WANG Binqi, KANG Zhaoqing, ZHOU Le, PAN Fengjiao, ZHANG Xiangping. Manufacturing technology and development direction on regenerated cellulose fibers using ionic liquids[J]. CIESC Journal, 2019, 70(10): 3836-3846 DOI： 10.11949/0438-1157.20190621.

摘要

首先概述了再生纤维素纤维制造技术的发展历史，总结了以天然纤维素为原料的黏胶纤维、Lyocell纤维和离子液体纤维（Ioncell）及其技术发展现状。重点介绍了这三种再生纤维素纤维的性能、应用领域及市场前景，并比较了其生产工艺，包括纺丝原液的制备、纺丝工艺、溶剂回收等。与黏胶纤维相比，Lyocell 纤维和Ioncell纤维在溶解纤维素及干喷湿纺纺丝方面具有独特的优势。进一步对该类技术的重点和难点，如纺丝原液的连续制备和溶剂的高效回收进行了分析。与Lyocell纤维使用的NMMO溶剂相比，Ioncell纤维使用的离子液体具有离子液体可设计等优点，可根据纤维素原料的不同来源，设计合成对纤维素具有更好的溶解能力而无降解特征且环境友好的离子液体溶剂，同时对温度、金属离子具有很好的稳定性，为发展新一代纤维素绿色制造技术提供了新途径。另外，对Ioncell纤维存在的问题也进行了详细的分析，提出了未来拟开展的重点研究方向和拟解决的关键难题。

Abstract

Based on the history of cellulose fiber development

the progress of three kinds of fibers

. viscous fiber

Lyocell fiber and ionic liquid fiber (Ioncell) with natural cellulose as raw materials are summarized. Firstly

the development history of regenerated cellulose fiber manufacturing technology is summarized

and the development status of viscose fiber

Lyocell fiber and ionic liquid fiber (Ioncell) with natural cellulose as raw material is summarized. In this work

the performance

application field

and market prospect are mainly introduced

and their technologies including spinning technology

the preparation of spinning solution

and the methods of solvent recovery are compared. In comparison with viscous fiber

both the dissolution of cellulose and the dry-jet wet spinning for the other two fibers show unique advantages. But their key points lie in the continuous preparation of spinning solution and efficient recovery of solvent. Compared to the NMMO solvent used by Lyocell fiber

ionic liquids (ILs) used by Ioncell fiber have the advantages of negligible volatility and properties tunable. Therefore

this kind of ILs with high solubility but without degradation ability of cellulose

high thermal stability to water and metal ions

and little environmental impact can be designed

which provide a new approach for the development of green spinning technology. In addition

the existing problems of Ioncell fiber are analyzed

and some research direction for the two kinds of fibers produce

d by solvent method are pointed out.

关键词

Keywords

references

Woodings C . Regenerated Cellulose Fibres [M ] . Amsterdam : Elsevier , 2001 .

Zhou R , Li C G , Yang M X . Comparative study on structural performance of several new regenerated cellulose fibers [J ] . Advanced Materials Research , 2012 , 573 / 574 : 174 - 180 .

杨明霞 , 沈兰萍 . 新型再生纤维素纤维的现状及发展趋势 [J ] . 纺织科技进展 , 2011 , ( 2 ): 16 - 20 .

Yang M X , Shen L P . Development status and strend of new regenerated cellulose fiber [J ] . Progress in Textile Science & Technology , 2011 , ( 2 ): 16 - 20 .

李雄彪 . 纤维素的化学结构,生物合成和糖化研究 [J ] . 大自然探索 , 1992 , ( 1 ): 56 - 62 .

Li X B . Structure, biosynthesis and saccharification of cellulose [J ] . Exploration of Nature , 1992 , ( 1 ): 56 - 62 .

刘洁 , 杨肖婉 , 齐静 . 再生纤维素纤维溶剂体系的发展 [J ] . 纺织导报 , 2018 , ( 3 ): 36 - 38 .

