Li Huasheng Fang Wenji(Zhengzhou Institute of Technology, Zhengzhou). The Kinetics of NO Absorption into Aqueous Fe(II)-EDTA Solution[J]. CIESC Journal, 1988, (1).
Li Huasheng Fang Wenji(Zhengzhou Institute of Technology, Zhengzhou). The Kinetics of NO Absorption into Aqueous Fe(II)-EDTA Solution[J]. CIESC Journal, 1988, (1).DOI:
A process for the simultaneous absorption of NO (from nitric acid plant emissions) and H2S(from coal gas produced in synthetic ammonia plants) in aqueous Fe(II)-EDTA solution was proposed. The kinetics of absorption of NO in aqueous Fe(II)-EDTA solution was studied. It was found that the reaction was rather complicated: NO +Fe(II) - EDTA = Fe(II) (NO) EDTA
and was a second order reaction with respect to the forward reaction and first order with respect to the reverse reaction. The mechanism of the absorption process was discussed
the mathematical model describing the absorption process of(2
l)order fast reversible reaction: A + B = E
was established
and compared with other mathematical models describing the same system. Data from kinetic experiments of NO absorption in aqueous Fe(II)-EDTA solution correlated well with the mathematical model presented by the authors. The Marquardt Method was used to get optimum values for calculations. A kinetic equation of NO absorption in aqueous Fe(II)-EDTA solution was finally established.