贺承祖. The Relationship between Freezing Point Depression of Aqueous Inhibitor Solution and Depression of Gas-Hydrate Formation Temperature[J]. CIESC Journal, 1982, (4).
贺承祖. The Relationship between Freezing Point Depression of Aqueous Inhibitor Solution and Depression of Gas-Hydrate Formation Temperature[J]. CIESC Journal, 1982, (4).DOI:
the correlation between depression of gas hydrate formation temperature AT and freezing point depression of aqueous inhibitor solution △T has been established according to the principle of thermodynamics: where n is water molecular number in the gas hydrate
T0
T0 are gas hydrate formation temperature and freezing point of water in the absence of inhibitors
respectively
λ
λ are gas hydrate formation heat and ice fusion heat respectively. △T can be calculated from △T with this coreelation. The results obtained are close to experimental values. Pieroens mehtod can only be used for non-electrolyte inhibitors
whereas this method is independent of the types of inhibitors. Since △T is obtained more easily than △T