Electrosynthesis of electrode board material LiAlO2
化工学报2010年第S1期
作者机构:
淮南师范学院化学系
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网络首发:2010-06-29,
纸质出版:2010-06-29
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方文彦. 电化学方法制备电极板材料LiAlO2[J]. 化工学报, 2010,(S1).
方文彦. Electrosynthesis of electrode board material LiAlO2[J]. CIESC Journal, 2010, (S1).
方文彦. 电化学方法制备电极板材料LiAlO2[J]. 化工学报, 2010,(S1).DOI:
方文彦. Electrosynthesis of electrode board material LiAlO2[J]. CIESC Journal, 2010, (S1).DOI:
电化学方法制备电极板材料LiAlO2
摘要
Abstract
0.18 g Li slice was put into 100 ml ethanol and 1 ml acetyl-acetone solution and then the precursor of nano-LiAlO2 was synthesized by electrolysis of aluminum for 6 h at the current of 0.2 A in the above.Nano-LiAlO2 was obtained at 550℃ for 2 h after drying and hydrolysis of the precursor.The products were characterized by XRD
TEM and Raman.The results indicate that the precursor should be calcined at 550℃ in order to make the nano-sized LiAlO2 of 30 nm.In molten carbonate fuel cell stack(MCFC)
the average opening circuit voltage of individual cell is about 1.15 V.The density of the electric current reaches 187 mA·cm-2 .The output power of stack is 217.8 W.The cell was operated for 10 thermal circles without reducing its performance.