Cu-Ce-Zr基催化剂上甲苯自持燃烧贫燃极限研究

赵晨晨; 郝庆兰; 闫宁娜; 杨德宇; 黄亚飞; 豆宝娟

doi:10.11949/0438-1157.20190136

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Cu-Ce-Zr基催化剂上甲苯自持燃烧贫燃极限研究

更新时间：2026-07-24

- Cu-Ce-Zr基催化剂上甲苯自持燃烧贫燃极限研究
- Study on lean-combustion limit of toluene self-sustained combustion on Cu-Ce-Zr based catalysts
- 化工学报 2019年70卷第8期页码：3050-3057
- 作者机构：
  
  天津科技大学化工与材料学院，天津 300457
- 作者简介：
  
  赵晨晨（1994—），女，硕士研究生，847558718@qq.com
  豆宝娟（1982—），女，博士，副教授，bjdou@tust.edu.cn
- 基金信息：
  
  中国博士后科学基金面上项目(2017M623284)
- DOI：10.11949/0438-1157.20190136
  中图分类号： TQ 032.41
- 收稿：2019-02-20，
  
  修回：2019-05-16，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-08-05
- 稿件说明：
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赵晨晨, 郝庆兰, 闫宁娜, 杨德宇, 黄亚飞, 豆宝娟. Cu-Ce-Zr基催化剂上甲苯自持燃烧贫燃极限研究[J]. 化工学报, 2019, 70(8): 3050-3057

ZHAO Chenchen, HAO Qinglan, YAN Ningna, YANG Deyu, HUANG Yafei, DOU Baojuan. Study on lean-combustion limit of toluene self-sustained combustion on Cu-Ce-Zr based catalysts[J]. CIESC Journal, 2019, 70(8): 3050-3057
赵晨晨, 郝庆兰, 闫宁娜, 杨德宇, 黄亚飞, 豆宝娟. Cu-Ce-Zr基催化剂上甲苯自持燃烧贫燃极限研究[J]. 化工学报, 2019, 70(8): 3050-3057 DOI： 10.11949/0438-1157.20190136.

ZHAO Chenchen, HAO Qinglan, YAN Ningna, YANG Deyu, HUANG Yafei, DOU Baojuan. Study on lean-combustion limit of toluene self-sustained combustion on Cu-Ce-Zr based catalysts[J]. CIESC Journal, 2019, 70(8): 3050-3057 DOI： 10.11949/0438-1157.20190136.

摘要

在内径4 mm的微型反应器内对两种活性不同的Cu-Ce-Zr基催化剂进行甲苯自持燃烧的贫燃极限研究和热量计算。研究结果表明，活性高的CuCe

0.75

0.25

-BC催化剂的贫燃极限小于活性低的CuCe

0.75

0.25

/TiO

催化剂的贫燃极限，当流量为200 ml/min时，其当量比

值最小，为0.024。混合气在催化剂表面的停留时间随混合气流量的增大而缩短，使得催化自持燃烧的壁温高温区向催化剂床层后端移动，且壁温高温区温度随催化剂活性的增高而降低。在散热率高达91.9%的情况下，甲苯仍可维持稳定的自持燃烧状态。同时结合微管反应实验结果和理论计算，在有效降低飞温上限对反应器和催化剂的影响下实现了甲苯在固定床反应器中的自持燃烧。

Abstract

The self-sustained combustion of toluene on the Cu-Ce-Zr based catalysts with different activity has been carried out in a micro-tube with inner diameter of 4 mm. It was shown that the lean-combustion limits over CuCe

0.75

0.25

-BC catalyst with the higher activity were less than that on CuCe

0.75

0.25

/TiO

catalyst at the same flow rate

and the minimum of equivalence

ratio (

) was 0.024 under the flow rate of 200 ml/min. The residence time of the mixed gas on the catalyst surface declined with the increasing of flow rate

making the highest surface wall-temperature range shift to the back of catalyst bed. Toluene could maintain self-sustained combustion even when the heat loss was as high as 91.9%. Combined with the theoretical model

the heat transport of toluene self-sustained combustion in micro-tube was calculated. The self-sustained combustion in a fixed-bed reactor was realized with reducing the upper limit of temperature runaway s impacts for the reactor and catalysts.

关键词

Keywords

references

Bijjula K , Vlachos D G . Catalytic ignition and autothermal combustion of JP-8 and its surrogates over a Pt/γ-A l 2 O 3 catalyst [J ] . Proceedings of the Combustion Institute , 2011 , 33 ( 2 ): 1801 - 1807 .

Bin F , Wei X L , Li T , et al . Self-sustained catalytic combustion of carbon monoxide ignited by dielectric barrier discharge [J ] . Proceedings of the Combustion Institute , 2017 , 36 ( 3 ): 4193 - 4200 .