Liu J , Yang X W , Qi J . The development of solvent system for regenerated cellulose fiber [J ] . China Textile Leader , 2018 , ( 3 ): 36 - 38 .

Perepelkin K . Ways of developing chemical fibres based on cellulose: viscose fibres and their prospects (Part 1): Development of viscose fibre technology. Alternative hydrated cellulose fibre technology [J ] . Fibre Chemistry , 2008 , 40 ( 1 ): 10 - 23 .

Moritz A J L , Jackson A L , Thurmond G I . Manufacture of rayon: US 2346696 [P ] . 1944-4-18 .

季柳炎 . 从百年发展史看粘胶纤维之未来 [J ] . 纺织科学研究 , 2017 , ( 10 ): 25 - 29 .

Ji L Y . Prospecting the future of viscose fiber from the development history of one hundred year [J ] . Textile Science Research , 2017 , ( 10 ): 25 - 29 .

刘为民 . 上规模降成本增效益——粘胶纤维行业及上市公司比较分析 [J ] . 中国纺织 , 1999 , ( 6 ): 20 - 23 .

Liu W M . Upscale, cutting cose, increasing benefit—comparative analysis of viscose fiber industry and listed cmpany [J ] . China Textile , 1999 , ( 6 ): 20 - 23 .

季柳炎 . 2018~2019年我国粘胶短纤维市场回顾与展望 [J ] . 人造纤维 , 2019 , ( 1 ): 28 - 32 .

Ji L Y . Review and prospect of viscose staple fiber market in China from 2018 to 2019 [J ] . Artificial Fiber , 2019 , ( 1 ): 28 - 32 .

Ranabhat R . Environmental impact of textile fibers: a case study of Nextiili-paja [D ] . Tampere : Tampere University of Applied Sciences , 2019 : 15 - 16 .

Zhang H X , Zhang X C , Xu R C . Structure and thermo-regulated performance of outlast viscose fiber [J ] . Advanced Materials Research , 2011 , 332 / 333 / 334 : 812 - 815 .

Konwarh R , Karak N , Misra M . Electrospun cellulose acetate nanofibers: the present status and gamut of biotechnological applications [J ] . Biotechnology Advances , 2013 , 31 ( 4 ): 421 - 437 .

Hatua P , Majumdar A , Das A . Comparative analysis of in vitro ultraviolet radiation protection of fabrics woven from cotton and bamboo viscose yarns [J ] . Journal of the Textile Institute Proceedings & Abstracts , 2013 , 104 ( 7 ): 708 - 714 .

董奎勇 , 杨萍 . Lyocell纤维发展概况及趋势 [J ] . 中国纤检 , 2004 , ( 11 ): 40 - 42 .

Dong K Y , Yang P . Developmet situation and trend of Lyocell fiber [J ] . China Fiber Inspection , 2004 , ( 11 ): 40 - 42 .

王乐军 , 刘怡宁 , 房迪 , 等 . Lyocell纤维的国内外研发现状与发展方向 [J ] . 纺织学报 , 2017 , 38 ( 4 ): 164 - 170 .

Wang L J , Liu Y N , Fang D , et al . Status and development research of Lyocell fiber at home and abroad [J ] . Journal of Textile Research , 2017 , 38 ( 4 ): 164 - 170 .

Swatloski R P , Spear S K , Holbrey J D , et al . Dissolution of cellulose with ionic liquids [J ] . Journal of America Chemistry Society , 2002 , 124 ( 18 ): 4974 - 4975 .

Sun N , Swatloski R P , Maxim M L , et al . Magnetite-embedded cellulose fibers prepared from ionic liquid [J ] . Journal of Materials Chemistry , 2008 , 18 ( 3 ): 283 - 290 .

Jiang G S , Huang W F , Wang B C , et al . The changes of crystalline structure of cellulose during dissolution in 1-butyl-3-methylimidazolium chloride [J ] . Cellulose , 2012 , 19 ( 3 ): 679 - 685 .

Jiang G S , Huang W F , Li L , et al . Structure and properties of regenerated cellulose fibers from different technology processes [J ] . Carbohydrate Polymers , 2012 , 87 ( 3 ): 2012 - 2018 .

