蒋文华, 韩世钧. COORDINATION SOLUTION THEORY OF TWO-FLUID POLYMER——EQUATION OF STATE FOR POLYMER MIXTURES AND ITS APPLICATION[J]. CIESC Journal, 1997, (4).DOI:
On the basis of two-fluid polymer coordination solution model
an equation of state (EOS) for polymer mixtures is derived
and applied to pVT correlation of four polymer mixture systems (polyisobutene/cyclohexane
polyisobutene/benzene
polydimediylsiloxane/hexadimethyl-siloxane
polydimethyl siloxane/benzene). A satisfactory accuracy is obtained. A new concept named fluidity coefficient is proposed. It could be obtained from equilibrium properties (pVT data)