金属有机框架光催化剂微环境调控研究进展

安珂; 杨冬; 赵展烽; 任汉杰; 陈瑶; 周致远; 姜忠义

doi:10.11949/0438-1157.20190601

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金属有机框架光催化剂微环境调控研究进展

综述与专论 | 更新时间：2026-07-24

- 金属有机框架光催化剂微环境调控研究进展
- Research progress on microenvironment regulation of metal-organic framework photocatalyst
- 化工学报 2019年70卷第10期页码：3776-3790
- 作者机构：
  
  1.天津大学化工学院绿色化学化工教育部重点实验室，天津 300072
  2.天津化学化工协同创新中心，天津 300072
  3.天津大学化工学院系统生物工程教育部重点实验室，天津 300072
  4.天津大学环境科学与工程学院，天津 300072
- 作者简介：
  
  安珂（1996—），男，硕士研究生，sonoflordkirk@tju.edu.cn
  姜忠义（1966—），男，博士，教授，zhyjiang@tju.edu.cn
- 基金信息：
  
  国家自然科学基金创新研究群体项目(21621004;91534126);天津市自然科学基金面上项目(18JCYBJC21000)
- DOI：10.11949/0438-1157.20190601
  中图分类号： O 643
- 收稿：2019-05-31，
  
  修回：2019-08-11，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-10-05
- 稿件说明：
移动端阅览
安珂, 杨冬, 赵展烽, 任汉杰, 陈瑶, 周致远, 姜忠义. 金属有机框架光催化剂微环境调控研究进展[J]. 化工学报, 2019, 70(10): 3776-3790

AN Ke, YANG Dong, ZHAO Zhanfeng, REN Hanjie, CHEN Yao, ZHOU Zhiyuan, JIANG Zhongyi. Research progress on microenvironment regulation of metal-organic framework photocatalyst[J]. CIESC Journal, 2019, 70(10): 3776-3790
安珂, 杨冬, 赵展烽, 任汉杰, 陈瑶, 周致远, 姜忠义. 金属有机框架光催化剂微环境调控研究进展[J]. 化工学报, 2019, 70(10): 3776-3790 DOI： 10.11949/0438-1157.20190601.

AN Ke, YANG Dong, ZHAO Zhanfeng, REN Hanjie, CHEN Yao, ZHOU Zhiyuan, JIANG Zhongyi. Research progress on microenvironment regulation of metal-organic framework photocatalyst[J]. CIESC Journal, 2019, 70(10): 3776-3790 DOI： 10.11949/0438-1157.20190601.

摘要

金属有机框架材料（MOFs）是一类无机金属中心和有机配体自组装形成的晶体多孔材料，既有无机材料高结晶度、高电子迁移率等特点，又兼具有机材料高比表面积、高孔隙率、强可修饰性等特点，在光催化领域显示出广阔的应用前景。围绕物理化学微环境调控，对近年来MOFs光催化材料的研究进行了详细综述。其中，物理微环境的调控重点介绍了微观形貌调控、贵金属沉积和异质结构建三个方面；化学微环境调控重点介绍了金属位点调控与有机配体调控两个方面。此外，对MOFs光催化材料的未来发展进行展望，以期为高性能MOFs光催化剂的理性设计和可控制备等方面的研究提供思路。

Abstract

Metal organic framework materials (MOFs) are a class of inorganic metal centers and organic ligands formed by self-assembly of crystalline porous materials. MOFs combine high crystallinity and electron mobility of inorganic materials with high specific surface area

porosity and modifiability of organic materials

thus exhibiting broad application prospects in the field of photocatalysis. The research on MOFs photocatalytic materials in recent years is reviewed centering on the regulation of physical and chemical microenvironment. The regulation of physical microenvironment has been focused on micromorphology regulation

noble metal deposition and heterostructure construction

meanwhile the regulation of chemical microenvironment has been focused on metal site regulation and organic ligand regulation. In addition

in order to provide ideas for rational design and controllable preparation of high-performance MOF photocatalysts

the future development of MOF photocatalytic materials is also prospected.

关键词

Keywords

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