超盐环境下含氮碳气凝胶的制备及其在超级电容器中的应用

张璇; 杨佳兴; 金秋阳; 佟明兴; 周俊熹; 高静; 李国华

doi:10.11949/0438-1157.20190106

您当前的位置：

首页 >

文章列表页 >

超盐环境下含氮碳气凝胶的制备及其在超级电容器中的应用

材料化学工程与纳米技术 | 更新时间：2026-07-24

- 超盐环境下含氮碳气凝胶的制备及其在超级电容器中的应用
- Preparation of nitrogen-doped carbon aerogel under hypersaline condition and its application for supercapacitors
- 化工学报 2019年70卷第7期页码：2748-2757
- 作者机构：
  
  浙江工业大学化学工程学院，浙江杭州 310014
- 作者简介：
  
  张璇（1994—），女，硕士研究生，2111601105@zjut.edu.cn
  高静（1984—），女，博士，教授，jinggeo@zjut.edu.cn
  李国华（1966—），男，博士，教授，nanozjut@zjut.edu.cn
- 基金信息：
- DOI：10.11949/0438-1157.20190106
  中图分类号： TB 32
- 收稿：2019-01-30，
  
  修回：2019-04-19，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-07-05
- 稿件说明：
移动端阅览
张璇, 杨佳兴, 金秋阳, 佟明兴, 周俊熹, 高静, 李国华. 超盐环境下含氮碳气凝胶的制备及其在超级电容器中的应用[J]. 化工学报, 2019, 70(7): 2748-2757

ZHANG Xuan, YANG Jiaxing, JIN Qiuyang, TONG Mingxing, ZHOU Junxi, GAO Jing, LI Guohua. Preparation of nitrogen-doped carbon aerogel under hypersaline condition and its application for supercapacitors[J]. CIESC Journal, 2019, 70(7): 2748-2757
张璇, 杨佳兴, 金秋阳, 佟明兴, 周俊熹, 高静, 李国华. 超盐环境下含氮碳气凝胶的制备及其在超级电容器中的应用[J]. 化工学报, 2019, 70(7): 2748-2757 DOI： 10.11949/0438-1157.20190106.

ZHANG Xuan, YANG Jiaxing, JIN Qiuyang, TONG Mingxing, ZHOU Junxi, GAO Jing, LI Guohua. Preparation of nitrogen-doped carbon aerogel under hypersaline condition and its application for supercapacitors[J]. CIESC Journal, 2019, 70(7): 2748-2757 DOI： 10.11949/0438-1157.20190106.

摘要

多孔碳材料因其优异的导电性和稳定性，以及成本低廉等优点而成为当今的研究热点之一。以苯酚、甲醛和三聚氰胺为原料，利用高浓度氯化锌来提供超盐环境，经溶剂热反应后，在氮气中800℃下热解制得了含氮碳气凝胶(NCA)。扫描电子显微镜、拉曼光谱、X射线光电子能谱和氮气吸附等表征结果表明，该含氮碳气凝胶具有分级多孔蜂窝状结构，其比表面积高达729.6 m²/g。采用三电极测试体系测试了含氮碳气凝胶的电化学性能，结果表明，在三电极体系中，以0.5 mol/L H

作为电解液，含氮碳气凝胶在电流密度为1 A/g时比电容达到350.7 F/g；在电流密度为20 A/g时，经过10000次充放电后，含氮碳气凝胶的电容保持率仍高达97.8%。在双电极体系中，含氮碳气凝胶在800 W/kg的功率密度下，能量密度可达26.8 (W·h)/kg。上述结果表明，该含氮碳气凝胶是一种非常理想的超级电容器电极材料。

Abstract

Porous carbon materials have become one research hotspot due

to their excellent electrical conductivity

superior stability and low cost. Using phenol

formaldehyde and melamine as raw materials

a high concentration of zinc chloride was used to provide a super-salt environment. After solvothermal reaction

a nitrogen-containing carbon aerogel(NCA) was obtained by pyrolysis at 800℃ in nitrogen. Scanning electron microscope (SEM)

Raman and Brunauer-Emmett-Teller (BET) results demonstrate that the NCA sample has hierarchically honeycomb-like structure and its specific surface area reaches 729.6 m²/g. The as-prepared NCA

when tested in three-electrode system as supercapacitor electrode

exhibits a high specific capacitance of 350.7 F/g at 1 A/g and outstanding cycling stability with 97.8 % of the initial capacitance retained after 10000 cycles at 20 A/g in 0.5 mol/L H

. Moreover

symmetric supercapacitor based on the NCA electrodes could deliver an impressively high energy density of 26.8 (W·h)/kg at a power density of 800 W/kg. Therefore

NCA is one promising material that can be used in supercapacitors.

