VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS
化工学报2002年第8期
作者机构:
1. 河南大学化学系
2. 华东师范大学化学系
作者简介:
基金信息:
DOI:
中图分类号:
网络首发:2002-08-25,
纸质出版:2002-08-25
稿件说明:
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孙仁义, 孙茜. 含盐体系汽液平衡数据的检验[J]. 化工学报, 2002,(8).
SUN Renyi, SUN Qian. VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS[J]. CIESC Journal, 2002, (8).
孙仁义, 孙茜. 含盐体系汽液平衡数据的检验[J]. 化工学报, 2002,(8).DOI:
SUN Renyi, SUN Qian. VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS[J]. CIESC Journal, 2002, (8).DOI:
含盐体系汽液平衡数据的检验
摘要
Abstract
This paper regards the activity coefficient of salt in mixed solvents with constant composition as a function of vapor-liquid equilibrium data by means of ternary Gibbs-Duhem equation. A verification method including two independent criteria for vapor-liquid equilibrium data of salt containing system is proposed on the bases of thermodynamics and the Debye-Hückel electrolytical solution theory.A ccording to the criteria every experimental point can be verified by the calculation of its vapor-liquid equilibrium data.Not only is this method rigorous in the theory
but also very convenient in the application.Under the condition of fixing the ratio between two solvents it can be used for vapor-liquid equilibrium data verification of various salt-containing systems