高继慧. Effect of SO2 on NO removal by calcium hydroxide[J]. CIESC Journal, 2010, (11).
高继慧. SO2对钙基吸收剂吸收NO的作用机理[J]. 化工学报, 2010,(11).DOI:
高继慧. Effect of SO2 on NO removal by calcium hydroxide[J]. CIESC Journal, 2010, (11).DOI:
SO2对钙基吸收剂吸收NO的作用机理
摘要
Abstract
The effect of SO2 on NO removal by Ca(OH)2 was investigated at a low temperature. The influence of H2O and O2 on the enhancement effect of SO2 on NO removal was analyzed. The experimental results showed that NO removal was negligible in the absence of SO2. SO2 could enhance NO removal. H2O and O2 have great influence on the enhancement of SO2 on NO removal. NO could not be absorbed by Ca(OH)2 in the absence of O2
even though a high SO2 removal could be attained. SO2 could enhance NO removal when H2O and O2 were present in the flue gas simultaneously. CaSO3
a typical desulfurization reaction product
could not oxidize NO to NO2. The multi-molecular intermediate species
which could decompose to NO2
was not formed from the adsorption of NO
H2O and O2 on the surface of absorbent. There may be some unstable intermediate species formed from the desulfurization reaction