王洁莹. Preparation of FePt/GC nanocatalysts and their electrocatalytic activities for ethanol oxidation[J]. CIESC Journal, 2010, (S1).DOI:
纳米FePt/GC催化剂的制备及其对乙醇的电氧化性能
摘要
Abstract
Iron nanoparticles were uniformly deposited on glassy carbon electrode by electrochemical cyclic voltammetry,and the Fe core/Pt shell nanoparticles were further obtained through “galvanic replacement”.SEM observation illustrated that the cuboid nanoparticles dispersing uniformly on GC surface.The electrocatalytical properties for ethanol oxidation of the nano-Pt/GC,nano-FePt/GC were studied by cyclic voltammetry(CV).The nano-FePt/GC electrode shows high electrocatalytical activity.The catalytic activity is in the order of:nano-Pt/GC<nano-FePt/GC.The onset potential(Ei)of ethanol oxidation on nano-FePt/GC electrode is negatively shifted 0.044 V,and the steady oxidation current density(jp)is enhanced about 2.16 times,compared with nano-Pt/GC electrode.