史有强. Preparation and characterization of 2MMZ-PS microcapsule-type latent curing agent[J]. CIESC Journal, 2011, (9).DOI:
潜伏性2MMZ-PS微胶囊固化剂的制备与表征
摘要
Abstract
A novel heat released microcapsule-type latent curing agent was prepared by solvent evaporation technique with 2-methylimidazole(2MMZ)as core material and polystyrene(PS)as wall material.The chemical structure
core material content
surface morphology
size distribution and curing characteristics of this microcapsule-type curing agent were characterized by FT-IR
TGA
SEM
granulometer and DSC.The obtained microcapsules had a smooth surface and displayed a narrow size distribution with the mean size about 10.18 μm
and its core material content was about 40.36%.In addition
the one-component adhesive made from the microcapsules and epoxy resin E-51 showed excellent curing characteristics and latent properties.It was found that the E-51/2MMZ-PS microcapsule system could be cured at 100℃ in 1 h and its shelf life at room temperature was more than 1 month.