孙启文, 朱英, 朱炳辰. Study on The Fluidized Bed Electrochemical Reactor(Ⅱ) Conduction Mechanism and VoltageFluctuation Characteristics[J]. CIESC Journal, 1991, (5).
孙启文, 朱英, 朱炳辰. Study on The Fluidized Bed Electrochemical Reactor(Ⅱ) Conduction Mechanism and VoltageFluctuation Characteristics[J]. CIESC Journal, 1991, (5).DOI:
the voltage fluctuation characteristics are experimentally studied for a silver deposition system. At the same time
the influences on voltage fluctuation of the degree of expansion of fluidized bed
of the voltage difference between collector and counter
and of the fluidization state are investigated. The conduction mechanism proposed in Part( I ) is corroborated experimentally.The experimental results show that there are two manners for the particle and electrolyte voltage fluctuations
one of high frequency but low amplitude and the other of low frequency but high amplitude. When slugging or channeling appears
the particle voltage and the electrolyte voltage fluctuate irregularly while the overvoltage has essentially no irregular fluctuation. The influence of the voltage difference between collector and counter on the voltage fluctuations is rather pronounced. When the voltage difference is lower than about 1V for the reactor used there are essentially not low frequency
high amplitude voltage fluctuations. When the voltage difference is greater than about 1V
the low frequency
high amplitude voltage fluctuations for both the particle and electrolyte become more and more remarkable.