Chen J J , Yan L F , Song W Y , et al . Effect of heat and mass transfer on the combustion stability in catalytic micro-combustor [J ] . Applied Thermal Engineering , 2018 , 131 : 750 - 765 .

李军伟 , 钟北京 . 甲烷/氧气在微细直管内的燃烧和散热研究 [J ] . 燃料科学与技术 , 2008 , 14 ( 3 ): 199 - 204 .

Li J W , Zhong B J . Investigation on methane/oxygen combustion and heat loss in micro-tube [J ] . Journal of Combustion Science and Technology , 2008 , 14 ( 3 ): 199 - 204 .

Wang Y F , Yang W J , Zhou J H , et al . Heterogeneous reaction characteristics and their effects on homogeneous combustion of methane/air mixture in micro channels(Ⅰ): Thermal analysis [J ] . Fuel , 2018 , 234 : 20 - 29 .

Wang Y F , Yang W J , Zhou J H , et al . Heterogeneous reaction characteristics and its effects on homogeneous combustion of methane/air mixture in microchannels(Ⅱ): Chemical analysis [J ] . Fuel , 2019 , 235 : 923 - 932 .

Yan Y F , Wu G G , Huang W P , et al . Numerical comparison study of methane catalytic combustion characteristic between newly proposed opposed counter-flow micro-combustor and the conventional ones [J ] . Energy , 2019 , 170 : 403 - 410 .

中华人民共和国生态环境部 . 关于征求《制药工业大气污染物排放标准(征求意见稿)》国家环境保护标准意见的函 [EB/OL ] . [ 2019-06-04 ] . http://www.mee.gov.cn/gkml/hbb/bgth/201705/t20170531_415077.htm http://www.mee.gov.cn/gkml/hbb/bgth/201705/t20170531_415077.htm .

Ministry of Ecology and Environment of the People s Republic of China . Letter on soliciting opinions on national environmental protection standards for “Emission standard of air pollutions for pharmaceutical industry (draft)” [EB/OL ] . [ 2019-06-04 ] . http://www.mee.gov.cn/gkml/hbb/bgth/201705/t20170531_415077.htm http://www.mee.gov.cn/gkml/hbb/bgth/201705/t20170531_415077.htm .

中华人民共和国生态环境部，关于印发《“十三五”挥发性有机物污染防治工作方案》的通知 [EB/OL ] . [ 2019-06-04 ] . http://www.mee.gov.cn/gkml/hbb/bwj/201709/t20170919_421835.htm http://www.mee.gov.cn/gkml/hbb/bwj/201709/t20170919_421835.htm .

Ministry of Ecology and Environment of the People s Republic of China . Notice on the issuance of “13th five-year plan for the prevention and control of volatile organic compounds” [EB/OL ] . [ 2019-06-04 ] . http://www.mee.gov.cn/gkml/hbb/bwj/201709/t20170919_421835.htm http://www.mee.gov.cn/gkml/hbb/bwj/201709/t20170919_421835.htm .

Yang W J , Wang Y F , Zhou J H , et al . Catalytic self-sustaining combustion of the alkanes with Pt/ZSM-5 packed bed in a microscale tube [J ] . Chemical Engineering Science , 2017 , 158 : 30 - 36 .

Scarpa A , Pirone R , Russo G , et al . Effect of heat recirculation on the self-sustained catalytic combustion of propane/air mixtures in a quartz reactor [J ] . Combustion and Flame , 2009 , 156 : 947 - 953 .

Specchia S , Tacchino S , Specchia V . Facing the catalytic combustion of CH 4 /H 2 mixtures into monoliths [J ] . Chemical Engineering Journal , 2011 , 167 ( 2 ): 622 - 633 .

Yan Y F , Pan W L , Zhang L , et al . Numerical study of the geometrical parameters on CH 4 /air premixed combustion in heat recirculation micro-combustor [J ] . Fuel , 2015 , 159 : 45 - 51 .

Spadaccini C M , Zhang X , Cadou C P , et al . Preliminary development of a hydrocarbon-fueled catalytic micro-combustor [J ] . Sensors and Actuators A: Physical , 2003 , 103 ( 1 / 2 ): 219 - 224 .

Zhang Y C , Pan J F , Tang A K , et al . Effects of inlet parameters on combustion characteristics of premixed CH 4 /air in micro channels [J ] . Journal of the Energy Institute , 2019 , 92 ( 3 ): 824 - 834 .

Bin F , Wei X L , Li B , et al . Self-sustained combustion of carbon monoxide promoted by the Cu-Ce/ZSM-5 catalyst in CO/O 2 /N 2 atmosphere [J ] . Applied Catalysis B: Environmental , 2015 , 162 : 282 - 288 .