Liu Y R , Thomsen K , Nie Y , et al . Predictive screening of ionic liquids for dissolving cellulose and experimental verification [J ] . Green Chemistry , 2016 , 18 ( 23 ): 6246 - 6254 .

Hermanutz F , Vocht M P , Panzier N , et al . Processing of cellulose using ionic liquids [J ] . Macromolecular Materials and Engineering , 2019 , 304 : 1 - 8 .

任强 , 武进 , 张军 , 等 . 1-烯丙基-3-甲基咪唑室温离子液体的合成及其对纤维素溶解性能的初步研究 [J ] . 高分子学报 , 2003 , ( 3 ): 448 - 451 .

Ren Q , Wu J , Zhang J , et al . Synthesis of 1-allyl-3-methylimicazolium-based room temperature ionic liquid and preliminary study of its dissolving cellulose [J ] . Acta Polymerica Sinica , 2003 , ( 3 ): 448 - 451 .

Zhang H , Wang Z G , Zhang Z N , et al . Regenerated-cellulose/multiwalled-carbon-nanotube composite fibers with enhanced mechanical properties prepared with the ionic liquid 1-allyl-3-methylimidazolium chloride [J ] . Advance Materials , 2007 , 19 ( 5 ): 698 - 704 .

Hermanutz F , Gaehr F , Uerdingen E , et al . New developments in dissolving and processing of cellulose in ionic liquids [J ] . Macromolecular Symposia , 2008 , 262 : 23 - 27 .

Fukaya Y , Hayashi K , Wada M , et al . Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions [J ] . Green Chemistry , 2008 , 10 ( 1 ): 44 - 46 .

Nie Y , Li C X , Sun A J , et al . Extractive desulfurization of gasoline using imidazolium-based phosphoric ionic liquids [J ] . Energy & Fuel , 2006 , 20 ( 5 ): 2083 - 2087 .

Kamiya N , Matsushita Y , Hanaki M , et al . Enzymatic in situ saccharification of cellulose in aqueous-ionic liquid media [J ] . Biotechnology Letters , 2008 , 30 ( 6 ): 1037 - 1040 .

Zhu C , Richardson R M , Potter K D , et al . High modulus regenerated cellulose fibers spun from a low molecular weight microcrystalline cellulose solution [J ] . ACS Sustainable Chemistry & Engineering , 2016 , 4 ( 9 ): 4545 - 4553 .

Zhu C C , Koutsomitopoulou A F , Eichhorn S J , et al . High stiffness cellulose fibers from low molecular weight microcrystalline cellulose solutions using DMSO as co-solvent with ionic liquid [J ] . Macromolecular Materials and Engineering , 2018 , 303 ( 5 ): 1 - 6 .

Sixta H , Michud A , Hauru L , et al . Ioncell-F: a high-strength regenerated cellulose fiber [J ] . Nord. Pulp. Pap. Res. J ., 2015 , 30 ( 1 ): 43 - 57 .

Michud A , Tanttu M , Asaadi S , et al . Ioncell-F: ionic liquid-based cellulosic textile fibers as an alternative to viscose and Lyocell [J ] . Textile Research Journal , 2016 , 86 ( 5 ): 543 - 552 .

Stepan A M , Michud A , Helisten S , et al . IONCELL-P&F: pulp fractionation and fiber spinning with ionic liquids [J ] . Industrial & Engineering Chemistry Research , 2016 , 55 ( 29 ): 8225 - 8233 .

Asaadi S , Hummel M , Ahvenainen P , et al . Structural analysis of Ioncell-F fibers from birch wood [J ] . Carbohydrate Polymers , 2018 , 181 : 893 - 901 .

Ma Y , Hummel M , Kontro I , et al . High performance man-made cellulosic fibers from recycled newsprint [J ] . Green Chemistry , 2018 , 20 ( 1 ): 160 - 169 .

