A Study on Complex Network Reaction Kinetics of Hydroisomerization of C_8-Aromatics
化工学报1989年第3期
作者机构:
华东化工学院化学工程研究所,华东化工学院化学工程研究所 ,上海,上海
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DOI:
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网络首发:1989-06-25,
纸质出版:1989-06-25
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戴星, 施亚钧. 八碳芳烃临氢异构化反应网络的动力学研究[J]. 化工学报, 1989,(3).
Dai Xing and Shi Yajun(East China Institute of Chemical Technology, Shanghai). A Study on Complex Network Reaction Kinetics of Hydroisomerization of C_8-Aromatics[J]. CIESC Journal, 1989, (3).
Dai Xing and Shi Yajun(East China Institute of Chemical Technology, Shanghai). A Study on Complex Network Reaction Kinetics of Hydroisomerization of C_8-Aromatics[J]. CIESC Journal, 1989, (3).DOI:
A new complex reaction network has been proposed for the hydroisome-rization of C8-aromatics
in which three xylene isomers
ethylbenzene and a lumped component C8-cycloparaffins are present in the reaction system with the products from all irreversible reactions lumped into one pseudo component. The kinetic model of Hougen-Watson hyperbolic type is used to describe the complex reaction network. Experiments were conducted in a flow-type mini-reactor with on-line GC analyzer. The catalyst used is ot Pt/Zeolite type (SKI-300). Measurements were made at an approximately constant activity and selectivity level of the catalyst A trial and error matrix method was used to solve the hyperbolic kinetic problem. The parameters of the model and the activation energies and trequency tactors were obtained from the experimental data.