In spite of the effect of cycling on crystal size distribution(CSD) of potassium chloride in a pilot plant crystallizer
the average size can still be simulated by a steady-state mathematical model. According to this model
the CSD in the main size range for industrial crystallizers may be expressed as an exponential function of the population density n with respect to crystal size L
as for mixed-suspension-mixed-product-removal (MSMPR) crystallizers. For fine and coarse crystals
the withdrawal of fines and the classification of coarse crystals
respectively
should be taken into account as in the case of the R-Z model. For intermediate crystals
which can settle behind the baffles and can not be drawn off effectively from the elutriator
their retention time is taken to be infinite for simplification. The resulting mathematical model is expressed by Eqs. ( 2 )-( 5 ) and illustrated in Fig. 2. This model is a generalized form of all previous models for crystallizers. The calculated CSD in the main-size range fits well data from a 520-liter pilot-plant crystallizer. The calculated values for crystal growth rate G
dominant crystal size LD
median crystal size L50
suspension density MT
and production rate P/V
all agree
within 10%
with the corresponding experimental data. However
the MT equation
Eq. (10)
is rather complicated
so a. simplified model
in which LF = 0 and Z = ∞
is derived
and a simplified MT equation
Eq. (11)
is used for crystallizer design. The design Procedure for industrial crystallizers with elutriators is also given.