Wang Zihao and Fu Jufu(Beijing Institute of Chemical Technolongy, Beijing). The Swelling Behavior of (W/O)/W Liquid Surfactant Membrane (Ⅱ) Modeling of the Permeation Swelling Process[J]. CIESC Journal, 1989, (4).
Wang Zihao and Fu Jufu(Beijing Institute of Chemical Technolongy, Beijing). The Swelling Behavior of (W/O)/W Liquid Surfactant Membrane (Ⅱ) Modeling of the Permeation Swelling Process[J]. CIESC Journal, 1989, (4).DOI:
The transfer of water through the organic phase of kerosene containing surfactants Span80
L113B and certain carriers was studied theoretically and experimentally in (W/O)/W LSM. The process of swelling owing to osmotic pressure can be pictured as solubilization of water in the membrane phase caused by surfactants and carriers and then its diffusion through the membrane between the two aqueous phases due to a gradient of chemical potential. The data of solubilization of water in oil caused by surfactants and carriers were measured. A mathematical model containing no adjustable parameters for estimating the "permeation swelling" rate
Fso
was developed. The predicted values agreed well with the experimental data of Fujinawa (1984)