含非对称Gemini离子液体二元混合体系的体积和黏度性质

Xuzhao YANG; Jun WANG; Yun FANG

doi:10.11949/0438-1157.20190470

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含非对称Gemini离子液体二元混合体系的体积和黏度性质

热力学 | 更新时间：2020-06-24

- 含非对称Gemini离子液体二元混合体系的体积和黏度性质
- Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid
- 化工学报 2019年70卷第11期页码：4131-4142
- 作者机构：
  
  1.Key Laboratory of Synthetic and Biological Colloids，Ministry of Education, School of Chemical and Material Engineering，Jiangnan University，Wuxi 214122, Jiangsu, China
  2.Zhengzhou Key Laboratory of Fine Chemicals, School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, Henan, China
  江南大学化学与材料工程学院，合成与生物胶体教育部重点实验室，江苏无锡 214122
- 作者简介：
  
  方云（1957—），男，博士，教授，yunfang@126.com
- 基金信息：
  
  河南省科技攻关项目(162102210056);“十二五”国家科技支撑计划项目(2013BAC01B04);郑州市科技项目(141PQYJS555)
- DOI：10.11949/0438-1157.20190470
  中图分类号： TQ 013.1
- 收稿：2019-05-06，
  
  修回：2019-08-15，
  
  纸质出版：2019-11-05
- 稿件说明：
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杨许召, 王军, 方云. 含非对称Gemini离子液体二元混合体系的体积和黏度性质[J]. 化工学报, 2019, 70(11): 4131-4142

YANG Xuzhao, WANG Jun, FANG Yun. Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid[J]. CIESC Journal, 2019, 70(11): 4131-4142
杨许召, 王军, 方云. 含非对称Gemini离子液体二元混合体系的体积和黏度性质[J]. 化工学报, 2019, 70(11): 4131-4142 DOI： 10.11949/0438-1157.20190470.

YANG Xuzhao, WANG Jun, FANG Yun. Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid[J]. CIESC Journal, 2019, 70(11): 4131-4142 DOI： 10.11949/0438-1157.20190470.

摘要

在温度分别为293.15、303.15、313.15、323.15和333.15 K及大气压下，系统测定了非对称Gemini离子液体，1-(3-(三甲基铵)丙-1-基)-3-甲基咪唑

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810649&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810656&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810653&type=

3.17499995

3.09033346

双氰胺盐([N

111

MIM][N(CN)

]

)，分别与乙腈(MeCN)、甲醇(MeOH)、乙醇(EtOH)所组成的二元混合物的密度和黏度。由密度和黏度值分别计算了二元混合物的超额摩尔体积(

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810294&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810292&type=

3.47133350

)和超额黏度(Δ

)。

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810301&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810298&type=

3.47133350

和Δ

随组成的变化关系由Redlich-Kister方程进行了回归，得到方程参数。结果表明，

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810307&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810304&type=

3.47133350

和Δ

值与理想溶液间为负偏差，且存在最小值，说明二元体系中[N

111

MIM][N(CN)

]

和溶剂分子间相互作用力更强，同时与所研究分子的大小和形状的差异有关。同时，

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810321&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810311&type=

3.47133350

和Δ

随温度的变化关系表明，温度对研究混合物中的分子间相互作用有很大影响。

Abstract

Densities and dynamic viscosities of binary solutions containing asymmetrical Gemini ionic liquid (GIL)

1-(3-(trimethylammonio)prop-1-yl)-3-methylimidazolium bis(dicyanamide) ([N

111

MIM][N(CN)

]

) with acetonitrile (MeCN)

methanol (MeOH) or ethanol (EtOH) over the entire mole fraction range have been measured from 293.15 K to 333.15 K under atmospheric pressure. Excess molar volumes (

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810327&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810323&type=

3.89466667

4.06400013

) and excess viscosities (Δ

) of the solutions were calculated based on the experimental density and

viscosity

values of pure [N

111

MIM][N(CN)

]

molecular solvents

and their binary mixtures. The values of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810336&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810332&type=

3.89466667

4.06400013

and Δ

were fitted by using the Redlich–Kister equations and the optimal ﬁtting parameters were obtained. The results indicate that

the values of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810345&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810340&type=

3.89466667

4.06400013

and Δ

reveal negative deviations from ideal solutions. There exists a minimum excess values. Negative values of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810352&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810349&type=

3.89466667

4.06400013

and Δ

for all the binary mixtures indicate

compared to pure [N

111

MIM][N(CN)

]

and molecular solvents

stronger interactions between [N

111

MIM][N(CN)

]

and MeCN

MeOH or EtOH. These negative values are also related to the difference in size and shape of the molecules studied. Moreover

the variation of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810359&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810355&type=

3.89466667

4.06400013

and Δ

on temperature suggests that temperature has an enormous inﬂuence on the intermolecular interactions between [N

111

MIM][N(CN)

]

and molecular solvents.

关键词

Keywords

references

Welton T . Room-temperature ionic liquids. Solvents for synthesis and catalysis [J]. Chemical Reviews , 1999 , 8 : 2071 - 2084 .

