The Derivation of an Equation of State for Fluids Through Statistical Mechanics (Ⅱ) The Multi -Square-Well Nonspherical Hard Particle Perturbation Theory
Zhang Bingjian and Hou Yujun(Chemical Engineering Thermodynamics Laboratory, Zhejiang University). The Derivation of an Equation of State for Fluids Through Statistical Mechanics (Ⅱ) The Multi -Square-Well Nonspherical Hard Particle Perturbation Theory[J]. CIESC Journal, 1987, (4).
Zhang Bingjian and Hou Yujun(Chemical Engineering Thermodynamics Laboratory, Zhejiang University). The Derivation of an Equation of State for Fluids Through Statistical Mechanics (Ⅱ) The Multi -Square-Well Nonspherical Hard Particle Perturbation Theory[J]. CIESC Journal, 1987, (4).DOI:
An approach to perturbation theory of fluids (including liquids and dense gases) is described. Two equations of state for hard particle reference fluid are series representations. These are obtained from a new radial distribution function For hard spheres
the three-term truncated form of the equations are the same as the pressure and the compressibility equation of state given by the Precus-Yevick theory. The molecular potential of real fluid is approximated with a number of square-well nonspherical potentials and the higher-order perturbation terms are obtained by using generalized Barker-Henderson approximation. A formula for the thermodynamic properties of multi-square-weii nonspherical potential hard particle perturbation is being derived.