PR方程用于低温高压含氢体系汽液平衡计算和结果分析

肖九高; 卢焕章

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PR方程用于低温高压含氢体系汽液平衡计算和结果分析

化工学报 | 更新时间：2025-12-16

- PR方程用于低温高压含氢体系汽液平衡计算和结果分析
- High Pressure Low Temperature Vapor-Liquid Equilibria Calculation and Analysis of Hydrogen Containing Systems with Peng-Robinson Equation of State
- 化工学报 1988年第3期
- 作者机构：
  
  北京化工学院化学工程系,北京化工学院化学工程系
- 作者简介：
- 基金信息：
- DOI：
  中图分类号：
- 网络首发：1988-06-25，
  
  纸质出版：1988-06-25
- 稿件说明：
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肖九高, 卢焕章. PR方程用于低温高压含氢体系汽液平衡计算和结果分析[J]. 化工学报, 1988,(3).

Xiao Jiugao and Lu Huanzhang(Depertment of Chemical Engineering, Be jing Institute of Chemical Technology). High Pressure Low Temperature Vapor-Liquid Equilibria Calculation and Analysis of Hydrogen Containing Systems with Peng-Robinson Equation of State[J]. CIESC Journal, 1988, (3).
肖九高, 卢焕章. PR方程用于低温高压含氢体系汽液平衡计算和结果分析[J]. 化工学报, 1988,(3). DOI：

Xiao Jiugao and Lu Huanzhang(Depertment of Chemical Engineering, Be jing Institute of Chemical Technology). High Pressure Low Temperature Vapor-Liquid Equilibria Calculation and Analysis of Hydrogen Containing Systems with Peng-Robinson Equation of State[J]. CIESC Journal, 1988, (3). DOI：

摘要

本文用PR状态方程推算低温高压含氢体系汽液相平衡.在计算中

考虑了正、仲氢的转化

并且采用两种方法考虑了量子效应.结果表明比原PR方程更精确地描述了汽液平衡.

Abstract

The Peng-Robison equation of state is used for predicting vapor-liquid equilibria of hydrogen containing systems at low temperature and high pressure. Quantum correction and the effect of ortho-para conversion of hydrogen were introduced into the P-R equation. Several ways of incorporating these effects into the original P-R equation were studied and the calculated results were compared. The incorporation of these effects led to a more accurate description of VLE than the original P-R equation of state.

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