胡甜甜 , 赵地顺 , 武宇 , 等 . 醚基功能化离子液体催化合成乙酸正丁酯 [J]. 化工学报 , 2017 , 68 ( 1 ): 136 - 145 .

Hu T T , Zhao D S , Wu Y , et al . Synthesis of n -butyl acetate by ether-functionalized ionic liquid [J]. CIESC Journal , 2017 , 68 ( 1 ): 136 - 145 .

Abo-Hamad A , Hayyan M , AlSaadi M A , et al . Potential applications of deep eutectic solvents in nanotechnology [J]. Chemical Engineering Journal , 2015 , 273 : 551 - 567 .

Rogers R D , Seddon K R . Ionic liquids: solvents of the future? [J]. Science , 2003 , 302 : 792 - 793 .

Zhang S , Chen Y , Li F , et al . Fixation and conversion of CO 2 using ionic liquids [J]. Catalysis Today , 2006 , 115 : 61 - 69 .

Zhao Y , Yu B , Yang Z , et al . A protic ionic liquid catalyzes CO 2 conversion at atmospheric pressure and room temperature: synthesis of quinazoline-2, 4(1 H , 3 H )-diones [J]. Angewandte Chemie International Edition , 2014 , 53 : 5922 - 5925 .

Antonietti M , Kuang D , Smarsly B , et al . Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures [J]. Angewandte Chemie International Edition , 2004 , 43 : 4988 - 4992 .

Bösmann A , Datsevich L , Jess A , et al . Deep desulfurization of diesel fuel by extraction with ionic liquids [J]. Chemical Communications , 2001 , ( 23 ): 2494 - 2495 .

Lima S , Neves P , Antunes M M , et al . Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids [J]. Applied Catalysis A: General , 2009 , 363 ( 1/2 ): 93 - 99 .

Brandt A , Gräsvik J , Hallett J P , et al . Deconstruction of lignocellulosic biomass with ionic liquids [J]. Green Chemistry , 2013 , 15 ( 3 ): 550 - 583 .

Anderson J L , Ding R , Ellernand A , et al . Structure and properties of high stability geminal dicationic ionic liquids [J]. Journal of the American Chemical Society , 2005 , 127 ( 2 ): 593 - 604 .

Qi M , Armstrong D W . Dicationic ionic liquid stationary phase for GC-MS analysis of volatile compounds in herbal plants [J]. Analytical and Bioanalytical Chemistry , 2007 , 388 ( 4 ): 889 - 899 .

Huang K , Han X , Zhang X , et al . PEG-linked geminal dicationic ionic liquids as selective, high-stability gas chromatographic stationary phases [J]. Analytical and Bioanalytical Chemistry , 2007 , 389 ( 7/8 ): 2265 - 2275 .

Bhawal S S , Patil R A , Armstrong D W . Rapid, effective deprotection of tert -butoxycarbonyl (Boc) amino acids and peptides at high temperatures using a thermally stable ionic liquid [J]. RSC Advances , 2015 , 5 ( 116 ): 95854 - 95856 .

Jin C M , Ye C , Phillips B S , et al . Polyethylene glycol functionalized dicationic ionic liquids with alkyl or polyfluoroalkyl substituents as high temperature lubricants [J]. Journal of Materials Chemistry , 2006 , 16 ( 16 ): 1529 - 1535 .

Yang X , Wang J , Zou W , et al . Synthesis and thermodynamic properties of a novel pyridinium-based asymmetrical gemini ionic liquid [J]. Korean Journal of Chemical Engineering , 2015 , 32 ( 12 ): 2369 - 2374 .

Wang X , Zhang P , Cui P , et al . Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids [J]. Chinese Journal of Chemical Engineering , 2017 , 25 ( 9 ): 1182 - 1186 .

Lu X , Zhu J , Qian X , et al . Separation of methyl linolenate and its analogues by functional mixture of imidazolium based ionic liquid-organic solvent-cuprous salt [J]. Chinese Journal of Chemical Engineering , 2019 , 27 ( 4 ): 811 - 817 .

Li C , Zhang Z , Zhao Z . Direct conversion of glucose and cellulose to 5-hydroxymethylfurfural in ionic liquid under microwave irradiation [J]. Tetrahedron Letters , 2009 , 50 ( 38 ): 5403 - 5405 .

Hou Q , Zhen M , Liu L , et al . Tin phosphate as a heterogeneous catalyst for efficient dehydration of glucose into 5-hydroxymethylfurfural in ionic liquid [J]. Applied Catalysis B: Environmental , 2018 , 224 : 183 - 193 .

Qi X , Watanabe M , Aida T M , et al . Efficient catalytic conversion of fructose into 5-hydroxymethylfurfural in ionic liquids at room temperature [J]. ChemSusChem , 2009 , 2 ( 10 ): 944 - 946 .

Carneiro A P , Rodríguez O , Macedo E A . Fructose and glucose dissolution in ionic liquids: solubility and thermodynamic modeling [J]. Industrial & Engineering Chemistry Research , 2013 , 52 ( 9 ): 3424 - 3435 .

