两亲性超支化聚酯-酰胺的制备及其性能

童身毅; 寇玉霞; 刘新泰; 曾光明; 温晋嵩

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两亲性超支化聚酯-酰胺的制备及其性能

材料科学与工程 | 更新时间：2026-03-26

- 两亲性超支化聚酯-酰胺的制备及其性能
- Preparation and properties of amphiphilic hyperbranched poly(ester-amide)
- 化工学报 2006年57卷第2期
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- 网络首发：2006-02-25，
  
  纸质出版：2006
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童身毅, 寇玉霞, 刘新泰, 等. 两亲性超支化聚酯-酰胺的制备及其性能[J]. 化工学报, 2006,57(2).

TONG Shenyi, KOU Yuxia, LIU Xintai, et al. Preparation and properties of amphiphilic hyperbranched poly(ester-amide)[J]. CIESC Journal, 2006, 57(2).
童身毅, 寇玉霞, 刘新泰, 等. 两亲性超支化聚酯-酰胺的制备及其性能[J]. 化工学报, 2006,57(2). DOI：

TONG Shenyi, KOU Yuxia, LIU Xintai, et al. Preparation and properties of amphiphilic hyperbranched poly(ester-amide)[J]. CIESC Journal, 2006, 57(2). DOI：

摘要

Abstract

A hyperbranched poly(ester-amide)(HP) with hydroxyl end-groups was synthesized from diisopropanolamine (DIPA) cis-1

2-clyclohexane-dicarboxylic anhydride (HHPA) and pentaerythritol (PETL)

and a kind of amphiphilic hyperbranched macromolecule was prepared with the hydroxyl end-groups modified by the addition of polyethylene glycol monomethyl ether（MW550

MPEG550）.The structure of the macromolecules was characterized with IR

DSC

GPC and SEM.The results indicated that the hyperbranched poly(ester-amide) had narrow molecular mass distribution with polydispersity 1.47

and glass transformation temperature (Tg) 36℃.It was shown by SEM micrographs that the amphiphilic polymer in water solution exhibited nano-spherical particles dispersion with 50～100 nm diameter.

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