Reaction characteristics of CO2 captured by red mud
化工学报2011年第9期
作者机构:
1. 1中国矿业大学(北京)化学与环境工程学院,北京,100083
2. 新疆大学资源与环境科学学院,新疆,乌鲁木齐,830046
作者简介:
基金信息:
DOI:
中图分类号:
网络首发:2011-09-05,
纸质出版:2011-09-05
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伊元荣1. 利用赤泥捕获CO2反应特性[J]. 化工学报, 2011,(9).
伊元荣1. Reaction characteristics of CO2 captured by red mud[J]. CIESC Journal, 2011, (9).
伊元荣1. 利用赤泥捕获CO2反应特性[J]. 化工学报, 2011,(9).DOI:
伊元荣1. Reaction characteristics of CO2 captured by red mud[J]. CIESC Journal, 2011, (9).DOI:
利用赤泥捕获CO2反应特性
摘要
Abstract
Red mud is an alkaline solid waste released from Al2O3 smelting and can be used as capture agent to absorb CO2 in fume.In this paper
red mud from Bayer process of China Aluminum Corporation was selected and used
and the effect of reaction temperature
time
and ratio of solid to liquid
agitation speed and CO2 flow rate on absorbing efficiency of red mud was investigated to obtain the best process parameters and conditions.The results show that one gram fluidic red mud containing 44.12%(mass) water can capture 0.11—0.12 g CO2 at 40℃
under the ratio of solid to liquid of 1∶10
the reaction time of 120 min
the agitation speed of 700 r·min-1 and the CO2 gas flow rate of 0.25 L·min-1.The properties of red mud before and after absorbing CO2 were characterized by XRD
SEM
BET
and FT-IR.The data from XRD show that main components of red mud are Ca2SiO4
CaCO3
Na2Si2O5
CaTiO3
Ca3Si2O5
Ca3Al2O6
and NaCO3
after the reaction with CO2
the peaks of Ca2SiO4
Na2Si2O5 and Na2CO3 in XRD pattern disappear.Furthermore
owing to the alkaline substances in red mud can react with CO2 to get carbonates;some new phases can be found in the XRD spectrum.The analysis by SEM
BET and FT-IR imply that the microstructures and shapes of red mud have occurred a change and are different before and after capturing CO2.These data results show that red mud can be used for capturing CO2 in fume and provide an effective way with low cost for reducing carbon emissions.