Mo/ZSM-5催化作用下生物质快速热解制生物油实验研究

孙来芝; 陈雷; 赵保峰; 杨双霞; 谢新苹; 孟凡军; 司洪宇

doi:10.11949/0438-1157.20190305

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Mo/ZSM-5催化作用下生物质快速热解制生物油实验研究

更新时间：2026-07-24

- Mo/ZSM-5催化作用下生物质快速热解制生物油实验研究
- Experiment research on catalytic fast pyrolysis of biomass into bio-oils over Mo/ZSM-5 catalyst
- 化工学报 2019年70卷第8期页码：3160-3166
- 作者机构：
  
  山东省生物质气化技术重点实验室，齐鲁工业大学（山东省科学院）能源研究所，山东济南250014
- 作者简介：
  
  孙来芝（1984—），男，博士，助理研究员，sunlz@sderi.cn
- 基金信息：
  
  国家重点研发计划项目(2018YFB1501403);山东省自然科学基金项目(ZR2019MB061;ZR2019MEE069;ZR2016YL010;ZR2016YL012;ZR2016YL007);山东省重点研发计划项目(2018GGX104026;2017GSF17103;2018GGX104028);齐鲁工业大学（山东省科学院）青年博士合作基金项目(2018BSHZ0025);山东省科学院青年科学基金项目(2019QN0020)
- DOI：10.11949/0438-1157.20190305
  中图分类号： TK 6
- 收稿：2019-04-01，
  
  修回：2019-05-27，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-08-05
- 稿件说明：
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孙来芝, 陈雷, 赵保峰, 杨双霞, 谢新苹, 孟凡军, 司洪宇. Mo/ZSM-5催化作用下生物质快速热解制生物油实验研究[J]. 化工学报, 2019, 70(8): 3160-3166

SUN Laizhi, CHEN Lei, ZHAO Baofeng, YANG Shuangxia, XIE Xinping, MENG Fanjun, SI Hongyu. Experiment research on catalytic fast pyrolysis of biomass into bio-oils over Mo/ZSM-5 catalyst[J]. CIESC Journal, 2019, 70(8): 3160-3166
孙来芝, 陈雷, 赵保峰, 杨双霞, 谢新苹, 孟凡军, 司洪宇. Mo/ZSM-5催化作用下生物质快速热解制生物油实验研究[J]. 化工学报, 2019, 70(8): 3160-3166 DOI： 10.11949/0438-1157.20190305.

SUN Laizhi, CHEN Lei, ZHAO Baofeng, YANG Shuangxia, XIE Xinping, MENG Fanjun, SI Hongyu. Experiment research on catalytic fast pyrolysis of biomass into bio-oils over Mo/ZSM-5 catalyst[J]. CIESC Journal, 2019, 70(8): 3160-3166 DOI： 10.11949/0438-1157.20190305.

摘要

采用等体积浸渍法制备Mo/ZSM-5催化剂，并应用于生物质快速热解制备生物油。采用Py-GC/MS装置，重点研究了Mo负载量、反应温度、反应时间和催化剂与木粉质量比等参数对生物油产率和组成的影响规律。实验结果表明，与纯木粉热解相比较，ZSM-5和Mo/ZSM-5催化作用下生物油的产率大幅提高；在反应温度为600℃、反应时间为25 s、催化剂与木粉质量比为10/1的条件下，10Mo/ZSM-5催化作用下生物油中芳香烃类化合物的产率和相对含量达到最大值。根据生物油产率和组成的变化，可以得出Mo负载的ZSM-5催化剂强化促进酸类、醛酮类等含氧化合物转化为芳香烃类化合物，有效实现了生物质热解生物油品质的提升。

Abstract

The Mo/ZSM-5 catalyst was prepared by an equal volume impregnation method and applied to the rapid pyrolysis of biomass to prepare bio-oil. The effects of Mo loadings

reaction temperature

reaction time and

catalyst/biomass mass ratio on the yields and composition of bio-oils were researched. Compared to the pyrolysis of sawdust

the yields of bio-oils were greatly increased by ZSM-5 and Mo/ZSM-5 catalysts. Under the reaction condition of

=600℃

=25 s

catalyst/biomass mass ratio=10/1

the yields and amounts of aromatic hydrocarbons in bio-oil reached the maximum by 10Mo/ZSM-5 catalysts. According to the variations of products in bio-oils

Mo/ZSM-5 catalysts promoted the conversion of oxygenated compounds

such as acids

aldehydes and ketones

into aromatic hydrocarbons

which could effectively upgrade the bio-oils.

关键词

Keywords

references

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