Yang X , Wang J , Fang Y . Properties of pure 1-(3-(trimethylammonio)prop-1-yl)-3-methylimidazolium bis(dicyanamide) asymmetrical gemini ionic liquid and its binary mixture with isopropanol at T = (283.15—333.15) K [J]. The Journal of Chemical Thermodynamics , 2019 , 134 : 84 - 95 .

Chen F , Yang Z , Chen Z , et al . Density, viscosity, speed of sound, excess property and bulk modulus of binary mixtures of γ-butyrolactone with acetonitrile, dimethyl carbonate, and tetrahydrofuran at temperatures (293.15 to 333.15) K [J]. Journal of Molecular Liquids , 2015 , 209 : 683 - 692 .

Gołdon A , Dabrowska K , Hofman T . Densities and excess volumes of the 1, 3-dimethylimidazolium methylsulfate + methanol system at temperatures from (313.15 to 333.15) K and pressures from (0.1 to 25) MPa [J]. Journal of Chemical & Engineering Data , 2007 , 52 ( 5 ): 1830 - 1837 .

Yang C , Sun Y , He Y , et al . Volumetric properties and viscosities of binary mixtures of N , N -dimethylformamide with methanol and ethanol in the temperature range (293.15 to 333.15) K [J]. Journal of Chemical & Engineering Data , 2008 , 53 ( 1 ): 293 - 297 .

Yang C , Lai H , Liu Z , et al . Densities and viscosities of diethyl carbonate + toluene, + methanol, and + 2-propanol from (293.15 to 363.15) K [J]. Journal of Chemical & Engineering Data , 2006 , 51 ( 2 ): 584 - 589 .

Djojoputro H , Ismadji S . Density and viscosity of binary mixtures of ethyl-2-methylbutyrate and ethyl hexanoate with methanol, ethanol, and 1-propanol at (293.15, 303.15, and 313.15) K [J]. Journal of Chemical & Engineering Data , 2005 , 50 ( 4 ): 1343 - 1347 .

Kurnia K A , Mutalib M I A . Densities and viscosities of binary mixture of the ionic liquid bis(2-hydroxyethyl)ammonium propionate with methanol, ethanol, and 1-propanol at T = (293.15, 303.15, 313.15, and 323.15) K and at P = 0.1 MPa [J]. Journal of Chemical & Engineering Data , 2011 , 56 ( 1 ): 79 - 83 .

Ciocirlan O , Croitoru O , Iulian O . Densities and viscosities for binary mixtures of 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid with molecular solvents [J]. Journal of Chemical & Engineering Data , 2011 , 56 ( 4 ): 1526 - 1534 .

Lu X , Xie H , Lei Q , et al . Densities and viscosities of binary mixtures of 2, 2-diethyl-1, 1, 3, 3-tetramethylguanidinium bis (trifluoromethylsulfonyl) imide with methanol and ethanol [J]. The Journal of Chemical Thermodynamics , 2019 , 136 : 44 - 53 .

Zec N , Bešter-Rogač M , Vraneš M , et al . Physicochemical properties of (1-butyl-1-methylpyrrolydinium dicyanamide+ γ-butyrolactone) binary mixtures [J]. The Journal of Chemical Thermodynamics , 2015 , 91 : 327 - 335 .

Anouti M , Jacquemin J , Lemordant D . Volumetric properties, viscosities, and isobaric heat capacities of imidazolium octanoate protic ionic liquid in molecular solvents [J]. Journal of Chemical & Engineering Data , 2010 , 55 ( 12 ): 5719 - 5728 .

Li X , Zhou Q , Lu X , et al . Densities and viscosities of binary mixtures of magnetic ionic liquids 1-alkyl-3-methylimidazolium tetrachloroferrate with ethyl acetate at temperatures (293.15 to 323.15) K [J]. Journal of Molecular Liquids , 2017 , 243 : 285 - 292 .

Ye F , Zhu J , Yu K , et al . Physicochemical properties of binary mixtures of 1, 1, 3, 3- tetramethylguanidine imidazolide ionic liquid with water and alcohols [J]. The Journal of Chemical Thermodynamics , 2016 , 97 : 39 - 47 .

Moosavi M , Motahari A , Omrani A , et al . Investigation on some thermophysical properties of poly (ethylene glycol) binary mixtures at different temperatures [J]. The Journal of Chemical Thermodynamics , 2013 , 58 : 340 - 350 .

Anwar N , Riyazuddeen . Excess molar volumes, excess molar isentropic compressibilities, viscosity deviations, and activation parameters for 1-ethyl-3-methyl-imidazolium trifluoro-methanesulfonate + dimethyl sulfoxide and/or acetonitrile at T = 298.15 to 323.15 K and P = 0.1 MPa [J]. Journal of Chemical & Engineering Data , 2018 , 63 ( 2 ): 269 - 289 .

Chen J , Chen L , Xu Y . Properties of pure 1, 1, 3, 3-tetramethylguanidine imidazole ionic liquid and its binary mixtures with alcohols at T =(293.15 to 313.15)K [J]. The Journal of Chemical Thermodynamics , 2015 , 88 : 110 - 120 .

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