Hummel M , Michud A , Tanttu M , et al . Ionic liquids for the production of man-made cellulosic fibers opportunities and challenges [M ] // Rojas O J. Advances in Polymer Science . Berlin : Springer , 2016 : 133 - 168 .

Chen J H , Xu J K , Huang P L , et al . Effect of alkaline pretreatment on the preparation of regenerated lignocellulose fibers from bamboo stem [J ] . Cellulose , 2016 , 23 ( 4 ): 2727 - 2739 .

Hauru L K J , Hummel M , Michud A , et al . Dry jet-wet spinning of strong cellulose filaments from ionic liquid solution [J ] . Cellulose , 2014 , 21 ( 6 ): 4471 - 4481 .

Yoo M K , Reza M S , Kim I M , et al . Physical properties and fibrillation tendency of regenerated cellulose fiber dry jet-wet spun from high-molecular weight cotton linter Pulp/NMMO solution [J ] . Fiber and Polymers , 2015 , 16 ( 8 ): 1618 - 1628 .

Kreze T , Malej S . Structural characteristics of new and conventional regenerated cellulosic fibers [J ] . Textile Research Journal , 2003 , 73 ( 8 ): 675 - 684 .

Chen J H , Guan Y , Wang K , et al . Regulating effect of hemicelluloses on the preparation and properties of composite Lyocell fibers [J ] . Cellulose , 2015 , 22 ( 3 ): 1505 - 1516 .

Sharma A , Nagarkar S , Thakre S , et al . Structure–property relations in regenerated cellulose fibers: comparison of fibers manufactured using viscose and Lyocell processes [J ] . Cellulose , 2019 , 26 ( 6 ): 3655 - 3669 .

Carrillo F , Colom X , Suñol J J , et al . Structural FTIR analysis and thermal characterisation of Lyocell and viscose-type fibers [J ] . European Polymer Journal , 2004 , 40 ( 9 ): 2229 - 2234 .

de Silva R , Byrne N . Utilization of cotton waste for regenerated cellulose fibres: Influence of degree of polymerization on mechanical properties [J ] . Carbohydrate Polymers , 2017 , 174 : 89 - 94 .

Bulota M , Michud A , Hummel M , et al . The effect of hydration on the micromechanics of regenerated cellulose fibers from ionic liquid solutions of varying draw ratios [J ] . Carbohydrate Polymers , 2016 , 151 : 1110 - 1114 .

Asaadi S , Hummel M , Hellsten S , et al . Renewable high-performance fibers from the chemical recycling of cotton waste utilizing an ionic liquid [J ] . ChemSusChem , 2016 , 9 : 3250 - 3258 .

Michud A , Hummel M , Sixta H . Influence of process parameters on the structure formation of man-made cellulosic fibers from ionic liquid solution [J ] . Journal of Applied Polymer Science , 2016 , 133 ( 30 ): 43718 - 43726 .

纤维材料的特征及行业市场需求情况分析 [EB/OL ] . [ 2019-05-29 ] . http://market.chinabaogao.com/huagong/1223049392017.html http://market.chinabaogao.com/huagong/1223049392017.html .

Characteristics of fiber material and demand analysis of industrial market [EB/OL ] . [ 2019-05-29 ] . http://market.chinabaogao.com/huagong/1223049392017.html http://market.chinabaogao.com/huagong/1223049392017.html .

再生纤维机会来临发展前景好 [EB/OL ] . [ 2019-05-29 ] . https://www.tnc.com.cn/info/c-011002-d-3351458.html https://www.tnc.com.cn/info/c-011002-d-3351458.html .

Good development future of regenerated fiber [EB/OL ] . [ 2019-05-29 ] . https://www.tnc.com.cn/info/c-011002-d-3351458.html https://www.tnc.com.cn/info/c-011002-d-3351458.html .

