Study on the Radiation-induced Bulk Polymerization of Chlorotrifluoroethylene——The Effect of Radiation Conditions on Polymerization Progress and None-strength Temperature of Polymer
刘钰铭, 姜林宗. Study on the Radiation-induced Bulk Polymerization of Chlorotrifluoroethylene——The Effect of Radiation Conditions on Polymerization Progress and None-strength Temperature of Polymer[J]. CIESC Journal, 1981, (2).
刘钰铭, 姜林宗. Study on the Radiation-induced Bulk Polymerization of Chlorotrifluoroethylene——The Effect of Radiation Conditions on Polymerization Progress and None-strength Temperature of Polymer[J]. CIESC Journal, 1981, (2).DOI:
The effect of radiation conditions on the polymerization progress and none-strength temperature (NST) in the radiationinduced bulk polymerization of chloro-trifluoroethylene is presented in order to bring to light the regularity by which high quality products may be prepared. On changing the dose(D)
dose rate(I)and radiation temperature (T)
the kinetic progress remains smooth. One of the principal factors of controlling the product quality
i. e. NST
has been especially discussed and a relation between the factors which affect NST is obtained. This relation provides the basis for the selection of conditions for preparing products with various properties: when t≤20℃
NST = 1.75.l0-2.T0.9.I-0.39.D0.39; when t≥20℃
NST = 4.108.T-3.3.I-0.36.D0.39. The test results testify that the products from the bench-scale experiment have good thermal stability
excellent mechanical properties
reproducible quality
and high purity. The technological process is simple.