关键词

Keywords

references

Zhang L L , Zhao X S . Carbon-based materials as supercapacitor electrodes [J ] . Chemical Society Reviews , 2009 , 38 ( 9 ): 2520 - 2531 .

朱红艳 , 赵建国 , 庞明俊 , 等 . 石墨烯/δ-MnO 2 复合材料的制备及其超级电容器性能 [J ] . 化工学报 , 2017 , 68 ( 12 ): 4824 - 4832 .

Zhu H Y , Zhao J G , Pang M J , et al . Preparation of graphene/δ-MnO 2 composites and supercapacitor performance [J ] . CIESC Journal , 2017 , 68 ( 12 ): 4824 - 4832 .

周王帆 , 陈新 , 曹红亮 , 等 . 法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用 [J ] . 化工学报 , 2017 , 68 ( 7 ): 2918 - 2924 .

Zhou W F , Chen X , Cao H L , et al . Preparation of platanus leaf-based activated carbon and its application to supercapacitors [J ] . CIESC Journal , 2017 , 68 ( 7 ): 2918 - 2924 .

Salanne M , Rotenberg B , Naoi K , et al . Efficient storage mechanisms for building better supercapacitors [J ] . Nature Energy , 2016 , 1 ( 16 ): 16070 .

Wang J G , Liu H Z , Sun H H , et al . One-pot synthesis of nitrogen-doped ordered mesoporous carbon spheres for high-rate and long-cycle life supercapacitors [J ] . Carbon , 2018 , 127 : 85 - 92 .

Cheng P , Li T , Yu H , et al . Biomass-derived carbon fiber aerogel as a binder-free electrode for high-rate supercapacitors [J ] . Journal of Physical Chemistry C , 2016 , 120 ( 4 ): 2079 - 2086 .

Li Y Q , Samad Y A , Polychronopoulou K , et al . Carbon aerogel from winter melon for highly efficient and recyclable oils and organic solvents absorption [J ] . ACS Sustainable Chemistry Engineering , 2014 , 2 ( 6 ): 1492 - 1497 .

Gueon D , Moon J H . Nitrogen-doped carbon nanotube spherical particles for supercapacitor applications: emulsion-assisted compact packing and capacitance enhancement [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 36 ): 20083 - 20089 .

Du Y X , Liu L B , Xiang Y , et al . Enhanced electrochemical capacitance and oil-absorbability of N-doped graphene aerogel by using amino-functionalized silica as template and doping agent [J ] . Journal of Power Sources , 2018 , 379 : 240 - 248 .

Macías C , Rasines G , Lavela P , et al . Mn-containing N-doped monolithic carbon aerogels with enhanced macroporosity as electrodes for capacitive deionization [J ] . ACS Sustainable Chemistry Engineering , 2016 , 4 ( 5 ): 2487 - 2494 .

Lee E J , Lee Y J , Kim J K , et al . Preparation and characterization of nitrogen-enriched carbon aerogel as a supercapacitor electrode material [J ] . Journal of Nanoscience and Nanotechnology , 2016 , 16 ( 10 ): 10413 - 10419 .

Xie M J , Dong H H , Zhang D D , et al . Simple synthesis of highly ordered mesoporous carbon by self-assembly of phenol–formaldehyde and block copolymers under designed aqueous basic/acidic conditions [J ] . Carbon , 2011 , 49 ( 7 ): 2459 - 2464 .

Guo J , Wu D L , Wang T , et al . P-doped hierarchical porous carbon aerogels derived from phenolic resins for high performance supercapacitor [J ] . Applied Surface Science , 2019 , 475 : 56 - 66 .

Quan X P , Fu Z B , Yuan L , et al . Capacitive deionization of NaCl solutions with ambient pressure dried carbon aerogel microsphere electrodes [J ] . RSC Advances , 2017 , 7 ( 57 ): 35875 - 35882 .

Yu Z L , Li G C , Fechler N , et al . Polymerization under hypersaline conditions: a robust route to phenolic polymer-derived carbon aerogels [J ] . Angewandte Chemie International Edition , 2016 , 55 ( 47 ): 14623 - 14627 .