全球化纤中短期发展预测及产业用纤维发展趋势 [EB/OL ] . [ 2019-05-29 ] . http://smartruby. com. tw/file/02-%E5%85%A8% E7%90%83%E4%B8%AD%E7%9F%AD%E6%9C%9F%E5%8C%96%E5%AD%A6%E7%BA%A4%E7%BB%B4%E4%BE%9B%E7%BB%99%E9%9C%80%E6%B1%82% E9% A2%84%E6%B5%8B%E5%92%8C%E8%B6%8B%E5%8A%BF%E7%A0%94%E7%A9%B6%20-%20Hideshi%20UEDA.pdf http://smartruby. com. tw/file/02-%E5%85%A8% E7%90%83%E4%B8%AD%E7%9F%AD%E6%9C%9F%E5%8C%96%E5%AD%A6%E7%BA%A4%E7%BB%B4%E4%BE%9B%E7%BB%99%E9%9C%80%E6%B1%82% E9% A2%84%E6%B5%8B%E5%92%8C%E8%B6%8B%E5%8A%BF%E7%A0%94%E7%A9%B6%20-%20Hideshi%20UEDA.pdf .

Forecast of mid- or short-fiber and development trend of industrial fiber in the world [EB/OL ] . [ 2019-05-29 ] . http://smartruby. com. tw/file/02-%E5%85%A8%E7%90%83%E4%B8%AD%E7%9F%AD%E6%9C%9F%E5%8C%96%E5%AD%A6%E7%BA%A4%E7%BB%B4%E4%BE%9B%E7%BB%99%E9%9C%80%E6%B1%82%E9%A2%84%E6%B5%8B%E5%92%8C%E8%B6%8B%E5%8A%BF%E7%A0%94%E7%A9%B6%20-%20Hideshi%20UEDA.pdf http://smartruby. com. tw/file/02-%E5%85%A8%E7%90%83%E4%B8%AD%E7%9F%AD%E6%9C%9F%E5%8C%96%E5%AD%A6%E7%BA%A4%E7%BB%B4%E4%BE%9B%E7%BB%99%E9%9C%80%E6%B1%82%E9%A2%84%E6%B5%8B%E5%92%8C%E8%B6%8B%E5%8A%BF%E7%A0%94%E7%A9%B6%20-%20Hideshi%20UEDA.pdf .

汪进秋 . 粘胶纤维生产工艺技术 [J ] . 人造纤维 , 2000 , ( 1 ): 42 - 44 .

Wang J Q . Technology of viscose fiber [J ] . Artificial Fiber , 2000 , ( 1 ): 42 - 44 .

王建荣 , 刘杰 . 浸渍压榨液半纤维素含量测定方法改进探讨 [J ] . 人造纤维 , 2014 , 44 ( 6 ): 25 - 27 .

Wang J R , Liu J . Improvement discussion for the measurement method of hemicellulose content in the pressed liquor [J ] . Artificial Fiber , 2014 , 44 ( 6 ): 25 - 27 .

Rajalaxmi D , Jiang N , Leslie G , et al . Synthesis of novel water-soluble sulfonated cellulose [J ] . Carbohydrate Research , 2010 , 345 ( 2 ): 284 - 290 .

Ivanov A A , Rzhevtseva Y I , Kim V P . Effect of precipitation bath composition on the process of spinning viscose yarn [J ] . Fiber Chemistry , 1987 , 19 ( 1 ): 57 - 60 .

Wilkes A G . The viscose process [M ] // Woodings C. Regenerated Cellulose Fibers . England : Woodhead Publishing Limited , 2001 : 37 - 61 .

Wu C , Zhou S , Zhao C , et al . Improved reactivity of bamboo dissolving pulp for the viscose process: post-treatment with beating [J ] . BioResources , 2014 , 9 ( 2 ): 3449 - 3455 .

雷海斌 . Lyocell纤维纺丝溶剂NMMO溶液蒸发特性研究 [J ] . 福建轻纺 , 2017 , ( 8 ): 33 - 35 .

Lei H B . Study on evaporation characteristic of NMMO solution obtained during the process of Lyocell fiber spinning [J ] . The Light&Textile Industries of Fujian , 2017 , ( 8 ): 33 - 35 .

