PREPARATION AND CATALYTIC PROPERTY OF SUPPORTED H3PW12O40
化工学报2001年第9期
作者机构:
哈尔滨工业大学环境工程与科学系
作者简介:
基金信息:
DOI:
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网络首发:2001-09-25,
纸质出版:2001-09-25
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王海彦, 周定. 负载磷钨酸催化剂制备与催化性能[J]. 化工学报, 2001,(9).
WANG Haiyan, ZHOU Ding. PREPARATION AND CATALYTIC PROPERTY OF SUPPORTED H3PW12O40[J]. CIESC Journal, 2001, (9).
王海彦, 周定. 负载磷钨酸催化剂制备与催化性能[J]. 化工学报, 2001,(9).DOI:
WANG Haiyan, ZHOU Ding. PREPARATION AND CATALYTIC PROPERTY OF SUPPORTED H3PW12O40[J]. CIESC Journal, 2001, (9).DOI:
负载磷钨酸催化剂制备与催化性能
摘要
Abstract
Active carbon supported H 3PW 12 O 40 (PW 12 )solid acid catalysts are prepared and used in the etherification of light FCC gasoline with methanol.The effects of preparation conditions and the PW 12 loading on the activities of PW 12 (40)/C catalysts are studied.The results showed that the reflux time and the activating temperature influence the activity of the catalyst.As the loading of PW 12 on active carbon is lower
the reaction of PW 12 with the hydroxyl on the surface of active carbon makes the activity of the catalyst decrease.With the increase of loading of PW 12 on active carbon
the activities of the catalysts increase.Using PW 12 (40)/C as catalyst
under the conditions of reaction temperature 75℃
pressure 0.8MPa
molar ratio of methanol with tertiary carbonic olefins 1.0
and hourly space velocity 1.0 h -1
the ethers content in etherified light gasoline is up to 13.86%.