Fechler N , Wohlgemuth S A , Philipp J , et al . Salt and sugar: direct synthesis of high surface area carbon materials at low temperatures via hydrothermal carbonization of glucose under hypersaline conditions [J ] . Journal of Materials Chemistry A , 2013 , 1 : 9418 - 9421 .

Zeng Y , Wang K , Yao J F , et al . Hollow carbon beads fabricated by phase inversion method for efficient oil sorption [J ] . Carbon , 2014 , 69 : 25 - 31 .

Yu M , Li J , Wang L . KOH-activated carbon aerogels derived from sodium carboxymethyl cellulose for high-performance supercapacitors and dye adsorption [J ] . Chemical Engineering Journal , 2017 , 310 : 300 - 306 .

Lee W H , Moon J H . Monodispersed N-doped carbon nanospheres for supercapacitor application [J ] . ACS Applied Materials & Interfaces , 2014 , 6 ( 16 ): 13968 - 13976 .

Zhang J L , Chen L , Zhan G Q , et al . Self-assembly synthesis of N-doped carbon aerogels for supercapacitor and electrocatalytic oxygen reduction [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 23 ): 12760 - 12766 .

Wei X J , Wan S G , Gao S Y . Self-assembly-template engineering nitrogen-doped carbon aerogels for high-rate supercapacitors [J ] . Nano Energy , 2016 , 28 : 206 - 215 .

Shang H , Zuo Z C , Zheng H Y , et al . N-doped graphdiyne for high-performance electrochemical electrodes [J ] . Nano Energy , 2018 , 44 : 144 - 154 .

Han B , Lee E J , Choi W H , et al . Three-dimensionally ordered mesoporous carbons activated by hot ammonia treatment as high-performance anode materials in lithium-ion batteries [J ] . New Journal of Chemistry , 2015 , 39 ( 8 ): 6178 - 6185 .

Choi W H , Choi M J , Bang J H . Nitrogen-doped carbon nanocoil array integrated on carbon nanofiber paper for supercapacitor electrodes [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 34 ): 19370 - 19381 .

Gu W T , Sevilla M , Magasinski A , et al . Sulfur-containing activated carbons with greatly reduced content of bottle neck pores for double-layer capacitors: a case study for pseudocapacitance detection [J ] . Energy & Environmental Science , 2013 , 6 ( 8 ): 2465 - 2476 .

Meng Q S , Qin K Q , Ma L Y , et al . N-doped porous carbon nanofibers/porous silver network hybrid for high-rate supercapacitor electrode [J ] . ACS Applied Materials & Interfaces , 2017 , 9 ( 36 ): 30832 - 30839 .

Chizari K , Vena A , Laurentius L , et al . The effect of temperature on the morphology and chemical surface properties of nitrogen-doped carbon nanotubes [J ] . Carbon , 2014 , 68 : 369 - 379 .

Ma K Y , Cheng J P , Liu F , et al . Co-Fe layered double hydroxides nanosheets vertically grown on carbon fiber cloth for electrochemical capacitors [J ] . Journal of Alloys and Compounds , 2016 , 679 : 277 - 284 .

Zhou J , Zhang Z S , Xing W , et al . Nitrogen-doped hierarchical porous carbon materials prepared from meta-aminophenol formaldehyde resin for supercapacitor with high rate performance [J ] . Electrochimica Acta , 2015 , 153 : 68 - 75 .

Zhang Y , Wen G W , Gao P , et al . High-performance supercapacitor of macroscopic graphene hydrogels by partial reduction and nitrogen doping of graphene oxide [J ] . Electrochimica Acta , 2016 , 221 : 167 - 176 .

Chen H , Xiong Y C , Yu T , et al . Boron and nitrogen co-doped porous carbon with a high concentration of boron and its superior capacitive behavior [J ] . Carbon , 2017 , 113 : 266 - 273 .

Daems N , Sheng X , Vankelecom I F J , et al . Metal-free doped carbon materials as electrocatalysts for the oxygen reduction reaction [J ] . Journal of Materials Chemistry A , 2014 , 2 : 4085 - 4110 .

Yang J , Jo M R , Kang M , et al . Rapid and controllable synthesis of nitrogen doped reduced graphene oxide using microwave-assisted hydrothermal reaction for high power-density supercapacitors [J ] . Carbon , 2014 , 73 : 106 - 113 .

Dong Y H , Wang W X , Quan H Y , et al . Nitrogen-doped foam-like carbon plate consisting of carbon tubes as high-performance electrode materials for supercapacitors [J ] . ChemElectroChem , 2016 , 3 ( 5 ): 814 - 821 .