Kosan B , Michels C , Meister F . Dissolution and forming of cellulose with ionic liquids [J ] . Cellulose , 2008 , 15 ( 1 ): 59 - 66 .

Zhang J M , Zhang H , Wu J , et al . NMR spectroscopic studies of cellulose solvation in [Emim]Ac aimed to understand the dissolution mechanism of cellulose in ionic liquids [J ] . Physical Chemistry Chemical Physics , 2010 , 12 ( 8 ): 1941 - 1947 .

Li Y , Wang J J , Liu X M , et al . Towards a molecular understanding of cellulose dissolution in ionic liquids: anion/cation effect, synergistic mechanism and physicochemical aspects [J ] . Chemical Science , 2018 , 9 ( 17 ): 4027 - 4043 .

Feng L , Chen Z I . Research progress on dissolution and functional modification of cellulose in ionic liquids [J ] . Journal of Molecular Liquids , 2008 , 142 ( 1-3 ): 1 - 5 .

Xu J L , Yao X Q , Xin J Y , et al . An effective two-step ionic liquids method for cornstalk pretreatment [J ] . Journal of Chemical Technology & Biotechnology , 2015 , 90 ( 11 ): 2057 - 2065 .

Zhong X J , Fan Z , Liu Z P , et al . Local structure evolution and its connection to thermodynamic and transport properties of 1-butyl-3-methylimidazolium tetrafluoroborate and water mixtures by molecular dynamics simulations [J ] . The Journal of Physical Chemistry B , 2012 , 116 : 3249 - 3263 .

Wang J F , Luo J Q , Zhang X P , et al . Concentration of ionic liquids by nanofiltration for recycling: filtration behavior and modeling [J ] . Separation & Purification Technology , 2016 , 165 : 18 - 26 .

Deng Y , Long T , Zhang D , et al . Phase diagram of [Amim]Cl plus salt aqueous biphasic systems and its application for [Amim]Cl recovery [J ] . Journal of Chemical & Engineering Data , 2009 , 54 ( 9 ): 2470 - 2473 .

Li C , Han J , Wang Y , et al . Phase behavior for the aqueous two-phase systems containing the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate and kosmotropic salts [J ] . Journal of Chemical & Engineering Data , 2009 , 55 ( 3 ): 1087 - 1092 .

Peng X , Hu Y , Liu Y , et al . Separation of ionic liquids from dilute aqueous solutions using the method based on CO 2 hydrates [J ] . Journal of Natural Gas Chemistry , 2010 , 19 ( 1 ): 81 - 85 .

Wang J , Luo J , Zhang X , et al . Concentration of ionic liquids by nanofiltration for recycling: filtration behavior and modeling [J ] . Separation and Purification Technology , 2016 , 165 : 18 - 26 .

Gan Q , Xue M , Rooney D . A study of fluid properties and microfiltration characteristics of room temperature ionic liquids [C10min ] [NTf 2 ] and N 8881 [ NTf 2 ] and their polar solvent mixtures [J ] . Separation and Purification Technology , 2006 , 51 ( 2 ): 185 - 192 .

Wang X , Nie Y , Zhang X , et al . Recovery of ionic liquids from dilute aqueous solutions by electrodialysis [J ] . Desalination , 2012 , 285 : 205 - 212 .

Huang K L , Wu R , Cao Y , et al . Recycling and reuse of ionic liquid in homogeneous cellulose acetylation [J ] . Chinese Journal of Chemical Engineering , 2013 , 21 ( 5 ): 577 - 584 .

Earle M J , Seddon K R . Preparation of imidazole carbenes and the use thereof for the synthesis of ionic liquids: WO/2001/077081 [P ] . 2001-04-05 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

聚合物基疏水渗透汽化膜及其溶剂回收应用

白炭黑填充PDMS/PVDF复合膜的纳滤分离性能及传质特性

不同交联剂对PDMS/PVDF纳滤膜溶剂回收性能的影响

煤化工废盐中杂质对NaCl和Na2SO4溶剂化影响研究

GeCl4-MxCly-H2体系下锗-杂质竞争沉积热力学研究