王世锋. Preparation and characterization of α-Al2O3 submicron powders synthesized at low temperature by sol-gel method[J]. CIESC Journal, 2010, (12).DOI:
溶胶-凝胶法低温合成亚微米α-Al2O3的制备与表征
摘要
Abstract
Using Al(NO3)3·9H2O
Cu(NO3)2·3H2O and Ti(OC4H9)4 as raw materials
Al2O3 submicron powders were synthesized at a low temperature by the sol-gel process
and the phase and microstructure of powders were investigated.By doping Cu(NO3)2·3H2O and Ti(OC4H9)4 into alumina sol
a blue gel was obtained through placing the sol at 80℃ for a long time.Calcining the blue gel at 950℃ for 2 h produced amorphous Al2O3 powder with only a little γ-Al2O3 crystal phase
while α-Al2O3 nanopowders with a diameter of 80—100 nm were formed at the calcining temperature of 1000℃.As the calcining temperature increased to 1050℃
the grains grew to 200—400 nm.These results indicated that the synthesis temperature of α