Lu Nai-chen, Li Guang-fu, Lu Yun-zhi and Zhao Xu-jianInstitute of Chemistry, et al. Kinetics on Epoxidation of Propylene with Ethylbenzene Hydroperoxide[J]. CIESC Journal, 1980, (4).
Lu Nai-chen, Li Guang-fu, Lu Yun-zhi and Zhao Xu-jianInstitute of Chemistry, et al. Kinetics on Epoxidation of Propylene with Ethylbenzene Hydroperoxide[J]. CIESC Journal, 1980, (4).DOI:
and others studied the kinetics on molybdenum-catalysed epoxidation of propylene with ethylbenzene hydroperoxide
proposed a mechanism model of this reaction and suggested that effective concentration of catalyst is constant during the process of epoxidation. In this paper
the reaction has been studied experimentally based on investigation. After analyzing the data obtained in our experiment and that of
it is shown that the effective concentration of the catalyst is not a constant but a variable
and the consumption rate of the catalyst is in accordance with the first order reaction. Thus
the authors have corrected the mechanism model in literature [3] and indicated that the deactivation mechanism of the catalyst is different from the inhibition mechanism described by.