Du J , Liu L , Hu Z P , et al . Raw-cotton-derived N-doped carbon fiber aerogel as an efficient electrode for electrochemical capacitors [J ] . ACS Sustainable Chemistry Engineering , 2018 , 6 ( 3 ): 4008 - 4015 .

Sun G L , Ma L Y , Ran J B , et al . Templated synthesis and activation of highly nitrogen-doped worm-like carbon composites based on melamine-urea-formaldehyde resins for high performance supercapacitors [J ] . Electrochimica Acta , 2016 , 194 : 168 - 178 .

Mao N , Wang H L , Sui Y , et al . Extremely high-rate aqueous supercapacitor fabricated using doped carbon nanoflakes with large surface area and mesopores at near-commercial mass loading [J ] . Nano Research , 2017 , 10 : 1767 - 1783 .

Wang G Q , Zhang J , Kuang S , et al . Nitrogen-doped hierarchical porous carbon as an efficient electrode material for supercapacitors [J ] . Electrochimica Acta , 2015 , 153 : 273 - 279 .

Candelaria S L , Uchaker E , Cao G . Comparison of surface and bulk nitrogen modification in highly porous carbon for enhanced supercapacitors [J ] . Science China Materials , 2015 , 58 ( 7 ): 521 - 533 .

Hao L , Li X L , Zhi L J . Carbonaceous electrode materials for supercapacitors [J ] . Advanced Materials , 2013 , 25 ( 28 ): 3899 - 3904 .

Shan D D , Yang J , Liu W , et al . Biomass-derived three-dimensional honeycomb-like hierarchical structured carbon for ultrahigh energy density asymmetric supercapacitors [J ] . Journal of Materials Chemistry A , 2016 , 4 : 13589-13602 .

Fan X M , Yu C , Yang J , et al . Hydrothermal synthesis and activation of graphene-incorporated nitrogen-rich carbon composite for high-performance supercapacitors [J ] . Carbon , 2014 , 70 : 130 - 141 .

Chen H , Zhou M , Wang Z , et al . Rich nitrogen-doped ordered mesoporous phenolic resin-based carbon for supercapacitors [J ] . Electrochimica Acta , 2014 , 148 : 187 - 194 .

Chen H , Wang G , Chen L , et al . Three-dimensional honeycomb-like porous carbon with both interconnected hierarchical porosity and nitrogen self-doping from cotton seed husk for supercapacitor electrode [J ] . Nanomaterials , 2018 , 8 ( 6 ): 412 .

Sun L , Zhou H , Li L , et al . Double soft-template synthesis of nitrogen/sulfur-codoped hierarchically porous carbon materials derived from protic ionic liquid for supercapacitor [J ] . ACS Applied Materials & Interfaces , 2017 , 9 ( 31 ): 26088 - 26095 .

Xia K S , Huang Z Y , Zheng L , et al . Facile and controllable synthesis of N/P co-doped graphene for high-performance supercapacitors [J ] . Journal of Power Sources , 2017 , 365 : 380 - 388 .

Zhao L , Fan L Z , Zhou M Q , et al . Nitrogen-containing hydrothermal carbons with superior performance in supercapacitors [J ] . Advanced Materials , 2010 , 22 ( 45 ): 5202 - 5206 .

Heimböckel R , Kraas S , Hoffmann F , et al . Increase of porosity by combining semi-carbonization and KOH activation of formaldehyde resins to prepare high surface area carbons for supercapacitor applications [J ] . Applied Surface Science , 2018 , 427 : 1055 - 1064 .

Wang Z , Zhou M , Chen H , et al . Hierarchical activated mesoporous phenolic-resin-based carbons for supercapacitors [J ] . Chemistry-An Asian Journal , 2014 , 9 ( 10 ): 2789 - 2797 .

Wei L , Sevilla M , Fuertes A B , et al . Hydrothermal carbonization of abundant renewable natural organic chemicals for high-performance supercapacitor electrodes [J ] . Advanced Energy Materials , 2011 , 1 ( 3 ): 356 - 361 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

聚苯胺/二氧化锰/聚吡咯复合纳米球的制备及其电化学储能性

阳离子交换树脂基介孔石墨化碳合成与储钠性能

单层聚苯胺微球阵列结构的制备及其吸附性能

酚醛树脂基炭微球结构调控与功能化制备研究进展

酚醛泡沫的燃烧行为及阻燃研究进展