Zhao C C , Hao Q L , Zhang Q , et al . Catalytic self-sustained combustion of toluene and reaction pathway over Cu x Mn 1- x Ce 0.75 Zr 0.25 /TiO 2 catalysts [J ] . Applied Catalysis A: General , 2019 , 56 : 66 - 74 .

Bin F , Kang R N , Wei X L , et al . Self-sustained combustion of carbon monoxide over CuCe 0.75 Zr 0.25 O δ catalyst: stability operation and reaction mechanism [J ] . Proceedings of the Combustion Institute , 2019 , 37 ( 4 ): 5507 - 5515 .

杨青 , 郝庆兰 , 闫宁娜 , 等 . 溶胶凝胶法由细菌纤维素制备CuCe 0.75 Zr 0.25 O x 复合氧化物及其低温催化降解甲苯性能 [J ] . 燃料化学学报 , 2017 , 45 ( 11 ): 1401 - 1408 .

Yang Q , Hao Q L , Yan N N , et al . Preparation of CuCe 0.75 Zr 0.25 O x composite by bacterial cellulose promoted sol-gel method and its catalytic performance in the toluene degradation at low temperature [J ] . Journal of Fuel Chemistry and Technology , 2017 , 45 ( 11 ): 1401 - 1408 .

Dou B J , Li S M , Liu D L , et al . Catalytic oxidation of ethyl acetate and toluene over Cu-Ce-Zr supported ZSM-5/TiO 2 catalysts [J ] . RSC Advances , 2016 , 6 ( 59 ): 53852 - 53859 .

王业峰 , 周俊虎 , 赵庆辰 , 等 . 甲烷与正丁烷微小尺寸催化燃烧性能比较 [J ] . 化工学报 , 2017 , 68 ( 3 ): 896 - 902 .

Wang Y F , Zhou J H , Zhao Q C , et al . Comparison of catalytic combustion of methane and n -butane in microtude [J ] . CIESC Journal , 2017 , 68 ( 3 ): 896 - 902 .

Muhammad S K , Shaikh A R , Mohammad M H . Catalytic oxidation of volatile organic compounds (VOCs) — a review [J ] . Atmospheric Environment , 2016 , 140 : 117 - 137 .

Xin Y X , Wang H , Law C K . Kinetics of catalytic oxidation of methane, ethane and propane over palladium oxide [J ] . Combustion and Flame , 2014 , 161 ( 4 ): 1048 - 1054 .

张薇薇 . 甲苯在SBA-15上的吸附与催化性能的研究 [D ] . 大连 : 大连理工大学 , 2011 .

Zhang W W . Study on adsorption/catalytic properties of toluene over SBA-15 [D ] . Dalian : Dalian University of Technology , 2011 .

Terracciano A C , Oliveira S D , Molina D V , et al . Effect of catalytically active Ce 0.8 Gd 0.2 O 1.9 coating on the heterogeneous combustion of methane within MgO stabilized ZrO 2 porous ceramics [J ] . Combustion and Flame , 2017 , 180 : 32 - 39 .

Li J W , Zhong B J . Experimental investigation on heat loss and combustion in methane/oxygen micro-tube combustor [J ] . Applied Thermal Engineering , 2008 , 28 : 707 - 716 .

谭天恩 . 化工原理（上册） [M ] . 4 版. 北京 : 化学工业出版社 , 2013 : 170 - 191 .

Tan T E . Unit Operations of Chemical Engineering (Book one) [M ] . 4th ed. Beijing : Chemical Industry Press , 2013 : 170 - 191 .

徐侃 . 微小尺寸燃烧中淬熄距离和贫燃极限的研究 [D ] . 合肥 : 中国科学技术大学 , 2011 .

Xu K . Study of quenching distance and lean-burn extinction limit in mini-scale combustion [D ] . Hefei : University of Science and Technology of China , 2011 .

陈俊杰 , 王谦 . 微尺度催化燃烧的研究进展 [J ] . 应用化工 , 2008 , 37 ( 11 ): 1376 - 1380 .

Chen J J , Wang Q . Research progress of micro-scale catalytic combustion [J ] . Applied Chemical Industry , 2008 , 37 ( 11 ): 1376 - 1380 .

王宇豪 . 基于CuCe 1- x Zr x O y 系列催化剂的一氧化碳自持燃烧的研究 [D ] . 西安 : 西安交通大学 , 2016 .

Wang Y H . Investigation of carbon monoxide self-sustained combustion based on CuCe 1- x Zr x O y series catalysts [D ] . Xi an : Xi an Jiaotong University , 2016 .

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